Method for recovering iron in low-iron Bayer process red mud
A technology of Bayer process red mud and dealkalized red mud, which is applied in the field of recycling iron in low-iron Bayer process red mud, can solve the problems of low iron grade and recovery rate, unsatisfactory recovery effect, poor practicability, etc., so as to improve the recovery rate of iron Taste, conducive to growth and convergence, the effect of thorough restoration
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Embodiment 1
[0018] A method for reclaiming iron in low-iron Bayer process red mud, the specific steps are as follows:
[0019] (1) Calcium oxide is used to dealkalize the Bayer process red mud. The specific method of dealkalization treatment: under normal pressure, according to the ratio of calcium oxide to the mass ratio of sodium oxide in the Bayer process red mud of 4.5:1, in the Bayer process Add calcium oxide to the red mud, add water according to the liquid-solid ratio g:mL of 3.5:1 to make a slurry, and react for dealkalization for 3 hours at the leaching temperature of the slurry at 95°C. Mix to obtain a mixture in a ratio of 100:2;
[0020] (2) Mix the mixture in step (1) with the binder with a mass volume ratio g:mL of 7:2, and press it into a 3cm-high columnar sheet under a pressure of 6Mpa, with a binder concentration of 3.5g / mL polyvinylpyrrolidone ethanol solution;
[0021] (3) Put the pressed tablet of step (2) into a graphite crucible, bake in a vacuum electromagnetic i...
Embodiment 2
[0024] A method for reclaiming iron in low-iron Bayer process red mud, the specific steps are as follows:
[0025] (1) Calcium oxide is used to dealkalize the Bayer process red mud. The specific method of dealkalization treatment: under normal pressure, according to the mass ratio of calcium oxide to Bayer process red mud of 5:1, in the Bayer process Add calcium oxide to the red mud, add water according to the liquid-solid ratio g:mL of 4:1 to make a slurry, and react for dealkalization for 4 hours at the leaching temperature of the slurry at 95°C. A ratio of 100:1.5 is mixed to obtain a mixture;
[0026] (2) Mix the mixture in step (1) with the binder mass volume ratio g:mL of 8:2.5, and press it into a 3.5cm-high columnar sheet under a pressure of 6Mpa, with a binder concentration of 3g / mL polyvinylpyrrolidone ethanol solution;
[0027] (3) Put the pressed tablet of step (2) into a graphite crucible, and bake at 1400°C for 40 minutes in a vacuum electromagnetic induction ...
Embodiment 3
[0030] A method for reclaiming iron in low-iron Bayer process red mud, the specific steps are as follows:
[0031] (1) Calcium oxide is used to dealkalize the Bayer process red mud. The specific method of dealkalization treatment: under normal pressure, according to the mass ratio of calcium oxide to Bayer process red mud of 5.5:1, in the Bayer process Add calcium oxide to the red mud, add water according to the liquid-solid ratio g:mL of 4.5:1 to make a slurry, and react for dealkalization for 5 hours at the leaching temperature of the slurry at 95°C. Mix in a ratio of 100:1 to obtain a mixture;
[0032] (2) Mix the mixture in step (1) with the binder mass volume ratio g:mL:14:4, press it into a 2cm-high columnar sheet under a pressure of 6Mpa, and the binder concentration is 4g / mL of polyvinylpyrrolidone ethanol solution;
[0033] (3) Put the pressed tablet of step (2) into a graphite crucible, and bake at 1450°C for 60 minutes in a vacuum electromagnetic induction furnac...
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