Metal carrier loaded catalyst for purifying formaldehyde at room temperature

A metal carrier, formaldehyde purification technology, applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, gas treatment, etc., can solve the problem of unstable catalyst activity, low mechanical resistance of catalysts, powder falling And other issues

Inactive Publication Date: 2013-02-27
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the catalyst using cordierite honeycomb ceramics as a carrier has the problem of weak bonding strength between the carrier and the active component during use. Especially during long-term use, the catalyst has low mechanical resistance and serious powder shedding, which leads to catalyst Long-term activity instability
In addition, the catalyst with cordierite honeycomb ceramics as the carrier has high wind resistance and low catalytic efficiency during the air purification process, and the energy consumption caused by assembling the purification equipment is high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A catalyst supported by a metal carrier for room temperature formaldehyde purification, the catalyst is composed of a metal carrier, a porous inorganic oxide loaded on the metal carrier, a noble metal active component and an auxiliary agent loaded on the porous inorganic oxide, the The metal carrier is iron-chromium-aluminum alloy, the noble metal active component is palladium oxide, and the auxiliary agent is sodium carbonate.

[0044] Taking the weight of the catalyst as 100%, palladium oxide is based on the weight of palladium element, and the weight percentage of palladium oxide is 0.1%; Taking the weight of the catalyst as 100%, sodium carbonate is based on the weight of sodium element, and the weight percent of sodium carbonate is 30% %.

Embodiment 2

[0046] A catalyst supported by a metal carrier for room temperature formaldehyde purification, the catalyst is composed of a metal carrier, a porous inorganic oxide loaded on the metal carrier, a noble metal active component and an auxiliary agent loaded on the porous inorganic oxide, the The metal carrier is iron-chromium-aluminum alloy, the noble metal active component is rhodium oxide, and the auxiliary agent is potassium chloride.

[0047] Taking the weight of the catalyst as 100%, rhodium oxide is based on the weight of rhodium element, and the weight percentage of rhodium oxide is 10%; taking the weight of the catalyst as 100%, potassium chloride is based on the weight of potassium element, and the weight percentage of potassium chloride is 0.2%.

Embodiment 3

[0049] A catalyst supported by a metal carrier for room temperature formaldehyde purification, the catalyst is composed of a metal carrier, a porous carbon material loaded on the metal carrier, a noble metal active component and an auxiliary agent loaded on the porous carbon material, the The metal carrier is iron-chromium-aluminum alloy, the noble metal active components are AgCl and gold, and the additives are sodium carbonate and cesium carbonate.

[0050] Based on the weight of the catalyst as 100%, AgCl and gold are based on the weight of Ag and gold elements, and the weight percentage of AgCl and gold is 5%; based on the weight of the catalyst as 100%, sodium carbonate and cesium carbonate are based on the weight of sodium and cesium elements Calculated, the weight percent of sodium carbonate and cesium carbonate is 15%.

[0051] Get 60mg of catalyst described in embodiment 1-3 respectively, be placed in the tube-type fixed-bed reactor and carry out experiment, experimen...

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PUM

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Abstract

The invention relates to a metal carrier loaded catalyst for purifying formaldehyde at a room temperature. The catalyst comprises a metal carrier, porous inorganic material loaded on the metal carrier, noble metal active components loaded on the porous inorganic material and an additive, wherein the metal carrier is aludirome, the noble metal is any one or a mixture of at least two of platinum, rhodium, palladium, gold or silver and the additive is any one or a mixture of at least two of alkali metal simple substance, alkali metal compound, alkaline earth metal simple substance or alkaline earth metal compound. By the metal carrier load catalyst for purifying formaldehyde at the room temperature, most or all formaldehyde can be converted into carbon dioxide and water; by-products such as formic acid, carbon monoxide and methyl formate are not generated; and the formaldehyde conversion rate can be up to 100%.

Description

technical field [0001] The invention relates to a catalyst, in particular to a metal carrier-loaded catalyst used for purifying formaldehyde at room temperature. Background technique [0002] With the improvement of people's material and cultural living standards, interior decoration has become fashionable, but indoor air pollution is also becoming more and more serious. Formaldehyde is one of the most typical and serious pollutants in the indoor environment. The concentration limit of formaldehyde pollutants in indoor air stipulated by my country's national standards is 0.08mg / m 3 . At present, the concentration of formaldehyde in the indoor environment in my country is very serious. According to the sampling survey conducted by the National Center for Disease Control and Prevention, more than 60% of newly renovated residential buildings in my country have excessive formaldehyde concentrations, which has caused great harm to people's health. With the improvement of envir...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/232B01J27/132B01D53/86B01D53/72
CPCB01D53/72B01J23/58B01D53/86B01D53/8668B01D2255/1023B01D2255/1025B01D2255/104B01D2255/106B01D2255/202B01D2255/2022B01D2255/2027B01D2257/708
Inventor 贺泓张长斌王少莘
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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