The invention provides an ultralow-temperature high-voltage chip aluminum capacitor-used electrolyte, which comprises 32% to 58% of a main solvent, 5% to 34% of an auxiliary solvent, 5.2% to 21.4% ofa solute, 2.5% to 8.5% of a flash fire booster, 0.7% to 2.5% of a hydrogen scavenger and 1% to 10% of a modified synthetic additive, wherein the main solvent is one or multiple selected from ethyleneglycol, diethylene glycol, triethylene glycol, ethylene carbonate, propylene carbonate, gamma-butyrolactone and the like; and the auxiliary solvent is one or multiple selected from diethylene glycol mono-methyl ether, diethyl carbitol, diethylene glycol ethyl methyl ether, diglycol dimethyl ether, triethylene glycol dimethyl ether, diethylene glycol monobutyl ether, dimethyl sulfoxide, sulfolane and the like. The ultralow-temperature high-voltage electrolyte has good negative temperature electric performance, higher stability and stronger applicability.