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246 results about "Methyl formate" patented technology

Methyl formate, also called methyl methanoate, is the methyl ester of formic acid. The simplest example of an ester, it is a colorless liquid with an ethereal odour, high vapor pressure, and low surface tension. It is a precursor to many other compounds of commercial interest.

Efficient methanol preparation method based on biomass graded catalytic conversion and cycle coupling

The invention relates to the field of biomass energy and chemical industry, in particular to an efficient methanol preparation method based on biomass graded catalytic conversion and cycle coupling. The method comprises the following steps: in a graded catalytic oxidation reaction system, mixing a biomass raw material with a composite vanadium-based catalyst, water, oxygen and circulating methanol for reaction to generate a gas-liquid mixture containing methyl formate; recycling methyl formate by using a gradient variable-pressure rectification separation system; carrying out an interface hydrogenation reaction under the action of a copper-zinc-LTA hierarchical pore catalyst to generate methanol; finally, part of methanol is purified and recycled through membrane separation. The method realizes efficient conversion from biomass to methanol, has the advantages of mild reaction conditions, low energy consumption, high yield and good catalyst stability, and opens up a new path for industrialization of preparation of methanol from biomass.
Owner:BEIJING HEYUAN NEW MATERIAL TECHNOLOGY CO LTD

Yellowing-resistant PVB glue for laminated glass and preparation method of yellowing-resistant PVB glue

The invention discloses an anti-yellowing PVB (Polyvinyl Butyral) adhesive for laminated glass and a preparation method thereof, and relates to the technical field of adhesives. The yellowing-resistant PVB glue for the laminated glass has the advantages that the yellowing resistance is high; the modified PVB / nano silicon dioxide composite material is prepared from the following raw materials in parts by weight: 55 to 65 parts of modified PVB resin, 4 to 6 parts of modified nano silicon dioxide, 15 to 20 parts of dioctyl adipate, 0.5 to 1 part of a compound antioxidant, 0.3 to 0.8 part of an ultraviolet absorbent UV-327, 0.2 to 0.5 part of a silane coupling agent KH-560, 0.3 to 0.6 part of ethylene bis stearamide, 0.1 to 0.3 part of 2-benzimidazole methyl carbamate, 3 to 5 parts of tris (1-chloro-2-propyl) phosphate and 0.1 to 0.3 part of nano titanium dioxide. 5 to 8 parts of isopropanol; 0.8 to 1.2 parts of polycarbodiimide. The special modified PVB resin and the nano silicon dioxide are matched with the auxiliary agents such as the compound antioxidant, the anti-yellowing performance of the PVB glue for the laminated glass is remarkably improved through precise process preparation, the components have a synergistic effect, the process is controllable, the product performance is stable, and the cohesiveness is good.
Owner:NANTONG SHENGBAIWEI LOW CARBON TECHNOLOGY CO LTD

Preparation method of dicarbonyl cyclopentadienyl cobalt

The invention provides a preparation method of dicarbonyl cyclopentadienyl cobalt, which comprises the following steps: adding cobalt salt, a reducing agent, methyl formate and a catalyst into a high-pressure reaction kettle, keeping the reaction kettle in an inert gas atmosphere, and heating and stirring; cooling the high-pressure reaction kettle to room temperature, discharging gas, filtering reaction liquid, and putting filtrate into a normal-pressure reaction device in an inert gas atmosphere; and adding a cyclopentadiene monomer into the normal-pressure reaction device, carrying out heating reaction, filtering after the reaction is finished, and carrying out post-treatment on the obtained filtrate to obtain a dicarbonyl cyclopentadienyl cobalt crude product. The operation risk is reduced, the operation is simple, and the synthesis efficiency is high; cheap and easily available cobalt salt is used as a raw material, and a relatively cheap catalyst is used, so that the synthesis cost is low, and the method is suitable for industrial large-scale popularization and application.
Owner:SHANGHAI QINGJIANTING TECH CO LTD

