The invention discloses an ultrathin rigid phenolic
aerogel heat insulation sheet and a preparation method thereof, and belongs to the field of heat insulation materials. The preparation method comprises the following steps: firstly, impregnating a fibrofelt in a
sodium silicate-based rigidifying solution, and carrying out mould pressing and
drying to form a self-supporting rigid framework; then, the framework is soaked in a phenolic
aerogel precursor solution, curing, washing and
drying are carried out, and framework pores are filled with phenolic
aerogel; and finally compounding the
hot melt adhesive film. According to the preparation method, through the specific process sequence of first rigidifying and then compounding, the problems that a traditional aerogel material is poor in rigidity and prone to pulverization, and a
silicon dioxide-based material is insufficient in ultra-high-temperature
ablation resistance are successfully solved, and the thickness of the obtained heat resisting sheet is 0.1-5 mm; the
composite material has excellent rigidity (the compression strength is greater than 2MPa when the deformation quantity is 5%), low heat
conductivity coefficient (0.02-0.045 W / (m.K)) and excellent 1200 DEG C high-temperature
flame ablation resistance, and is especially suitable for
thermal protection in limited spaces such as
new energy batteries and the like.