1043 results about "Lead zinc" patented technology

The invention discloses a comprehensive recovery method of complex polymetal sulphide ore containing copper, lead and zinc and adopts dressing-metallurgy combination method and hydrometallurgy-pyrometallurgy combination method to recover metals. The recovery method comprises the following steps: first performing bulk flotation to the complex polymetal sulphide ore, fine grinding the obtained concentrate, leaching by using two-step counter flow oxygen pressure leaching process, extracting and separating copper and zinc from the obtained leachate, electrodepositing the strip liquor of copper-loaded organic phase to obtain cathode copper, cleaning the obtained raffinate and electrodepositing to obtain cathode zinc; pressurizing leaching residue to perform flotation separation and obtain sulfur concentrate and lead silver residue, distilling sulfur concentrate to obtain sulfur; performing lead smelting process to lead silver residue to obtain electrolytic lead product and lead anodic slime; and comprehensively recovering noble metals such as gold, silver and the like from lead anodic slime. The method can greatly improve the metal recovery rate, resource utilization and the economic efficiency of mines and generate a lot of sulfur so as to obviously reduce the sulfur dioxide pollution to the atmosphere.

The invention discloses a lead and zinc flotation method to ferreous blende and pyrrhotite typed complex lead zinc silver sulphide ore, mainly comprising lead ore branch flotation which controls the electrochemical conditions of the flotation and the zinc and sulfur flotation separation which controls the electrochemical conditions of the flotation. The invention has the advantages of implementing the lead-zinc sulfur separation by adopting twice branch flotation, carrying out fast flotation to the lead ore by using a novel composite catching agent to the galena and silver ore with easy floating coarse grains under the conditions of higher ore pulp potential and low pH; the normal flotation of the lead ore with difficultly floated fine grains is carried out under the conditions of lower ore pulp potential and high pH. The pH of the ore pulp is adjusted to more than 12 by lime for the gangue after the lead is floated; the iron blende is activated by bluestone; the iron blende is recovered by the catching agent with the same type of the lead sulfide floatation, thus leading the property of the lead flotation waste water to be basically consistent with that of the zinc flotation waste water and being beneficial for the circular application of floatation waste water.

The invention relates to a beneficiation method, in particular to a beneficiation method for separating the polymetallic sulphide ore containing copper, lead, zinc and tin. The method comprises the following steps: (1) carrying out ore grinding on the raw ore before carrying out bulk flotation on copper, lead and sulphur, using diethyl mixed with xanthate as collecting agent of copper and lead mineral, using zinc sulphate and sodium sulfite as inhibitor of zinc mineral; (2) carrying out phase-2 ore grinding and selection; (3) separating copper, lead and sulphur, using sodium sulfite and sodium thiosulfate as the inhibitor of the lead and sulphur mineral, using Z-200 as collecting agent for separation and scavenging and then carrying out lead flotation after the separation and scavenging; (4) carrying out zin flotation on the bulk flotation tailings; and (5) finally, carrying out reselection on the zinc flotation tailings to recover tin. The metalliferous mineral of the invention has the advantages of good separating effect, high metal recovery rate, more complete comprehensive recovery of useful minerals, low cost of medicament, simple method, easy operation and energy conservation.

The invention provides municipal sludge expanded ceramsite and a preparation method thereof. The municipal sludge expanded ceramsite is prepared from the following materials by mass percentage: 20% to 45% of municipal sludge, 50% to 70% of shale, tailings or clay, 1% to 5% of organic matter and 1% to 5% of iron powder, wherein, the tailings is one of pyrite tailings, gold tailings, lead-zinc tailings and aluminum tailings; and the organic matter is sawdust. The preparation method comprises the following steps: feeding the shale, tailings or clay into a crusher, and carrying out the screening treatment; adding and mixing the municipal sludge, the organic matter and the iron powder, feeding into an ageing silo and stirring; then, feeding into a granulating machine, granulating and calcinating in a rotary kiln; and finally, cooling and stacking the calcinated ceramsite by classification. By using a great amount of municipal sludge, the invention is resource-saving and environment-friendly; compared with the original cost, the overall cost of a building is reduced by 5% to 10%; and the prepared expanded ceramsite has the advantages of light weight, fire resistance, sound absorption, good heat insulating and preserving performance, simple process and low cost, so that the invention is suitable for industrialized production.