High-flexibility PET decorative film and preparation method thereof

The invention discloses a high-flexibility PET decorative film and a preparation method thereof, and belongs to the technical field of PET decorative films. According to the high-flexibility PET decorative film, the self-made flame retardant and 1, 3-benzene-5-boric acid are pre-polymerized to obtain a prepolymer, then the prepolymer, ethylene glycol and terephthalic acid are mixed to react, and then (4-carboxyl-2-nitrophenyl) malonaldehyde is used for blocking to obtain flame-retardant PET. The preparation method comprises the following steps: carrying out a pre-mixing reaction on flame-retardant PET and a modified nucleating agent, internally mixing the pre-mixed material with an antioxidant and a lubricant, carrying out extrusion granulation, and carrying out melt extrusion, sheet casting, two-way stretching and heat setting by using a double-screw extruder to obtain a PET base film; and finally, plating aluminum on the PET base film. The self-made flame retardant is obtained by enabling amino siloxane and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide to react with each other; the modified nucleating agent is obtained by modifying calcium carbonate with glycine; the high-flexibility PET decorative film prepared by the invention has good flexibility, flame retardance and antistatic property.
Owner:JIANGSU SUNDERRAY LASER PACKAGING MATERIALS CO LTD

Low-temperature catalyst for preparing methyl formate through methanol dehydrogenation as well as preparation method and application of low-temperature catalyst

The invention relates to the technical field of catalyst materials and discloses a low-temperature catalyst for preparing methyl formate through methanol dehydrogenation as well as a preparation method and application of the low-temperature catalyst. The low-temperature catalyst comprises Cu nano-particles and a composite metal oxide attached outside the Cu nano-particles, the composite metal oxide comprises CaO and CeO2. When the low-temperature catalyst disclosed by the invention is used for catalyzing methanol dehydrogenation to prepare methyl formate, the reaction can be realized at a relatively low temperature, and the low-temperature catalyst has relatively high methyl formate selectivity.
Owner:ZHEJIANG BAIMA LAKE LABORATORY CO LTD

Heat pump assisted integrated extractive distillation separation method for diethyl ether-methyl formate-n-pentane azeotropic mixture

The continuous production heat pump assisted integrated extractive distillation device is adopted to realize high-purity separation and recovery of the diethyl ether-methyl formate-n-pentane azeotrope, and separation is realized by utilizing the characteristic that the extraction agent has great influence on the relative volatility of the diethyl ether-methyl formate-n-pentane azeotrope. The purity of the separated diethyl ether, n-pentane and methyl formate reaches 99.9% or above, high-purity recycling of the extraction agent can be achieved, the separation cost is greatly reduced, and the method is low in energy consumption and flexible to operate.
Owner:QINGDAO UNIV OF SCI & TECH

Corrosion-resistant thin film, pipe and preparation method and application of corrosion-resistant thin film and pipe

The invention provides a corrosion-resistant film, a pipe and a preparation method and application of the corrosion-resistant film, the corrosion-resistant film at least contains modified LCP, the modified LCP comprises p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid and 3, 4-dihydroxythiophene methyl diformate, the p-hydroxybenzoic acid, the 6-hydroxy-2-naphthoic acid and the 3, 4-dihydroxythiophene methyl diformate are used as raw materials, and the 6-hydroxy-2-naphthoic acid and the 3, 4-dihydroxythiophene methyl diformate are used as raw materials. And the molar ratio of the 2, 4-dihydroxy thiophene methyl dicarboxylate is (60-80): (5-40): (0.5-3). The corrosion-resistant thin film provided by the invention is excellent in mechanical property and corrosion resistance, and the corrosion-resistant pipe provided by the invention is high in combining capacity with the thin film and good in corrosion resistance.
Owner:ZHEJIANG YUANBANG MATERIAL TECH

Chalconamide alpha-glucosidase inhibitors, and methods of making and using the same

The present application relates to a kind of chalcone amide alpha-glucosidase inhibitors and its preparation and application, the inhibitor structural formula is: preparation method specifically is (1) after 2-hydroxyacetophenone, sodium hydroxide and methyl p-formylbenzoate are reacted, intermediate in formula (a) is obtained after post-processing;(2) intermediate in formula (a) is dissolved in organic solvent and potassium hydroxide is reacted, after reaction, intermediate in formula (b) is obtained after post-processing;(3) intermediate in formula (b) and substituted aniline are dissolved in organic solvent, after reaction, the inhibitor shown in formula (c) is obtained after post-processing.Compared with prior art, the compound of the present application is novel, and experiments show that it has good alpha-glucosidase inhibitory activity, and can be used for preparing alpha-glucosidase activity inhibiting drug.
Owner:SHANGHAI INST OF TECH

Thiophene-containing tetraarylethene compound as well as preparation method and application thereof

