139results about How to "Prevent re-oxidation" patented technology

The invention discloses a metal greasy dirt cleaning agent and its production method, wherein the metal greasy dirt cleaning agent comprises degreasing agent and surface active agent, while the degreasing agent comprises (by weight ratio) sodium-hydroxide 10-18, sodium carbonate 20-35, sodium tripolyphosphate 15-24, normal sodium pyrophosphate 8-12, sodium silicate 20-30, the surface active agent comprises leveling agent, OP-10 and lauric diglycollic amide 0.8-1.2.

The invention relates to a method for directly preparing titanium and titanium alloy from titaniferous waste residues, and belongs to the technical field of electrochemical metallurgy. The method is characterized in that the titaniferous waste residues are made into an electrolysis electrode, and the electrolysis is performed in a crucible of an electrolytic cell by a solid oxygen permeable membrane in a specific molten salt electrolyte. The method comprises the following process steps: the titaniferous residues is processed by ball milling, then pressed and formed in a mould at 3-6MP, dried in the air, and then sinteredat the temperature of 1000-1100 DEG C for 2h to be made into an electrolysis cathode; molten salt is separated from an anode by an oxygen permeable membrane tube which only conducts oxyanion, the anode is liquid copper or copper alloy with saturated carbon powder, calcium chloride is taken as the molten salt electrolyte, the cathode and the anode are vertically arranged, the electrolytic temperature is 1000-1100 DEG C, the electrolytic voltage is 3.0-3.5V, the electrolysis time is 2-6h, and the cathodic products obtained by the electrolysis are metallic titanium and the titanium alloy. The method has the advantages of simple process, high electrolysis speed and high current efficiency.

The invention relates to a diffusion welding method of a copper target material and a back plate. The diffusion welding method comprises the following steps that (1), the copper target material, the back plate and a cushion block, wherein the back plate is provided with a groove, and the areas of the copper target material and the cushion block are equal to the bottom area of the groove of the back plate; (2), the copper target material and the cushion block in the step (1) are sequentially put into the groove of the back plate to finish assembly treatment, and then a whole body is put into asheath; (3), the sheath obtained in the step (2) is sealed and then degassed; and (4), hot isostatic pressing welding is carried out on the sheath degassed in the step (3), and then the sheath and thecushion block are removed to finish diffusion welding of the copper target material and the back plate. According to the diffusion welding method, by improving an assembly structure of the copper target material and the back plate, the bonding degree of welding faces of the copper target material and the back plate is guaranteed, abnormal growth of crystal grains is effectively avoided, and particularly the phenomenon that the crystal grains are thick and large at the edge of the copper target material is avoided.

The invention relates to a method for connecting a nickel-based superalloy with a Ti2AlNb alloy or a Ti3Al-based alloy, in particular to a diffusion welding connecting method adopting Cu foil and Ti foil as a composite interlayer. The diffusion welding connecting method comprises the steps that the nickel-based superalloy and the Ti2AlNb alloy or the Ti3Al-based alloy are processed into the neededsizes, ground and polished; the Cu foil and the Ti foil are subjected to oxidation film removing, and are placed into acetone with a welded base material to be subjected to ultrasonic cleaning; and the Cu foil makes contact with the nickel-based superalloy, the Ti foil makes contact with the Ti2AlNb alloy or the Ti3Al-based alloy, and thus a welded test piece with the structure of the Ti2AlNb alloy or the Ti3Al-based alloy/the Ti foil/ the Cu foil/ the nickel-based superalloy is obtained, a welded workpiece is placed into a vacuum heating furnace, the pressure is applied, and welding is completed after heating, heat preservation and cooling heat circulating. The welding temperature can be lowered, forming of a brittle phase of a joint is controlled, and the property of the joint is improved; and the obtained shearing strength of the joint at the room temperature reaches 240-310 MPa.

