Method for recovering iron in low-iron Bayer process red mud

A technology of Bayer process red mud and dealkalized red mud, which is applied in the field of recycling iron in low-iron Bayer process red mud, can solve the problems of low iron grade and recovery rate, unsatisfactory recovery effect, poor practicability, etc., so as to improve the recovery rate of iron Taste, conducive to growth and convergence, the effect of thorough restoration

Active Publication Date: 2019-06-28
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, red mud has great economic value. There are many ways to recover iron in red mud. Direct magnetic separation can be used to recover iron in red mud. However, the iron grade and recovery rate recovered by this method are low. And for low-iron red mud, the effect is even worse; reduction roasting and magnetic separation can also be used to recover iron in red mud. At present, this method mainly uses resistance furnace heating for reduction roasting and then magnetic separation. The recovery effect of red mud is better, but for low iron (T Fe <8%) red mud, the recovery effect is not ideal, and the practicability is poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A method for reclaiming iron in low-iron Bayer process red mud, the specific steps are as follows:

[0019] (1) Calcium oxide is used to dealkalize the Bayer process red mud. The specific method of dealkalization treatment: under normal pressure, according to the ratio of calcium oxide to the mass ratio of sodium oxide in the Bayer process red mud of 4.5:1, in the Bayer process Add calcium oxide to the red mud, add water according to the liquid-solid ratio g:mL of 3.5:1 to make a slurry, and react for dealkalization for 3 hours at the leaching temperature of the slurry at 95°C. Mix to obtain a mixture in a ratio of 100:2;

[0020] (2) Mix the mixture in step (1) with the binder with a mass volume ratio g:mL of 7:2, and press it into a 3cm-high columnar sheet under a pressure of 6Mpa, with a binder concentration of 3.5g / mL polyvinylpyrrolidone ethanol solution;

[0021] (3) Put the pressed tablet of step (2) into a graphite crucible, bake in a vacuum electromagnetic i...

Embodiment 2

[0024] A method for reclaiming iron in low-iron Bayer process red mud, the specific steps are as follows:

[0025] (1) Calcium oxide is used to dealkalize the Bayer process red mud. The specific method of dealkalization treatment: under normal pressure, according to the mass ratio of calcium oxide to Bayer process red mud of 5:1, in the Bayer process Add calcium oxide to the red mud, add water according to the liquid-solid ratio g:mL of 4:1 to make a slurry, and react for dealkalization for 4 hours at the leaching temperature of the slurry at 95°C. A ratio of 100:1.5 is mixed to obtain a mixture;

[0026] (2) Mix the mixture in step (1) with the binder mass volume ratio g:mL of 8:2.5, and press it into a 3.5cm-high columnar sheet under a pressure of 6Mpa, with a binder concentration of 3g / mL polyvinylpyrrolidone ethanol solution;

[0027] (3) Put the pressed tablet of step (2) into a graphite crucible, and bake at 1400°C for 40 minutes in a vacuum electromagnetic induction ...

Embodiment 3

[0030] A method for reclaiming iron in low-iron Bayer process red mud, the specific steps are as follows:

[0031] (1) Calcium oxide is used to dealkalize the Bayer process red mud. The specific method of dealkalization treatment: under normal pressure, according to the mass ratio of calcium oxide to Bayer process red mud of 5.5:1, in the Bayer process Add calcium oxide to the red mud, add water according to the liquid-solid ratio g:mL of 4.5:1 to make a slurry, and react for dealkalization for 5 hours at the leaching temperature of the slurry at 95°C. Mix in a ratio of 100:1 to obtain a mixture;

[0032] (2) Mix the mixture in step (1) with the binder mass volume ratio g:mL:14:4, press it into a 2cm-high columnar sheet under a pressure of 6Mpa, and the binder concentration is 4g / mL of polyvinylpyrrolidone ethanol solution;

[0033] (3) Put the pressed tablet of step (2) into a graphite crucible, and bake at 1450°C for 60 minutes in a vacuum electromagnetic induction furnac...

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Abstract

The invention discloses a method for recovering iron in low-iron Bayer process red mud. The method comprises the steps that de-alkalization treatment is conducted on the Bayer process red mud by adopting calcium oxide to mix the de-alkalization red mud with activated carbon; the mixture is mixed with a binding agent to be pressed into tablets; the tablets are placed into a graphite crucible, high-temperature treatment is conducted under the condition that argon is introduced all the time in a vacuum electromagnetic sensing furnace, the tablets are cooled down along with the furnace, grinding is conducted, and iron slags are separated through magnetic sorting. The method has the advantages that the recovery rate and grade of iron are higher than 80%, the processed Bayer red mud can be usedfor producing building materials, recovered iron is conformed to demands of industrial steel melting, the problem of excessively high red mud accumulation amount is effectively solved, and an excellent guiding meaning is achieved on the recovery of iron in the low-iron Bayer process red mud.

Description

technical field [0001] The invention belongs to the field of metallurgy and resource recycling, and in particular relates to a method for recycling iron in low-iron Bayer process red mud. technical background [0002] Bayer process red mud is a highly alkaline solid waste produced in the process of producing alumina by Bayer process. The chemical composition is quite complex. For every ton of alumina produced, about 1 to 2 tons of red mud will be produced. Under the existing technical conditions , Stockpiling is still the main way to deal with red mud. The cumulative stockpiling of red mud in the world has reached 4 billion tons, and the annual discharge is about 120 million tons; The speed is constantly increasing, taking up a lot of land. The production of a large amount of red mud has brought a very serious impact on human production and life. With the continuous increase of red mud discharge, the gradual depletion of mineral resources and people's attention to environm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/02C22B1/244C22B1/248C21B13/00
Inventor 刘战伟李鹏飞颜恒维马文会谢克强陈正杰雷云吕国强秦博于洁李绍元魏奎先伍继君
Owner KUNMING UNIV OF SCI & TECH
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