The invention relates to the technical field of organic synthesis, and particularly provides a thiophene-containing tetraarylethene compound as well as a preparation method and application thereof. According to the invention, two phenyl groups of tetraphenylethylene are replaced by methyl formate thiophene groups, and the substituted tetraarylethylene compound has more remarkable photochromic and mechanochromic dual functions through the interaction of a specific substituent group at the position 2 of thiophene and a large conjugated group formed by four aromatic rings; and light-operated double-color display in a polymer mechanism can be realized. The mechanochromism of the compound does not depend on ultraviolet light, when the compound is subjected to mechanical force, the molecular accumulation mode and conjugate planarity are changed, and the color change can be directly observed by naked eyes. Different from traditional tetraphenyl ethylene force-induced discoloration recessive fluorescence change, the dominant color change can be used in the fields of visual stress monitoring, anti-counterfeiting marks, inkless writing materials, safe ink and the like in ultraviolet-free environments (such as indoor and closed spaces), and the application prospect is wide.
Owner:HEBEI UNIV OF SCI & TECH

Synthesis method of (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate

The invention relates to the field of organic synthesis, in particular to a synthetic method of (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate. The synthesis method of (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate comprises the following steps: mixing a material A, a material B, potassium carbonate, sodium iodide and a solvent, and reacting to obtain a material C; mixing the material C, the material D, triethylamine and a solvent, and reacting to obtain a material E; mixing the material E, ammonia water and a solvent, and reacting to obtain a material F; and mixing the material F, di-tert-butyl dicarbonate, a palladium carbon catalyst and a solvent, and carrying out a reaction to obtain the (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate. The process route is easy to operate and has no special dangerous reaction. Reaction materials are cheap and easy to obtain, and the prepared product is high in purity.
Owner:TAIER BIOPHARMACEUTICAL TAIZHOU CO LTD

Foaming agent for extruded polystyrene foam, extruded polystyrene foam, and foaming method

The present invention provides a blowing agent for producing extruded polystyrene foam having low lambda over time and low foam density. [Solution] The foaming agent comprises (a) a first co-foaming agent consisting of (a) about 50% to about 70% by weight of HFO and / or HFCO having three or four carbon atoms, (b) about 2% to about 15% by weight of methyl formate, (c) a second co-foaming agent consisting of about 20% to about 30% by weight of dimethyl ether, isobutane and combinations thereof, and (d) a third co-foaming agent consisting of about 2% to about 25% by weight of carbon dioxide, acetone and combinations thereof.
Owner:SOLSTICE ADVANCED MATERIALS US INC

A high-impact material prepared by recycling polypropylene and its preparation method

ActiveCN119570160BPlastic recyclingChlorobenzeneThiothixene
The invention discloses a kind of recycling polypropylene to prepare high-impact material and preparation method thereof, relate to the field of materials. When the present invention uses recycling polypropylene to prepare high-impact material, first, polypropylene is grafted with vinyl diphenylphosphine, then reacted with 1-(3-chlorophenyl)-2-propyn-1-ol, and then reacted with 6-(methyl formate) pyridine-3-boric acid to obtain modified polypropylene; Secondly, calcium carbonate pretreated with 3-aminopropyltrimethoxysilane and 3-thiophene carboxaldehyde are reacted, and thiophene, 6-(thiophene-2-yl) pyridine-2-carboxylic acid, and 6-(3-thienyl) pyridine-2-carboxaldehyde are polymerized on the surface of calcium carbonate to obtain modified calcium carbonate; Finally, recycled polypropylene, modified polypropylene, modified calcium carbonate, sodium cyanide, and bismaleimide are melt-blended, and then extrusion granulation is performed to obtain high-impact material; The high-impact material prepared by the present invention has good impact resistance, anti-aging performance and antibacterial performance.
Owner:肇庆市合亚科技有限公司

Dual stimulus-responsive supramolecular gel temporary plugging agent and preparation method thereof

The invention discloses a dual stimulus-responsive supramolecular gel temporary plugging agent and a preparation method thereof, and relates to the technical field of oil-gas field development. The supramolecular gel temporary plugging agent comprises the following components in percentage by mass: 5wt%-10wt% of a tertiary amine surfactant; the temperature response authigenic acid accounts for 0.2 wt%-2wt%; and the balance of water. Wherein the tertiary amine surfactant is prepared by reacting fatty acid and N, N-dimethyl-1, 3-diaminopropane according to the molar ratio of 1: 1, and the temperature response authigenic acid is composed of methyl formate, ethyl formate, methyl acetate, ethyl acetate and the like; the dual-stimulus-responsive supramolecular gel temporary plugging agent disclosed by the invention has the plugging strength of 4.3 MPa, takes water as a solvent, and is simple in process, high in yield, strong in environmental protection property, stable in performance and low in cost.
Owner:SOUTHWEST PETROLEUM UNIV +1

