The invention discloses a preparation method of high-
viscosity cationic
starch, which belongs to the technical field of
modified starch, and comprises the following steps: crosslinking
epichlorohydrin, ball-milling and cationizing; the
epoxy chloropropane crosslinking comprises the following steps: mixing
starch,
calcium hydroxide and deionized water, stirring at 40-50 DEG C, adding
sodium stearoyl
lactylate, stirring at 50-55 DEG C, naturally cooling to
room temperature, adding
sodium chloride and
epoxy chloropropane, stirring, dropwise adding a
potassium hydroxide aqueous solution, stirring, adjusting the pH value to 6, filtering, taking filter residues, washing and
drying to obtain crosslinked
starch; in the step of ball milling,
calcium hydroxide,
sucrose fatty acid ester SE-11 and deionized water are mixed and then subjected to ball milling, and a ball-milled material is obtained; the prepared high-
viscosity cationic starch is high in paste
liquid viscosity and cationic substitution degree, good in paste
liquid viscosity stability, uniform in substitution degree and paste
liquid viscosity, high in reaction efficiency in cationization and low in alkali consumption.