The invention provides an iron ore pre-reduction sintering method. The method comprises the steps that firstly, a traditional mixture is prepared, iron ore powder, a solvent and fuel are subjected to raw material matching, mixing and granulating are conducted, and the traditional mixture is obtained; secondly, a pre-reduction mixture is prepared, after the iron ore powder, an additive and the fuel are evenly mixed, pelleting is conducted, carbon-burdened pellets are obtained and placed in a cylinder mixer, fuel fine powder and quick lime or slaked lime are added for wrapping and granulating, and the pre-reduction mixture is obtained; thirdly, material distribution is conducted, a double-layer material distribution manner is adopted, the pre-reduction mixer prepared in the second step is placed on a sintering machine trolley in advance, and the traditional mixture prepared in the first step is placed on the pre-reduction mixture; and fourthly, sintering is conducted, ignition is conducted, and the traditional mixture and the pre-reduction mixture are subjected to smoke circulation type sintering on a sintering machine. The problem that CO smoke is hard to treat is solved, secondary oxidization in the pre-reduction sinter reducing process is reduced, the combustion atmosphere between material layers is improved, the material temperature is increased, and generation of the iron ore material reducing reaction is accelerated.

The invention belongs to the technical field of flue gas denitration and relates to a system for denitration by spraying ammonia gas in a large-sized boiler high-temperature flue gas area. A boiler comprises a horizontal flue and a vertical flue. The system comprises an SNCR (selective non-catalytic reduction) system provided with a reducing agent injector, the reducing agent injector is a spray pipe disposed on the transverse section of the horizontal flue, an input end of the spray pipe is connected with a reducing agent conveyer, the other end of the spray pipe is closed, and the wall of the spray pipe opposite to flue gas is provided with a spray hole. The invention also discloses a denitration process for denitration treatment using the system, the denitration treatment with the system gives high denitration rate and low ammonia escape quantity as well as full flue gas purification, this product is applicable to present coal-consuming boilers for thermal power generation, iron and steel, chemicals, cements and the like, and satisfactory NOx emission index of these boilers can be ensured.

The purpose of a highly reliable cuprous oxide semiconductor sparking plug sealing method provided by the invention is to provide a sealing method which does not need to carry out oxidation treatment on metal parts in advance and has a high sealing percent of pass. The method is implemented by the following technical scheme: an enamel layer is coated on the lower end surface of a semiconductor part and then sintered, a pre-vitrified glass blank and a porcelain tube are coaxially mounted into a sparking plug shell, and the assembly is then put into a clamp, sent into a furnace along with the clamp and heated to be sealed under high temperature; the sealing process is carried out by two times of heating and pressurization, and in each time of heating process, the porcelain tube connected with the upper end in the sparking plug shell is utilized to apply axial pressure on the end surface of the melted glass blank, so that the melted glass blank can be sufficiently filled in the space of a sealed area. The method solves the problem that the quality of the transitional layer of the bonding interface between an oxidation film and the fused sealing glass is poor.

The invention relates to direct alloying steelmaking process for manganese oxide composite briquettes used for a re-blowing revolving furnace. The technical scheme comprises the following steps of: when the carbon content of molten steel in the revolving furnace is reduced to less than 0.1 percent and the molten steel reaches the temperature of between 1,650 and 1,750DEG C, and adding manganese oxide composite briquettes into the revolving furnace at one time, wherein the manganese oxide composite briquettes, which undergo cold pressing and mixed with carbon, are quickly heated to above 1,500 DEG C by the heat of the molten steel in the revolving furnace, the manganese oxide is quickly self-reduced in the manganese oxide composite briquettes which undergo cold pressing and mixed with carbon, so that the aim of the direct alloying of the molten steel is achieved. Oxygen blowing is stopped in the revolving furnace after the manganese oxide composite briquettes are added into the revolving furnace in order to avoid the re-oxidation of manganese, but the uniformization of manganese in the molten steel is enforced by the bottom-blowing strengthening molten pool stirring of the revolving furnace. The process of the invention has the advantages of simple process, easy operation and control, high manganese yield, great energy conservation, low CO2 emission and low production cost of the alloying of the manganese in the molten steel.

The invention belongs to the technical field of semiconductor manufacturing, and particularly discloses a surface passivation method for Ge. By adopting a thioacetamide (CH3CSNH2) solution to passivate a Ge sheet, the natural oxide on the surface of the Ge sheet can be removed, and an even and compact GeSx passivation layer can be generated to prevent the reoxidation of the surface of the Ge sheet and eliminate the Fermi level pinning. A layer of high-quality Al2O3 film is deposited on the passivated Ge sheet by adopting an atom layer deposition method to prevent the reoxidation of the surface of the Ge sheet, and therefore, a good Al2O3/Ge interface can be obtained.

