1691 results about "Methyl acetate" patented technology

The invention relates to a process for the production of acetic acid by carbonylation of methanol, and reactive derivatives thereof, in a reaction mixture using a rhodium-based catalyst in low water conditions. The process is used to achieve reaction rates of at least 15 g mol/l/hr. The high rate reactions proceed at water concentrations of less than 2.0 wt. %. Under certain conditions, the water concentration in the reaction mixture of the process is maintained at a desired concentration by at least one process step including adding a compound such as methyl acetate, dimethyl ether, acetic anhydride, or mixtures of these compounds to the reaction system. The process step of adding the components to the reaction mixture may be combined with other process steps for controlling water concentrations in reaction mixtures for the carbonylation of methanol.

An environmentally clean dual fuel for an internal combustion engine, comprising acetylene as a primary fuel and a combustible fuel, such as one or more fluids selected from an alcohol such as ethanol, methanol or any other alcohol or alcohols from the group comprising C1-C20 carbon chains, ethers such as from the group comprising dimethyl ether, diethyl ether, methyl t-butyl ether, ethyl t-butyl ether, t-amyl methyl ether, di-isopropyl ether and the like, low-molecular-weight esters such as from the group comprising methyl formate, methyl acetate, ethyl acetate, methyl propionate, ethyl propionate and the like, or other suitable combustible fluid such as mineral spirits and the like, as a secondary fuel for operatively preventing early ignition and knock arising from the primary fuel. The dual fuel, internal combustion system, which generally utilizes a two-stage process for start-up and operation and can be operated with air- or liquid-cooling, is environmentally clean with hydrocarbon, CO, NOx, and SOx emissions substantially eliminated.

The invention relates to a 2-(2-(2, 6-dichlorophenyl amido) phenyl) methyl acetate, relative synthesis method and application, belonging to the technical field of chemical pharmacy, which comprises that adds acid into diclofenac salt to acidify the salt into diclofenac, reacts diclofenac with methanol, or adds acid into diclofenac salt to acidify the salt into diclofenac, to be reacted with chloracetyl chloride to obtain 2-(2-(2, 6-dichlorophenyl amido) phenyl) methyl acetate. The inventive drug has significant anti-inflammatory and analgesic effects.

Acetic acid is produced while inhibiting an increased concentration or production of hydrogen iodide in a carbonylation reactor or corrosion of the carbonylation reactor.

A production process of acetic acid comprises a reaction step for continuously allowing methanol to react with carbon monoxide in the presence of a catalyst system comprising a metal catalyst (e.g., a rhodium catalyst), an ionic iodide (e.g., lithium iodide), and methyl iodide in a carbonylation reactor; and in the process, (i) the concentration of the metal catalyst is maintained at not less than 860 ppm on the basis of weight, the concentration of water is maintained at 0.8 to 15% by weight, the concentration of methyl iodide is maintained at not more than 13.9% by weight, and the concentration of methyl acetate is maintained at not less than 0.1% by weight, in a whole liquid phase in the reactor, and/or (ii) the concentration of the metal catalyst is maintained at not less than 660 ppm on the basis of weight, the concentration of water is maintained at 0.8 to 3.9% by weight, the concentration of the ionic iodide is maintained at not more than 13% by weight, the concentration of methyl iodide is maintained at not more than 13.9% by weight, and the concentration of methyl acetate is maintained at not less than 0.1% by weight, in a whole liquid phase in the reactor.

Acetic acid is produced while inhibiting increased concentrations of hydrogen iodide and acetic acid in an acetaldehyde distillation column.

A production process of acetic acid comprises a step for allowing methanol to react with carbon monoxide; a step for feeding a flasher with the reaction mixture to separate a volatile component (2A) and a low-volatile component (2B); a step for feeding a distillation column with the volatile component (2A), and separating an overhead (3A) containing methyl iodide, acetic acid, methyl acetate, water, acetaldehyde, and hydrogen iodide, and a stream (3B) containing acetic acid to collect acetic acid; and a separation step for feeding an acetaldehyde distillation column with at least part of the overhead (3A) and separating a liquid object to be treated containing the overhead (3A) into a lower boiling point component (4A) containing acetaldehyde and a higher boiling point component (4B); wherein, in the separation step, the liquid object contains methanol and/or dimethyl ether in a concentration of 0.1 to 50% by weight is subjected to distillation.

