The invention provides a preparation method of core-shell magnetic microspheres, and belongs to the technical field of functional material preparation. The preparation method comprises the steps thatfirstly, monodispersed
phenolic aldehyde microspheres or monodispersed
silicon dioxide
phenolic aldehyde core-shell microspheres are synthesized; then the microspheres and
ferric salts are dispersed in a mixing
solvent containing glycerinum and isopropanol, added into a
hydrothermal reaction still for an airtight high-pressure
solvothermal reaction, and a
phenolic aldehyde microsphere / glycerinum
ferric core-shell structure product or a
silicon dioxide / phenolic
aldehyde / glycerinum
ferric core double-shell structure product are correspondingly obtained; and finally, the phenolic
aldehyde microsphere / glycerinum ferric core-shell structure product is calcined in an
inert atmosphere in a
tube furnace to form carbon / ferroferric
oxide core-shell magnetic microspheres, and the
silicon dioxide / phenolic
aldehyde / glycerinum ferric core double-shell structure product is subjected to high-temperature
calcination and alkali
etching by
inert gas to obtain hollow carbon / ferroferric
oxide double-shellmicrospheres. The preparation method is simple, magnetic nanosheets and carbon are compounded successfully, the electromagnetic property of the magnetic nanosheets is improved, the nanosheets adoptedon an outer layer can effectively inhibit a
skin effect, the prepared products have the excellent electromagnetic property, and the preparation method of the core-shell magnetic microspheres can be used for
electromagnetic wave absorption and shielding fields.