(E)-1, 4-diether olefin and preparation method thereof

The invention discloses (E)-1, 4-diether olefin and a preparation method thereof, and the (E)-1, 4-diether olefin is obtained by using 1, 3-diene as a raw material and carrying out electrochemical reaction in the presence of an electrolyte and a solvent, wherein the 1, 2, 4-trimethyl-1, 3- The structural formula of the 1, 3-diene is as follows: R1 is phenyl, p-fluorophenyl, p-chlorphenyl, p-bromophenyl, p-methylphenyl, p-methoxyphenyl, p-trifluoromethylphenyl, p-trifluoromethoxyphenyl, p-acetoxyphenyl, p-methyl formate phenyl, p-cyanophenyl, p-pinacol borate phenyl, p-phenylphenyl, o-oxybenzyl phenyl and o-methoxyphenyl; r1 is one of 1, 2-naphthyl; the solvent is a mixed solvent containing methanol. The preparation method of (E)-1, 4-diether olefin has high E-selectivity and 1, 4-selectivity, and an electro-catalysis mode is adopted, so that the use of a stoichiometric toxic, expensive or dangerous oxidant is avoided.
Owner:HEFEI UNIV OF TECH

Method for preparing high-quality probiotic fermented strawberry juice based on magnetic field assistance

The present application belongs to the technical field of fermented fruit juice, and particularly relates to a method for preparing high-quality probiotic fermented strawberry juice based on magnetic field assistance. The present application first uses Lactobacillus plantarum CTCF-LP-1 to perform static fermentation on the strawberry juice to be fermented in a fermentation device for more than 24 hours, and then places the fermentation device in a static magnetic field. The static magnetic field reduces the generation of organic acid components by Lactobacillus plantarum during the fermentation process of the strawberry juice, reduces the acidity, and improves the fermentation quality of the strawberry juice. The magnetic field strength of the static magnetic field is 1.0-2.5 mT, and the fermentation time in the static magnetic field is 0.5-1.5 h. After the static fermentation and the magnetic field treatment, the content of malic acid, isocitric acid, glutaconic acid and other organic acid components in the fermented strawberry juice is significantly reduced, while the content of alcohol and ester components such as n-octanol, 2-phenylethanol, methyl benzoate, 3-hexyl hexanoate and butyl valerate is increased, the types of aroma components are more abundant, and the taste and quality of the strawberry juice are significantly improved.
Owner:JINAN INST OF FRUIT PRODS CHINA GENERAL SUPPLY & MARKETING COOP

Methyl 5-(methoxycarbonyl)-2-oxy-1, 3-dioxacyclopentane-4-formate and preparation method of methyl 5-(methoxycarbonyl)-2-oxy-1, 3-dioxacyclopentane-4-formate

The preparation method comprises the following steps: 1, adding tartaric acid, an acid-binding agent and a first organic solvent into a reaction container, uniformly mixing, cooling, dropwise adding a mixed solution of triphosgene and the first solvent into the reaction container under the condition that the temperature does not exceed 10 DEG C, and reacting for 1-2 hours at the temperature of 20-30 DEG C, so as to obtain 5-(methoxycarbonyl)-2-oxo-1, 3-dioxolane-4-methyl formate, namely the 5-(methoxycarbonyl)-2-oxo-1, 3-dioxolane-4-methyl formate, namely the 5-(methoxycarbonyl)-2-oxo-1, 3-dioxolane-4-methyl formate. After dropwise adding, heating to room temperature, stirring, and concentrating filtrate to obtain an intermediate; and 2, adding the intermediate, a second organic solvent, a catalyst and methanol into a reflux reaction container with a water knockout drum and a condenser, carrying out heating reflux reaction to separate water, concentrating the reaction liquid after the reaction is finished to obtain a crude product, adding the crude product into a first organic solvent, carrying out heating reflux, filtering to remove insoluble substances while the crude product is hot, cooling and crystallizing the filtrate, carrying out suction filtration, and drying to obtain the target product. The method has the advantages that the synthesis method is simple and easy to implement, the post-treatment method is easy to operate, and the product is high in purity and good in yield.
Owner:NINGDE GUOTAI HUARONG NEW MATERIAL CO LTD