The invention relates to a formation method of a lithium ion secondary battery. The method comprises the following steps: performing a first formation on a battery containing a first electrolytic solution; and then injecting a second electrolytic solution into a battery container after the first formation to perform a second formation, wherein the first electrolytic solution contains an electrolyte and a first solvent which is mixture of a solvent A and a solvent B; the solvent A is ethylene carbonate, and the solvent B is one or more selected from dimethyl carbonate, diethyl carbonate, methylethyl carbonate, dimethyl sulfite and diethyl sulfite; and the second electrolytic solution contains electrolyte and a second solvent, and the second solvent is one or more selected from propylene carbonate, butylene carbonate, dimethoxyethane, gamma-butyrolactone, methyl formate, ethyl formate, methyl acetate, ethyl acetate, ethyl propionate, ethyl butyrate and propyl butyrate. The lithium ion secondary battery obtained by the method has excellent cycle performance and low-temperature multiplying factor discharge performance.

The invention provides a hydrolyzing and separation device of methyl acetate and a technique method thereof, which more particularly relates to a novel technique to catalyze and hydrolyze methyl acetate by a reaction bulkhead distillation tower, which can organically combine reaction process, product separation and recovery of no reactant into the tower. A separator extending from the upper part of the tower to the lower part of the tower is arranged on the vertical direction in the conventional distillation tower, the upper part of one side of which is covered and the other side of which is filled with a catalyst; therefore, the inner space of the reaction bulkhead distillation tower is divided into five regions with different functions. The hydrolyzing and separation device of methyl acetate can fully unleash the advantage of bulkhead tower and reaction distillation, and can cause hydrolysis reaction, product separation and recovery of non reactant to be realized in the same tower. The device provided by the invention and the technique process thereof can obtain the methyl acetate with 60 percent to 99.99 percent hydrolysis rate and products with high purity, restrain side effect effectively, reduce the volume of equipment markedly, simplify process, and reduce energy consumption and operation cost.

The invention relates o a universal adhesive and a preparation technology thereof. The universal adhesive is prepared by using the following raw materials in parts by weight: rubber, a tackifying resin, a hydrocarbon solvent, an ester solvent and a propellant; the preparation technology comprises the following steps of: firstly adding the barreled hydrocarbon solvent and the ester solvent to the stirred vessel through the compressed air of an air compressor, then successively adding the rubber, the tackifying resin and the other additives one by one to prepare a stock solution; and respectively charging the stock solution to iron tanks on an aerosol filling production line, sealing and then filling the propellant to obtain the product. When in use, the universal adhesive provided by the invention is rapid to operate and convenient to use; in addition, environment-friendly solvents such as methyl acetate and ethyl acetate are mainly adopted in the universal adhesive so that the universal adhesive is safer in use and environment-friendly; finally, the aerosol packaging form of the universal adhesive is firstly put forward; the universal adhesive has good packaging leak tightness and is long in the quality guarantee period; the rest of universal adhesive can be stored for long term after the universal adhesive is used, thereby the serious wasting of the universal adhesive is avoided; and the universal adhesive is in line with and abides by the standard requirements of energy saving, emission reduction and environmental protection.

The invention provides a method used for producing methyl acetate. According to the method, raw material gas containing alicyclic organic amine, dimethyl ether, carbonic oxide, and optionally selected hydrogen passes through a reaction reactor filled with a hydrogen-type mordenite molecular sieve catalyst so as to prepare methyl acetate, wherein the hydrogen-type mordenite molecular sieve catalyst is alicyclic organic amine absorbed hydrogen-type mordenite molecular sieve catalyst. According to the method, alicyclic organic amine absorbed hydrogen-type mordenite molecular sieve is taken as the catalyst, and alicyclic organic amine is added into the raw material gas, so that desorption of alicyclic organic amine in reaction processes can be made up stably, stability of the catalyst is increased, and service life of the catalyst is prolonged.

Provided in the present invention is a process for preparing methyl acetate through carbonylation of dimethyl ether, comprising: passing a feed gas containing dimethyl ether, carbon monoxide, and optional hydrogen gas through a reactor loaded with a mordenite molecular sieve catalyst, and preparing methyl acetate by reacting same at a reaction temperature of 19 to 320°C, a reaction pressure of 0.5 to 20.0 Mpa, and a gas volume space velocity of 500 to 5000 h-1; wherein the mordenite molecular sieve catalyst is a hydrogen-type mordenite molecular sieve catalyst with an adsorbed organic amine, the molar ratio of the dimethyl ether to carbon monoxide in the feed gas is DME/CO = 1/1 to 1/15, the molar ratio of the hydrogen gas to carbon monoxide is H2/CO = 0 to 10/1, and the dimethyl ether in the feed gas is charged into the reactor by means of feeding in stages. The present invention is characterized in that: through treatment by organic amine adsorption, the temperature distribution of catalyst bed can be effectively controlled so as to avoid the occurrence of hot points, and thereby side reactions are reduced, the selectivity of target product is improved, and the lifetime of the catalyst is greatly extended.