The invention discloses a technology of enhanced-dispersion partial selective and bulk flotation of lead and zinc sulfide ores under low and high alkalinity. During grading of the lead and zinc sulfide ores, sodium hexametahposphate is taken as a dispersion agent and directly added into a ball mill, the ores are ground till the ores with the size of 0.074mm account for 67%-70%, lime is taken as an adjusting agent, zinc sulfate and sodium sulfite are taken as inhibitors, dithiophosphate BA and diethyldithiocarbamate are taken as collectors, and selective flotation of part of lead minerals with good floatability can be performed under low alkalinity; then xanthate and the diethyldithiocarbamate are taken as collectors, and the flotation of the lead minerals is further performed under high alkalinity; copper sulfate is added in lead flotation tailings for activation, butyl xanthate is further taken as the collector for flotation of zinc blende and part of pyrite, and zinc-sulfur separation flotation is further performed on zinc-sulfur mixed concentrate; and sulfuric acid is added in zinc flotation tailings for activation, and the xanthate is taken as the collector for flotation of the remaining pyrite. By adopting the technology, the lead-silver recovery rate can be improved, the using amount of lime and sulfuric acid can be reduced, the circulating amount of middlings can be reduced, the ore dressing cost can be reduced and the grade of the concentrate can be improved.

The invention discloses a bath smelting method and an apparatus of zinc sulfide concentrate and lead-zinc containing materials. The smelting method comprises the following steps: mixing lead-zinc-containing mixed materials according to a certain proportion and pelletizing; and then, adding the pelletized materials into an oxidation furnace having a lead-containing high-zinc-slag bath with proper ingredients and smelting points, and blowing oxygen-enriched air into the bath for generating an oxidation reaction with the pelletizing materials to generate high-concentration SO2 flue gas and lead-containing high-zinc slag, wherein the SO2 flue gas is used for preparing acid, the lead-containing high-zinc slag is continuously discharged from the oxidation furnace into a reduction furnace bath, zinc in the lead-containing high-zinc slag is reduced into zinc vapor to be collected, and the lead is reduced into metal lead and such precious metals as gold and silver in the raw materials are captured and gathered at the bottom part of the bath to be discharged. The bath smelting method disclosed by the invention has the advantages of short flow, strong raw material adaptability, low energy consumption, environment friendliness, efficient source utilization and the like and is expected to solve the current treatment difficulty of high-iron zinc sulfide concentrate, zinc oxide ores, iron and steel plant zinc dust and gold-containing iron ores and the long-term pollution problems of zinc slag of hydrometallurgy.

The invention discloses a beneficiation method for cu-pb-zn polymetallic ores, and belongs to the technical field of non-ferrous metal beneficiation. According to the technical scheme, the characteristic of complex cu-pb-zn-sulfur polymetallic ores with embedded fine-grained carbon level is utilized, a technological process of carbon-removing, cu-pb partial bulk flotation, cu-pb separation and zn-and-sulfur choosing in tailings is adopted, a concentration and fine grinding mode is adopted to achieve deep reagent removal, the influence of slurry on flotation is effectively eliminated, efficient collectors A8 and depressors T721 for cu-pb separation are used in the cu-pb partial bulk flotation process, separation and recovery of copper, lead, zinc and sulfur are effectively achieved, and concentrate mixing is obviously lowered.