A process for the preparation of methyl 2-pyrimidinecarboxylate

The application discloses a preparation method of 2-pyrimidine methyl formate. The application provides a preparation method of 2-pyrimidine methyl formate, which comprises the following steps: step (1), 2-cyanopyrimidine and methanol are reacted in the presence of water and acid; and step (2), a dehydrating agent is added into the reaction solution in step (1) to prepare 2-pyrimidine methyl formate. The preparation method has one or more advantages of simple operation, high yield, high purity, low cost and suitability for industrial production.
Owner:上海药坦药物研究开发有限公司

Electrolyte for lithium ion capacitor and preparation method thereof

The invention relates to the technical field of electrolyte, in particular to electrolyte for a lithium ion capacitor and a preparation method of the electrolyte. The electrolyte for the lithium ion capacitor comprises the following preparation raw materials: 50 to 55 parts of ethylene carbonate, 30 to 35 parts of methyl cyclohexylformate, 8 to 10 parts of siloxane solvent, 20 to 25 parts of lithium salt, 0.5 to 0.8 part of bis (trifluoromethanesulfonyl) imine, 2 to 5 parts of quaternary ammonium salt and 2 to 2.5 parts of functional additive. The electrolyte for the lithium ion capacitor prepared by the invention has excellent low-temperature performance, high power characteristic, wide temperature range adaptability, long cycle life and safety by optimizing the solvent system, the lithium salt ratio and the synergistic effect of the multifunctional additive, and is suitable for the high-performance lithium ion capacitor.
Owner:FUZHIQING ELECTRONICS (SHENZHEN) CO LTD

Dispersion agent as well as preparation method and application thereof

The invention relates to the technical field of dispergators, and discloses a dispergator and a preparation method and application thereof, the dispergator comprises the following components by mass: 50-100 parts of a penetrant, 50-100 parts of a swelling agent, 10-20 parts of a dispersant, 0.1-1 part of a surfactant A, 0.1-1 part of a surfactant B, and 1-5 parts of a catalyst; the penetrant is composed of methyl formate, ethanol, ethyl acetate, acetone and dichloromethane; the swelling agent is prepared from N-methyl pyrrolidone, dimethyl sulfoxide, tetrahydrofuran, N, N-dimethyl formamide, N, N-dimethyl acetamide, hexamethylphosphoric triamide and xylene. By compounding the penetrating agent, the swelling agent, the dispersing agent, the surfactant and the catalyst, the obtained dispergator can decompose an epoxy resin adhesive at a higher dispergation speed in the process of disassembling the retired battery pack.
Owner:SOUTH CHINA UNIV OF TECH

A heat-insulating and high-temperature-resistant polyurethane rigid foam material and a low-temperature preparation method thereof

ActiveCN120349496BImidePolymer science
This invention discloses a heat-insulating, high-temperature-resistant polyurethane rigid foam material and its low-temperature preparation method, which relates to the field of polyurethane foam materials. Bismaleimide powder is liquefied and dispersed in a polyol through a DA reaction. Lewis acid catalysis shortens the reaction time and is reused as a foaming catalyst. Combined with the excellent high- and low-temperature performance of the polyol, a thermoreversible DA adduct is introduced to achieve endothermic temperature control during the foaming process and low-temperature reconstruction of a rigid cross-linked structure. A low-boiling point primary foaming agent is compounded with methyl formate to reduce the heat of vaporization and system viscosity, and the A / B material preparation temperature is controlled to ≤15°C to avoid foaming agent loss. This solution solves the problems of powder dispersion, viscosity control, and foaming stability at low temperatures, imparting excellent heat-insulating and high-temperature-resistant foam properties.
Owner:CHINA AEROSPACE TECHNOLOGY GROUP COMMERCIAL ROCKET CO LTD

Synthesis method of (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate

The invention relates to the field of organic synthesis, in particular to a synthetic method of (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate. The synthesis method of (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate comprises the following steps: mixing a material A, a material B, potassium carbonate, sodium iodide and a solvent, and reacting to obtain a material C; mixing the material C, the material D, triethylamine and a solvent, and reacting to obtain a material E; mixing the material E, ammonia water and a solvent, and reacting to obtain a material F; and mixing the material F, di-tert-butyl dicarbonate, a palladium carbon catalyst and a solvent, and carrying out a reaction to obtain the (2R, 4S)-N-BOC-4-hydroxypiperidine-2-methyl formate. The process route is easy to operate and has no special dangerous reaction. Reaction materials are cheap and easy to obtain, and the prepared product is high in purity.
Owner:TAIER BIOPHARMACEUTICAL TAIZHOU CO LTD