The invention provides a Cs-supported silica-based catalyst. One of SBA-15, SiO2 or silicon dioxide prepared by a silica sol method is used as a carrier, the support is selected from one of Cs salt and a mixture of Cs and modified elements, the catalyst is prepared by a dipping method, the Cs content is 0.1wt%-10wt%, and the content of the modified elements is 0-2wt%. Meanwhile, the invention further provides a preparation method of the Cs-supported silica-based catalyst and application of the Cs-supported silica-based catalyst to the process of preparing methyl acrylate by catalyzing condensation reaction of methyl acetate and a methanal gas phase. The prepared catalyst is capable of realizing the aldol condensation of the methyl acetate and the methanal gas phase under proper conditions so as to prepare the methyl acrylate, wherein the activity of the Cs/SBA-15 catalyst is higher than that of other Cs-supported silica-based catalysts, and the selectivity on the methyl acrylate is good.

The invention relates to a process for indirectly producing alcohol with synthetic gas. The process comprises the steps that the synthetic gas formed by mixing industrial carbon monoxide with hydrogen is taken as a raw material to synthesize methanol; methanol is dehydrated to prepare dimethyl ether; dimethyl ether, carbon monoxide and hydrogen are mixed for carbonylation reaction to prepare methyl acetate; methyl acetate is purified and hydrogenated; a hydrogenated product is purified; and an alcohol product is obtained. An adopted catalyst, the process and a device have the characteristics of high conversion per pass and high effective utilization rate of reaction heat; the load of separating a crude product is reduced greatly; the production flow is shortened; and the production energy consumption is reduced greatly.

A golf glove for increasing the flying distance of golf ball has an insert that provide a repulsion forces to the grip of a golf club when the head of the club impacts a golf ball. The insert is made of synthetic elastomer such as polyurethane, silicon rubber, EVA (Ethylene Vinyl Acetate copolymer, EMA (Ethylene Methyl Acetate copolymer), or EAA (Ethylene Acrylic Acetate copolymer). The insert has a planar shape that fits to the concave inner surface of human palm. The insert is firmly attached to the inner surface of the palm side of a golf glove.

The invention relates to a method for recycling acetic acid from diluted acetic acid, and aims at solving the problem that the recycling of acetic acid in the hydrolysis of furfural and methyl acetate as well as the Fischer-Tropsch combined production is difficult. The invention comprises the steps as follows: a) diluted acetic acid is extracted by a pulse filling extracting tower, the extractionphase containing extracting agent, the acetic acid and little water for the tower top is acquired, and the residual extraction phase of water containing micro acetic acid from the tower kettle is acquired; b) the extraction phase in an extracting agent recycling tower is conveyed; c) acetic acid 1 is fed into an azeotropic rectifying tower which utilizes one kind of benzene, cyclohexane, ethyl acetate, isopropyl acetate and butyl acetate as the extrainer, two-phase mixture of the extrainer and the water at a phase separator at the top of the tower is acquired, the water is extracted out from the tower top, and the retrainer returns into the tower. The utility model has the technical proposal of producing pure acetic acid at the tower top, solves the problems above, and adapts the industrial productions including recycling of acetic acid from wasted aldehyde water and extracting and refining acetic acid in the methyl acetate hydrolysis technique.

A carbonylation process for producing acetic acid including: (a) carbonylating methanol or its reactive derivatives in the presence of a Group VIII metal catalyst and methyl iodide promoter to produce a liquid reaction mixture including acetic acid, water, methyl acetate and methyl iodide; (b) feeding the liquid reaction mixture at a feed temperature to a flash vessel which is maintained at a reduced pressure; (c) heating the flash vessel while concurrently flashing the reaction mixture to produce a crude product vapor stream, wherein the reaction mixture is selected and the flow rate of the reaction mixture fed to the flash vessel as well as the amount of heat supplied to the flash vessel is controlled such that the temperature of the crude product vapor stream is maintained at a temperature less than 90° F. cooler than the feed temperature of the liquid reaction mixture to the flasher and the concentration of acetic acid in the crude product vapor stream is greater than 70% by weight of the crude product vapor stream.

The invention discloses a method for separating a methyl acetate-methanol mixture by ionic liquid intermittent extractive rectification, which is realized in a way that: a rectifier of an extractive rectification tower is adopted, an ionic liquid 1-ethyl-3-methyl imidazolyl acetate is used as an extractant, and the operation is carried out intermittently, so the top of the extractive rectification tower sequentially produces a methyl acetate product of which the mass content is up to 98-99.9%, a methyl acetate-methanol transitional fraction and methanol of which the mass content is 97-99%; and finally, the extractant of which the mass percent is 99% is left in the heating kettle. The invention has the following advantages: the extractant is adopted to enhance the relative volatility of the methyl acetate-methanol system, the purity of the separated methyl acetate product is high, and the ionic liquid used as the extractant is easy to recover and does not pollute the environment; and only one single tower needs to be operated, so that operation is flexible and the equipment investment is low.