The invention relates to PRTV durability anti-pollution flashover paint, which comprises the following components by part by weight: 40 to 50 parts of dihydric polydimethylsiloxane, 2 to 6 parts of nano Si02, 2 to 6 parts of cross-linking agent, 0.02 to 1 part of catalyst, 20 to 30 parts of aluminum hydroxide, 5 to 8 parts of decabromodiphenyl, 40 to 50 parts of solvent and 1 to 2 parts of pigment. The paint uses dihydric polydimethylsiloxane as base rubber and has the good properties of ageing resistance, corrosion resistance, water resistance, moisture prevention, no toxin, insulation, shake resistance, excellent simulation, demolding, extremely low contractibility rate and the like. Because nano Si02 is added to the paint, the weather fastness, the ultraviolet resistance and the ageing resistance of a coating are improved. The aluminum hydroxide and the decabromodiphenyl are used as excellent composite fire retardants for the paint, thereby remarkably enhancing the arc resistance of the paint and helping to increase the thickness of the coating. Therefore, inflaming retarding and ageing resistance become more stable.