10 results about "Diglyme" patented technology

Systems and methods are provided for treating, degrading, and incinerating fluorocarbons or fluorinated materials, such as Freon ® with reduced gaseous perfluorinated compound (PFC) emissions. The methods include mixing a fluorinated material with a hydroxide base and optionally a solvent system (e.g., diglyme, polyether, polyether alcohol, polyethylene glycol selected from ethylene glycol and PEG 50 to PEG 3350, N-methyl pyrrolidine, dihydrolevogluton, and / or water ("solvent")) in a batch reactor to form a reaction mixture (also referred to as a suspension). The reaction mixture is heated to a temperature in the range of about 25 °C to about 400 °C for about 0.5 hours to about 240 hours to defluorinate the fluorinated material and produce a defluorinated waste product. More specifically, the methods convert organic fluorine present in the fluorinated material, such as Freon ® to inorganic fluorides. As a result, the defluorinated waste product can be incinerated with reduced harmful gaseous PFC emissions.

The application discloses a high-rate anode-free sodium metal battery electrolyte and a preparation method and application thereof, and belongs to the technical field of energy storage batteries. The high-rate anode-free sodium metal battery electrolyte provided by the application comprises an organic solvent and a sodium salt dissolved in the organic solvent; and the organic solvent is prepared by mixing diglyme and methyl perfluorobutyl ether (MPE). The electrolyte prepared by the application changes the preferential reduction sequence by reconfiguring the molecular arrangement of the solvation cluster through the dipole-dipole interaction formed by the diglyme and the MPE, can spontaneously perform a chemical reaction, directly participates in the construction of the original SEI dominated by NaF, ensures that the dense NaF SEI can be effectively generated before the battery cycle, realizes the Na + The uniform distribution of flux and the optimized migration path promote the dense and uniform metal sodium deposition and effectively inhibit the dendrite growth. The application has excellent cycle stability and wide application prospect in the anode-free sodium metal battery.

To provide a solid electrolyte for a calcium ion secondary battery, the solid electrolyte being capable of exhibiting performance for stabilizing a negative electrode even when charging and discharging are repeated, while high energy capacity is maintained, in a calcium ion secondary battery.SOLUTION: A solid electrolyte for a calcium ion secondary battery includes a calcium salt, a polymer compound, and a polymer solvent. The calcium salt is a calcium complex hydride salt and / or a calcium closo-complex hydride salt, the polymer compound is an ether-based polymer, and the polymer solvent is at least one selected from the group consisting of THF (tetrahydrofuran), G1(1,2-dimethoxyethane; glyme), G2 (diglyme), G3 (triglyme), and Me-THF (methyltetrahydrofuran).SELECTED DRAWING: Figure 1

The disclosed embodiments detail improved methods for the synthesis of diketopiperazines from amino acids. In particular improved methods for the cyclocondensation and purification of N-protected 3,6-(aminoalkyl)-2,5-diketopiperazines from N-protected amino acids. Disclosed embodiments describe methods for the synthesis of 3,6-bis-[N-protected aminoalkyl]-2,5-diketopiperazine comprising heating a mixture of an amino acid in the presence of a catalyst in an organic solvent. The catalyst is selected from the group comprising sulfuric acid, phosphoric acid, p-toluenesulfonic acid, 1-propylphosphonic acid cyclic anhydride, tributyl phosphate, phenyl phosphonic acid and phosphorous pentoxide among others. The solvent is selected from the group comprising: dimethylacetamide, N-methyl-2-pyrrolidone, diglyme, ethyl glyme, proglyme, ethyldiglyme, m-cresol, p-cresol, o-cresol, xylenes, ethylene glycol and phenol among others.