The invention discloses a method for recovering valuable metal from waste residue containing lead and zinc through a wet-fire combination process. The method is characterized by comprising the steps of preparation of simple-substance lead, leaching of zinc hypoxide, preparation of simple-substance copper, indium and tin, preparation of zinc and the like. By utilizing the wet-fire combination process to recover the metal, the recovery rate of the lead and the zinc is high, the leaching separation effect of the copper, the indium and the tin is good, and the waste residue is utilized cyclically. The existing resources are further recovered, and pollution of the valuable metal to the environment is avoided, so that the method is safe and environment-friendly. Besides, the method is simple in principle, reasonable in flow path, high in yield and product quality and low in cost.

The invention discloses a method using mineral dressing backwater to float and recover gold, silver, lead and zinc in cyanidation tailings of a gold mine. The method comprises the following working procedures: (1) pulp pre-processing stage: adding mineral dressing backwater in cyaniding tailings, adding concentrated sulfuric acid to stir for 5 minutes, reacting the concentrated sulfuric acid withthe pulp until smoke is completely generated, adding activated carbon to remove reagent for 55 minutes, and then pumping to a flotation workshop section; and (2) bulk flotation stage: pumping the pretreated pulp into a 3-meter stirring buffer slot, stirring for 30 minutes continuously, flowing into a medicine injecting slot 1 and a medicine injecting slot 2 by proper motion, sequentially adding copper sulfate and diethyldithiocarbamate, stirring fully, then entering a floatation unit to perform roughing on the pulp, further carrying out selection stage by stage on the rough concentrate obtained by roughing to obtain qualified lead and zinc bulk concentrate containing gold and silver, and further carrying out scavenging stage by stage on the roughed tailing to obtain floated tailing which is the sulphur concentrate. The invention realizes comprehensive utilization of mineral dressing tailings and zero exhaust of the tailings, thus realizing cleaner production of the mineral dressing process.

A method that cyanide barren solution is used for recovering the copper-lead-zinc from cyanide tailing by means of floatation belongs to the field of nonferrous metal separation. The processing procedures of the method are as following: (1) mashing: the cyanide barren solution is added into the cyanide tailing and stirred to ore slurry, the concentration of which is 35 to 40 per cent; (2) lead-zinc preferential flotation: after being stirred, the ore slurry is put into flotation machine and lime, Ethyl thiocarbamate and Sodium n-butyl xanthate synthetic are added in to the ore slurry. The course of once rough floatation, twice scavenging and twice concentration is processed to recover Zinc and Lead; (3) Cu-S separation: after the tailing of lead and zinc bulk flotation is concentrated, the cyanide barren solution is added into the tailing and the tailing is made into the ore slurry with the concentration of 35 to 40 per cent. And then, the ore slurry is put into the floatation machine and sulfate, sodium sulfite, Z-200 and ammonium butyl aerofloat are added into the tailing. The course of once rough floatation, twice scavenging and twice concentration is processed to recover copper. And the tailing can be for sale as sulfur concentrate; (4) Reuse of separation tailing water: the press filtrate of bulk concentrate, the overflow of thickener, the press filtrate of copper concentrate and the press filtrate of the sulfur concentrate return to the buffer slot of the cyanide barren solution to be used for replacement fluid. The invention has the advantages of good flotation effect, high recovery rate of the copper-lead-zinc and zero discharge of waste water and residue.

The invention discloses a manufacturing method of metal lead and zinc through waste slag with lead and zinc or low-grade lead or zinc oxide, which comprises the following steps: grinding lead zinc slag or lead zinc oxide into 0.1-1mm; stirring and leaching through strong base solution under 10-100 deg.c for 30-1000min; filtering; draining filtrate; electrolyzing filtrate directly to generate lead with current density at 100-1000A/m2 under 30-100 deg.c for 1-5h; stopping electrolyzing when tank voltage is improved to 1.8-2.5V; producing rough lead with 97-99.9% lead on the cathode; pressing; obtaining electrolytic refined lead; electrolyzing residual electrolytic liquid with zinc under 10-100 deg.c at 2.5-3.5V with current density at 500-1500A/m2 for 1-10h; drying zinc on the cathode protected by inert gas; obtaining one-grade metal zinc powder; circulating residual electrolytic solution in the alkaline leaching course directly.