The invention discloses a preparation method of a titanium-doped lithium iron phosphate cathode material. The preparation method comprises the following steps: by using a lithium source compound, a phosphorus source compound, an iron source compound and metallic titanium as raw materials, evenly mixing the raw materials and melting the mixture in a melting furnace at high temperature to obtain a mixture; performing water quenching on the mixture into particles; grinding and dispersing the particles and a carbon source compound together to ensure that the particle size reaches the Fineness index of D90 being less than or equal to 0.2 micron; making powder in a spray drying method, and calcining the powder for 40 to 300 minutes in an atmosphere furnace of 600 to 800 DEG C; performing coolingto obtain the lithium iron phosphate cathode material. By adopting a high-temperature melting method, the uniformity of the lithium iron phosphate cathode material is improved; by introducing metallic titanium powder, Fe<3+> in a melt solution is reduced into Fe<2+> at high-temperature melting state, and generated Ti<4+> is doped into a lithium iron phosphate structure, and the electron conductivity of the lithium iron phosphate cathode material is improved through formation of vacant positions; the specific surface area is reduced by means of grinding and dispersion as well as carbon coating, and the tapping density of the lithium iron phosphate cathode material is improved. According to the preparation method disclosed by the invention, crushing and integration are not needed, so that the original sphericity can be maintained and technological processes are also simplified.

The invention discloses a low-corrosivity soldering flux which is prepared from the following raw materials in parts by weight: 35-45 parts of modified rosin, 7-9 parts of an activating agent, 4-5 parts of a thixotropic agent, 0.8-1 part of a surfactant, 1.2-1.4 parts of other additives and 30-40 parts of a solvent. According to the soldering flux, the modified rosin is adopted as a film forming matter of the soldering flux, the modified rosin has good film forming performance, -COOH with high reaction activity and high metal oxide removing capacity, an oxidation film on the surface of a welded matter can be removed together with an activating agent in the welding process, and the welding effect is enhanced; organic acid and triethanolamine are compounded to serve as an activating agent, so that the acidity of the whole soldering paste system is reduced (the corrosivity is reduced), the stability is enhanced, triethanolamine and organic acid can be decomposed from a neutral product inthe high-temperature welding process, the spreading performance of the soldering paste is improved, the welding spot spreading rate is increased, and then the welding effect is improved.

The invention discloses a method for welding an ultra-pure copper target material and a back plate. The welding method comprises the steps that coating of a welding surface of the back plate with a thread is performed; then the back plate and the ultra-pure copper target material are assembled; the assembled ultra-pure copper target material and back plate are put into a sheath; the sheath is sealed and vacuumized; the vacuumized sheath is subjected to hot isostatic pressing treatment; and welding of the ultra-pure copper target material and the back plate is completed. According to the method, as the structure of the welding surface of the back plate is improved, threaded protrusions can be embedded into the target material, and then a combination effect of the target material and the back plate is enhanced, then diffusivity of a coating film is utilized, and the target material and the welding surface of the back plate are fully covered, so that the welding combination degree betweenthe target material and the back plate is improved, and the welding strength is high; the coating film is placed on the back plate, so that completeness of the coating film is ensured during welding,and damage caused to the coating film by the threaded protrusions is avoided. According to the welding method, a hot isostatic pressing process is adopted to control the size of crystal grains of thetarget material, so that the target material meets application requirements of a super-large-scale integrated circuit.

The invention discloses a method for recovering iron in low-iron Bayer process red mud. The method comprises the steps that de-alkalization treatment is conducted on the Bayer process red mud by adopting calcium oxide to mix the de-alkalization red mud with activated carbon; the mixture is mixed with a binding agent to be pressed into tablets; the tablets are placed into a graphite crucible, high-temperature treatment is conducted under the condition that argon is introduced all the time in a vacuum electromagnetic sensing furnace, the tablets are cooled down along with the furnace, grinding is conducted, and iron slags are separated through magnetic sorting. The method has the advantages that the recovery rate and grade of iron are higher than 80%, the processed Bayer red mud can be usedfor producing building materials, recovered iron is conformed to demands of industrial steel melting, the problem of excessively high red mud accumulation amount is effectively solved, and an excellent guiding meaning is achieved on the recovery of iron in the low-iron Bayer process red mud.

