The invention provides high silicon cold-rolled non-oriented electrical steel and its preparation method, the high silicon cold-rolled non-oriented electrical steel comprises the following chemical components by weight: less than 0.0015% of C, 2.0%-2.5% of Si, 0.10%-0.3% of Mn, less than or equal to 0.008% of P, less than 0.0015% of S, less than or equal to 0.0020% of N, 1.5%-2% of Als, less than 0.0020% of Ti, less than 0.0020% of Nb, less than 0.0020% of V, and balance of Fe and other inevitable residual elements. The preparation method comprises smelting, continuous casting, hot rolling, normalizing, cold rolling, two-stage annealing and final product annealing, through the composition design using Si and high Al, each technical process is controlled, a high silicon effect is achieved, adding of REM, Ca, Mg, Sb, Sn trace alloy elements is avoided, the cost is reduced, and the product production process stability and finished product electromagnetic property improvement are facilitated.