Forsythia flower fragrance composition

ActiveJP2026111403AEthyl salicylateBenzoic acid
The objective is to provide a fragrance composition that has high reproducibility of the fragrance of forsythia flowers and excellent palatability. [Solution] The forsythia flower fragrance composition comprises (A) methyl salicylate and / or ethyl salicylate, (B) methyl benzoate and / or ethyl benzoate, and (C) linalool and / or limonene, wherein the total content of component (A) and component (B) is 50 to 90% by mass, and the mass ratio (A / B) is 1 to 10.
Owner:KRACIE CO LTD

Catalyst and process for preparing methyl glycolate and co-producing methyl formate through methanol dehydrogenation coupling oxalate hydrogenation

The invention relates to the technical field of organic chemical synthesis, in particular to a catalyst and a process for preparing methyl glycolate and co-producing methyl formate through methanol dehydrogenation coupling oxalate hydrogenation, which comprises the following steps: S1) providing a coal-to-ethylene glycol device which comprises a methanol rectifying tower, a DMO synthesis system, a DMO refining system, a DMO hydrogenation reactor and a condensing system; s2) taking methanol extracted from a methanol rectifying tower as a raw material, and carrying out anaerobic dehydrogenation reaction under the action of the catalyst in any one of claims 1-2 or the catalyst prepared by the preparation method in claim 3 to obtain methyl formate, H2 and CO; and S3) by taking dimethyl oxalate extracted from a DMO refining system as a raw material, carrying out hydrogenation reaction under the action of the catalyst in any one of claims 4-5 or the catalyst prepared by the preparation method in claim 6 to obtain methyl glycolate and methanol.
Owner:EAST CHINA ENGINEERING SCIENCE AND TECHNOLOGY CO LTD +1

Dithiocarbamate nickel (II) complex as well as preparation method and application thereof

The invention discloses a dithiocarbamate nickel (II) complex as well as a preparation method and application thereof, the chemical formula of the nickel (II) complex is [NiIILCl], and L is (E)-2-(phenyl (pyridine-2-yl) methylene) hydrazino methyl dithioformate. The nickel (II) complex is mild in synthesis condition and high in target yield. In-vitro MTT activity evaluation proves that the introduction of copper ions has a synergistic effect on the anticancer activity of the nickel (II) complex, so that the activity of the nickel (II) complex is improved from a micromole level to a nanomole level, and the amplification is as high as 200 times or more. Cell scratch experiments prove that the nickel (II) complex and copper (II) ions are combined for use, so that the migration resistance is achieved. A nickel (II) complex and copper ion combination strategy provided by the invention not only has a direct killing effect on cancer cells, but also can effectively inhibit the migration ability of the cancer cells, and shows huge application potential in the field of cancer treatment.
Owner:AFFILIATED HOSPITAL OF GUILIN MEDICAL UNIV

Carbon monoxide gas pretreatment and impurity removal equipment for industrial methyl formate preparation

The invention relates to the technical field of industrial methyl formate preparation, and particularly discloses carbon monoxide gas pretreatment and impurity removal equipment for industrial methyl formate preparation, the side face of a tower body is fixedly connected with a feeding component, the top of the tower body is fixedly connected with an exhaust port, the inner side of the tower body is fixedly connected with a spraying component, and the spraying component is fixedly connected with a gas outlet. The side face of the spraying part is fixedly connected with a water pipe. The carbon monoxide gas pretreatment and impurity removal equipment for industrial methyl formate preparation is provided with a contact mechanism, an arc-shaped contact plate is attached to the inner wall for cleaning, impurities are prevented from being attached and gathered on the tower body, the stable spraying and impurity removal efficiency is guaranteed, a second spring buffer structure can resolve overlarge extrusion force, the contact plate is prevented from rubbing the inner wall of the tower body, and the service life of the tower body is prolonged. The service life of equipment is prolonged, the cleaning range is complemented in the reset process of the triangular scraping plate, the blind area problem caused when a single contact plate moves downwards is solved, and inner wall cleaning under all working conditions is achieved.
Owner:SUQIAN XINYA TECH