The invention relates to an atmosphere-adjustable double-temperature-control composite ceramsite sintering rotary furnace and a working method thereof. The atmosphere-adjustable double-temperature-control composite ceramsite sintering rotary furnace comprises a tubular preheating furnace, a speed reducer, supports, a sectioning partition and a tubular sintering furnace, heaters are arranged outside a preheating furnace tube and a sintering furnace tube respectively, thermocouples are arranged in the preheating furnace tube and the sintering furnace tube respectively and are connected with automatic temperature controllers, the speed reducer drives the preheating furnace and the sintering furnace to rotate through linkage chains, and an atmosphere-adjustable ceramsite collector is further arranged outside the sintering furnace. The atmosphere-adjustable double-temperature-control composite ceramsite sintering rotary furnace integrates preheating and sintering and is capable of rotating at a uniform speed, adjustable in preheating and sintering atmosphere, reasonable in allocation and capable of achieving continuous production of ceramsite sintering.

The invention discloses continuous spot coating halogen-free solder paste and a preparation method. The continuous spot coating halogen-free solder paste comprises tin powder and a soldering flux, wherein the soldering flux comprises 40 to 45 weight percent of hydrogenated rosin, 5 to 6 weight percent of hydrogenated castor oil, 16 to 18 weight percent of organic acid, 1 to 2 weight percent of dispersing agent and 31 to 36 weight percent of organic solvent. According to the solder paste, due to the adoption of a needle cylinder packaging container and a two-time defoaming process in the horizontal direction and vertical direction, the problem of uncontinuous tin in the spot coating process due to air bubbles of the spot coating solder paste is solved.

The invention provides a bottom blowing reduction device. The bottom blowing reduction device comprises a furnace body, a feed port, a discharge port, a reduction gas inlet and a reduction gas outlet;the furnace body is transversely arranged, and forms a certain included angle with the horizontal direction; in the length direction of the furnace body, a gas cavity and a material cavity are formedin the furnace body; the gas cavity and the material cavity are separated by a porous plate; the feed port is formed in one higher end of the furnace body; and the reduction gas inlet and the reduction gas outlet both communicate with the gas cavity. The invention further provides a method for bottom blowing reduction by using the device; and materials to be reduced are fed in the material cavityfrom the feed port, slowly move downwards along the inclined furnace body under coaction of the gravity and the reduction gas, and are finally reduced and output from the discharge port. The method has no need to use a push rod or a conveying belt for driving a boat container to move, so that the boat container and a conveying device are omitted.

The present invention discloses a method for preparing a lipid aroma condensate by adopting fat as a raw material and by adopting a two step process of heating oxidation and degradation, and a product thereof. The specific method comprises: 1) in the presence of an antioxidant and water, introducing air to fat to carry out heating stirring oxidation, wherein an air flow rate is 0.1-2 m<3>/kg.h, a temperature is 100-180 DEG C, a time is 0.5-5 h, and a stirring speed is 200-1000 rpm/min; and 2) introducing nitrogen gas to the product obtained from the step 1) to carry out heating degradation, wherein a nitrogen gas flow rate is 0.1-0.5 m<3>/kg.h, a heating temperature is 100-180 DEG C, and a time is 0.5-6 h. According to the present invention, the obtained product has rich, harmonious and fruity lipid aroma, can be used as a thermal reaction flavor raw material, and can further be directly used in chicken essence, instant noodle condiments, soup sticks, sausages, cans, frozen dumplings and other seasonings or food as a natural food additive.

The invention provides a device and a method for online deduction of amino acid disulfide and determination of amino acid. The device mainly comprises a high-pressure pump, a high performance liquid chromatographic column, an online reduction column, and a chemiluminescent detector. The basic technical route is as follows: a amino acid solution to be determined enters the online reduction column after being subjected to high performance liquid chromatographic column separation; and the amino acid disulfide in the solution is restored into corresponding mercaptoamino acid by tri(2-propyloic) phosphine complex crystal of zinc (II) in the online reduction column, and then enters the chemiluminescent detector to be subjected to online determination of the amino acid. The online reduction device is simple and convenient in detection method, rapid in reduction process, high in reduction efficiency, good in repeatability, and wide in application prospect, and newly restored mercaptoamino acid is prevented from being oxidized into the amino acid disulfide again in sample treatment and analysis processes.