The present invention discloses a preparation method of an organic silicon material and concretely indicates a preparation method of hexamethyldisilane. The present invention considers one kind of two kinds of dimethylbenzene and trimethylbenzene as solvent, wherein, the dimethylbenzene is preferential; the solvent is put in a reactor under the state without oxygen, metal potassium is put into the solvent, then solution is heated to 60 DEG C to 85 DEG C, furthermore trimethylchlorosilane is added to react for certain time, finally the product can be obtained by normal separation method. The present invention has the advantages of saving energy, short reaction time, high product yield etc. The present invention can be widely applied to almost all national economic fields of the defense and military industry, the aviation and aerospace field, the electronic and electrical field, the building field, the machinery field, the metallurgy, the automobile field, the instrument field, the weaving field, the chemical industry, the light industry, the food field, the medical and health field, the personal health care field etc.