Process for producing biomonomers and precursors for biomonomers

The invention relates to a method for producing a biomonomer and a precursor for the biomonomer. A furoate carboxylation reaction is carried out with particles formed from a furoate and a base, and optionally a reaction accelerator. The particles may be in a slurry. The particles are exposed to gaseous carbon dioxide and heated. The reaction produces dicarboxylic acid esters that can be isolated and used to produce biomonomers, such as methyl furandicarboxylate and furandicarboxylic acid.
Owner:UOP LLC

Flotation collecting agent and preparation method and application thereof

ActiveCN120268566AFlotationMethyl carbamateOre concentrate
The invention discloses a flotation collecting agent and a preparation method and application thereof, and relates to the technical field of mineral separation. The flotation collecting agent comprises carbonized methyl carbamate, zinc diethyldithiocarbamate, butyl octanol and sulfate according to the mass ratio of (3-6): (1-12): (2-3): (3-8). According to the prepared composite flotation reagent, in the cassiterite ore flotation treatment process, after one-time roughing, three-time scavenging and three-time concentration, the loss of easily-argillized fine-grain and micro-fine-grain cassiterite in tailings is reduced, the cassiterite content in cassiterite ore is reduced through precise adsorption of the reagent, efficient recovery of the fine-grain and micro-fine-grain cassiterite is achieved, and the cassiterite flotation efficiency is improved. The effective recovery of cassiterite is improved, and the tin grade and the recovery rate in the tin concentrate are also remarkably improved.
Owner:CHINA UNIV OF MINING & TECH (BEIJING)

Preparation of p2x3 antagonist

Described herein are processes for the synthesis of P2X3 antagonists, wherein the P2X3 antagonist is methyl (S)-2-((2-(2,6-difluoro-4-(methylcarbamoyl)phenyl)-7-methylimidazo[1,2-a]pyridin-3-yl)methyl)morpholine-4-carboxylate (Compound 1), or a pharmaceutically acceptable salt or co-crystal thereof.
Owner:GLAXOSMITHKLINE INTELLECTUAL PROPERTY (NO 3) LIMITED

A heteropolyacid catalyst and its preparation and application

This invention relates to a heteropolyacid catalyst for the condensation of formaldehyde and methyl formate to methyl glycolate, the preparation method of which includes the following steps: (1) loading the active component and (2) overflow hydrogen reduction. This invention uses common silica as a support and employs a co-impregnation method to load the active component to prepare the catalyst, under mild conditions and with a stable and controllable process. By doping with an appropriate amount of metal, overflow hydrogen is induced to reduce some coordinating atoms in the heteropolyacid as basic sites, which synergistically interact with the strongly acidic sites of the heteropolyacid to promote the cross-condensation of formaldehyde and methyl formate, thereby improving the reaction activity and selectivity. The prepared catalyst has advantages such as low reaction temperature, high activity, and good selectivity.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Method for preparing long-chain olefin and co-producing fatty aldehyde and formic acid from fatty acid methyl ester

The invention belongs to the technical field of fatty acid methyl ester conversion, and discloses a method for preparing long-chain alpha-olefin and co-producing fatty aldehyde and formic acid from fatty acid methyl ester. The method comprises the following steps: carrying out hydrogenation reaction on fatty acid methyl ester to generate fatty alcohol and methanol; carrying out dehydration / dehydrogenation reaction on the fatty alcohol to obtain long-chain alpha-olefin, fatty aldehyde, water and hydrogen; carrying out dehydrogenation reaction on the methanol to generate methyl formate and hydrogen; carrying out hydrolysis reaction on the methyl formate to obtain formic acid and methanol; wherein the catalyst used in the dehydration / dehydrogenation reaction of the fatty alcohol comprises a dehydrogenation active site, a dehydration active site, a dispersing aid and a carrier; the dispersity of the dehydrogenation active site is greater than 31.0%; the concentration of the dehydration active site is 4.5 to 9.0 [mu] mol / g. Three high-added-value products of long-chain alpha-olefin, fatty aldehyde and formic acid can be simultaneously produced by using the single raw material fatty acid methyl ester, the comprehensive utilization rate of byproducts in the process is high, zero discharge of wastewater in the process is realized, and balanced utilization of the raw material and the products is achieved.
Owner:SICHUAN LUTIANHUA +1