The disclosed embodiments detail improved methods for the synthesis of diketopiperazines from amino acids. In particular improved methods for the cyclocondensation and purification of N-protected 3,6-(aminoalkyl)-2,5-diketopiperazines from N-protected amino acids. Disclosed embodiments describe methods for the synthesis of 3,6-bis-[N-protected aminoalkyl]-2,5-diketopiperazine comprising heating a mixture of an amino acid in the presence of a catalyst in an organic solvent. The catalyst is selected from the group comprising sulfuric acid, phosphoric acid, p-toluenesulfonic acid, 1-propylphosphonic acid cyclic anhydride, tributyl phosphate, phenyl phosphonic acid and phosphorous pentoxide among others. The solvent is selected from the group comprising: dimethylacetamide, N-methyl-2-pyrrolidone, diglyme, ethyl glyme, proglyme, ethyldiglyme, m-cresol, p-cresol, o-cresol, xylenes, ethylene glycol and phenol among others.

The application discloses a preparation method of 3-chloro-5-fluoro-2-methylbenzoic acid, relates to the technical field of 3-chloro-5-fluoro-2-methylbenzoic acid production, and the method is characterized in that: 2-methyl-5-nitrobenzoic acid is used as a starting raw material, selective chlorination is carried out on the starting raw material in preheated high-temperature concentrated sulfuric acid and dichloro hydantoin, then esterification is completed by a one-pot method, catalytic hydrogenation reduction is carried out under low-pressure and low-temperature conditions by the synergistic action of a Raney nickel catalyst and a platinum-carbon catalyst, a high-purity amino intermediate is obtained, smooth thermal decomposition fluorination is carried out in a diglycol dimethyl ether solvent, alkaline hydrolysis and refinement are carried out, and finally the end product is obtained; the product has high purity and high yield.

The disclosed embodiments detail improved methods for the synthesis of diketopiperazines from amino acids. In particular improved methods for the cyclocondensation and purification of N-protected 3,6-(aminoalkyl)-2,5-diketopiperazines from N-protected amino acids. Disclosed embodiments describe methods for the synthesis of 3,6-bis-[N-protected aminoalkyl]-2,5-diketopiperazine comprising heating a mixture of an amino acid in the presence of a catalyst in an organic solvent. The catalyst is selected from the group comprising sulfuric acid, phosphoric acid, p-toluenesulfonic acid, 1-propylphosphonic acid cyclic anhydride, tributyl phosphate, phenyl phosphonic acid and phosphorous pentoxide among others. The solvent is selected from the group comprising: dimethylacetamide, N-methyl-2-pyrrolidone, diglyme, ethyl glyme, proglyme, ethyldiglyme, m-cresol, p-cresol, o-cresol, xylenes, ethylene glycol and phenol among others.

The present disclosure relates to a sodium-metal cell comprising (a) an anode; (b) an electrolyte comprising a base electrolyte containing diglyme and sodium hexafluorophosphate, dioxolane, and tris(trimethylsilyl)borate; and (c) a cathode comprising sodium or Na2 / 3Cu1 / 12Ni1 / 4Mn2 / 3O2, having a high mass loading of at least 15 mg cm-2, wherein the sodium-metal cell enables stable cycling at a temperature of -40 °C or lower.

Disclosed is a process for the destruction of per- and polyfluoroalkyl substances (PFAS). The process could include the step of adding a solvent, such as acetonitrile, to PFAS materials to extract / dissolve PFAS. A sodium-metal based solution, such as sodium naphthalene diglyme solution, could be added to the mixture. Also disclosed is a process to measure extractable organic fluorine and total organic fluorine in samples or products containing PFAS using the sodium-metal based solutions.

A system and method for treating, degrading, and incinerating a fluorocarbon or fluorinated material, such as Freon®, with reduced emissions of gaseous perfluorinated compounds (PFCs) is provided. The method includes mixing the fluorinated material with a hydroxide base and optionally a solvent system, such as diglyme, polyethers, polyether alcohol, a polyethylene glycol selected from ethylene glycol and PEG50 through PEG3350, N-methylpyrrolidine, cyrene and / or water ("solvent"), in a batch reactor to form a reaction mixture, also referred to as a suspension. The reaction mixture is heated to a temperature ranging from about 25o C to about 400 ºC for about 0.5 hours to about 240 hours to defluorinate the fluorinated material and produce a defluorinated waste product. More specifically, the method converts organic fluorine present in the fluorinated material, such as Freon®, to inorganic fluoride. Thus, the defluorinated waste product can be incinerated with reduced emissions of harmful gaseous PFCs.