The invention discloses a flotation method of a brass ore-containing complex lead-zinc sulphide ore, which comprises the steps of: adjusting the pH value to be 10-11 in the process of ore grinding; adding ore pulp electric potential regulating agent-sodium pyrosulfite to adjust the electric potential of the ore pulp to be at 220-260mV (relative to hydrogen standard potential); adding zinc sulfate, ethoxy-dithioformicacid ethyl formate and ethyl thio carbamate grinding ore; performing one roughing, one scavenging and two selecting to enrich copper-lead mineral by means of mixing and floating and to form into copper-lead mixed concentrate; performing reagent desorption to the copper-lead mixed concentrate by adding active carbon; adding potassium peroxydisulfate and carboxymethyl starch to restrain lead-containing mineral in the copper-lead mixed concentrate such as galena and the like; performing one roughing, one scavenging and three selecting to obtain copper concentrate; adjusting the pH value of tailings after recovering copper mineral by floating the copper-lead mixed concentrate to be 9.0; adding sodium pyrosulfite, ethyl thio carbamate and butyl ether alcohol; and performing one roughing, one scavenging and two selecting to obtain lead concentrate. The method guarantees the grade of the copper and the lead concentrate, and reduces the environmental pollution.

The invention discloses a mineral dressing method for separating a Cu-Pb-Zn-Fe multi-metal sulfide mineral, which comprises the following steps: selecting a raw mineral, grinding the mineral, carrying out mixed flotation to Cu, Pb and Zn, carrying out mixed flotation to Cu and Pb, separating Cu and Pb, carrying out Zn flotation and pyrite flotation, and finally obtaining a Cu, Pb, Zn and pyrite concentrate. The method has the advantages of good metal sulfide mineral effect and high metal recovery rate, is simple to operate and is suitable to popularize and apply.

An inhibition gravity treatment separation method for lead-zinc, lead-zinc-copper or lead-copper floatation collective concentrates pertains to the mineral processing technical field. In gravity treatment separation of the collective concentrates, lead sulphide inhibitor is added. The method includes the following procedures: after lead sulphide inhibitor is added, the collective concentrate is sent to a table concentrator again for gravity treatment separation; after the gravity treatment separation in the table concentrator, the concentrate belt includes lead concentrate and sub-concentrate belt and the tailing zone includes sub-concentrate and gangue containing lead-zinc, lead-zinc-copper or lead-copper; the obtained sub-concentrate and the gangue undergo the gravity treatment separation in the table concentrator again or for a plurality of times, thus finally obtaining lead concentrate, zinc concentrate, zinc-copper concentrate or copper concentrate. Due to the existence of lead sulphide inhibitor, the floatability of the lead sulphide is completely inhibited so as to highlight the high specific gravity feature of the lead sulphide; therefore, the lead sulphide is easily separated from a plurality of metallic collective concentrates by the gravity treatment separation in the table concentrator. The content of the metal elements in the obtained concentrates is mutually low and the major metal concentrate and the attaching metal concentrate can both satisfy the metallurgical standards and requirements, thus having extremely remarkable economic benefits.

The objective of the invention is to provide a process of using sulphur lead-zinc containing tailings to prepare sulphur iron ore concentrate, using magnet-floating combination process or magnet-gravity-floating combination process to produce sulphur iron ore concentrate containing more than 90% sulphur and iron, using the sulphur iron ore concentrate to produce sulphuric acid, getting 98% sulphuric acid of national standard while getting iron ore concentrate power containing more than 60% iron, and sulphur in the tailings is reduced to less than 2%, recovery rate of sulphur iron in ore concentrate is more than 86%. The invention make comprehensive recovery and use of sulphur iron in the lead-zinc tailings.

