The invention relates to a synchronous 
fluorine-
calcium removal treatment process for the 
reverse osmosis concentrated liquor of waste water from lead-
zinc smelting. The process comprises the following steps: firstly, removing 
fluorine by virtue of oxidation and 
precipitation, secondly, removing 
calcium by precipitating, thirdly, removing 
fluorine by virtue of adsorption, next, sequentially regenerating 
activated aluminum oxide, removing fluorine from the generated mixed liquor, removing 
calcium from the generated mixed liquor and treating the generated mixed liquor, and finally, removing fluorine by precipitating, wherein the 
precipitation sludge generated in the calcium removal process is gathered and dehydrated by virtue of filter pressing, the water obtained by filter pressing is returned to a 
reverse osmosis concentrated liquor collecting tank for circular treatment, and the mud cake is subjected to unified disposal. After the oxidization, 
precipitation and adsorption treatment processes are adopted, the fluorine content and the 
calcium content of the 
reverse osmosis concentrated liquor are lower than 3mg / L and 50mg / L, respectively, and the problems of scaling and blockage caused by fluorine ions and calcium ions in the subsequent 
evaporation and concentration process of the reverse 
osmosis concentrated liquor are solved.