The invention relates to a biological ceramisite filter material made of vulcanized lead zinc ore flotation tailings. The material is characterized by being prepared from 80-90wt% of vulcanized lead zinc ore flotation tailings, 8-18wt% of clay, 1.5-2.5wt% of pore former and an additional bonder, wherein the pore former is sawdust, bamboo scraps or straws, the bonder is lignin calcium xanthate, sodium carbonate or sodium silicate liquid, and the solid-to-liquid ratio of materials used by the biological ceramisite filter material is (8-12):1. The preparation method comprises the following steps of: weighing based on proportion of main and auxiliary materials; drying; mixing; forming; drying; preheating; roasting; and cooling to prepare a biological ceramisite filter material product made of the vulcanized lead zinc ore flotation tailings. The preparation method is simple and convenient to implement, free from secondary pollution, practical and reliable. The biological ceramisite filter material made of the vulcanized lead zinc ore flotation tailings provided by the invention has the advantages of turning ore waste residue into wealth and greatly lowering the cost of materials, so that the biological ceramisite filter material is a high-quality water treatment agent.

The invention relates to a floating method of sulfide-oxide mixing Pb-Zn mine. The lead floating method adopts the flow process of one fast separation, one roughing separation, one sweeping separation and three classifications so that the mine grouting acidity of the full floating process can keep at pHú¥11. The zinc floating method adopts the flow process of one fast separation, one roughing separation, one sweeping separation and two classifications so that the mine grouting acidity of the full floating process can keep at pHú¥12. It can increase the recovery ratio of PbíóZn over 10% when Pb-Zn mine has oxide ratio over 30%.

A technological method for comprehensively recovering valued metal such as indium and germanium from lead-zinc smoke. The present invention relates to the technical field of wet-process metallurgy, specifically a technological method for recovering valued metal such as lead, zinc, germanium, indium and silver from smoke volatilizing from a rotary kiln containing lead, zinc, germanium, indium and silver. The method of the present invention includes the separation and recovery of lead and silver, the extraction, separation and recover of indium, the distillation, separation and recover of germanium, and the recovery of zinc. The method of the present invention has too much comprehensive recovery rate, too much resource utilization rate and a relatively low recovery cost.

The invention relates to a method for comprehensively recovering a valuable metal in a zinc tailing and belongs to the technical field of metal beneficiation. The process procedure comprises the following steps: roughing the prepared zinc tailing under the magnetic field strength of 8,000 to 12,000 OE by taking an attractive mineral in the zinc tailing as a carrier; performing ore grinding on the magnetic material until the magnetic material which can pass through 200 meshes screen accounts for 60 to 70 percent for dissociating lead-zinc combination; selecting the ground magnetic mineral under the magnetic field strength of 2,500 to 4,000 OE to obtain an iron ore concentrate finished product with the grade of iron over 60 percent; and sorting a nonmagnetic material through a multi-section table to obtain a tin-rich middling product with the grade of tin over 3 percent. The method has the advantages of increasing recovery rate of a tin metal, recovering ferrous metal and manganese metal in the zinc tailing, and effectively utilizing the tailing resource, along with simple beneficiation process flow, low production cost, environmental-friendliness and good application and popularizing prospect; and the fruit can be spread and applied to the development and exploiting of high-ferric and low-tin resources.

The invention provides an ore dressing method for lead-zinc-silver poly-metallic ores. Lead-silver concentrates and zinc concentrates are finally obtained through the steps of raw ore grinding, lead fast roughing, lead slow roughing, lead scavenging, lead fast concentration, lead slow concentration, zinc fast roughing, zinc slow roughing, zinc scavenging, zinc fast concentration and zinc slow concentration. The lead-zinc-silver poly-metallic ores sorted by the ore dressing method provided by the invention are good in sorting index and high in separation efficiency; the ore dressing method is a lead-zinc-silver ore dressing method which is stable, efficient, strong in adaptive capacity, good in sorting effect, high in comprehensive recovery index and low in production cost and is suitable for popularization and application.

The invention discloses a metallurgical process for recovering metal copper, lead, zinc and tin from copper refining waste slag, which uses waste liquid of zinc electrolysis with sulfuric acid or waste liquid of zinc electrolysis to perform the acid leaching; more than 95% of the zinc and copper are in the solution, the Fe 2+ in the solution is less than or equal to 1.5g/L; then the copper slag is used for removing chlorine; when the Cl- in the solution is less than or equal to 1.0g/L, the solution is sent to a copper electro-deposition; the electro-deposition decopperization can produce copper piece or copper powder; the decopperization neutralization is to add calcine or zinc oxide for neutralizing acid when the Cu2+ in the solution is less than or equal to 1.0g/L; lime is used for adjusting the pH value to 5.2-5.4; after purifying and removing residue of the zinc sulfate solution, the solution is sent to the zinc electro-deposition for producing zinc piece; the lean and tin pyrometallurgical purification is that, after more than 98% of lead and tin is sent to the acid leaching residue, the material of the acid leaching residue is balled and sent to a smelting furnace, so as to produce lead-tin alloy; the lead-tin alloy is directly sent to a vacuum fractionation furnace for purifying the lead and tin product; sulfur dioxide in the tail gas is absorbed by ammonia, so as to obtain ammonium sulphate product. The process is to extract copper and zinc joint wet process and to purify lead and tin by pyrometallurgical method; the process flow is effectively shortened, the metalrecovery rate and the resource utilization rate are both largely increased, and there is no secondary pollution in the process.

The invention discloses a flash smelting method and a device for zinc sulfide concentrates and materials containing lead and zinc. The flash smelting method for the zinc sulfide concentrates and the materials containing the lead and the zinc comprises mixing the dry powder materials containing lead and zinc in proportion and spraying the mixed materials and oxygen into a smelting device from the top of a reaction tower; the smelting device is formed by three portions namely a reaction tower area, a reducing area and a clarification area which are provided with communicated bottoms; materials containing zinc achieve a oxidation sweetening reaction in the air above the reaction tower to generate into high zinc slag melt with an appropriate melting point of minus 1200 DEG C and fall into the reaction tower area; the liquid form high zinc slag melt enters into the reducing area; zinc in the high zinc slag melt is performed reduction to generate zinc steam to be collected; lead is performed reduction to be metallic lead; precious metal such as golden, silver and the like of raw materials are gathered to be precipitated at the bottom of a melt pond and discharged through a lead discharging opening. Slags which are performed reduction are discharged through a slag discharging opening, fuming processing is abandoned or further performed according to the content of the lead and the zinc. The flash smelting method and the device for the zinc sulfide concentrates and the materials containing the lead and the zinc have the advantages of being short in process, strong in material adaptability, low in energy consumption, environmentally friendly, high in resource utilization efficiency, significant for technology progress of a lead and zinc smelting industry and the like.

The invention provides a method for extracting metal indium from waste residues generated from lead and zinc smelting. The method is implemented by the following steps: carrying out low-temperature and low-acid leaching on the waste residues generated from the lead and zinc smelting, and removing acid-soluble metals from the waste residues; then carrying out high-temperature and high-acid leachingto obtain indium; and obtaining the metal indium after extraction, re-extraction, reduction and refining. The method has relatively short process flow and low production cost, generates a great amount of byproducts, can comprehensively recover and recycle waste water and the waste residues, is not only good for environmental protection, but also realizes cyclic and comprehensive resource use. Thetotal recovery rate of the metal indium is 70-80%, and the recovery rate of high-purity metal indium is up to 99.995%.