The invention relates to a method for recovering
tin by mixed reduction
roasting of crystalline miscellaneous salt and
tin-containing iron concentrate, and belongs to the technical field of comprehensive
resource utilization. The invention grinds the
tin-containing iron concentrate and the crystalline miscellaneous salt to a particle size of less than 40 meshes to obtain tin-containing iron concentrate
powder and crystalline miscellaneous salt
powder, mixes the tin-containing iron concentrate
powder and the crystalline miscellaneous salt powder to obtain a mixed powder, wherein the main components of the crystalline miscellaneous salt are
sodium sulfate and
sodium chloride; adds a
reducing agent to the mixed powder or the
granulation of the mixed powder, mixes evenly, heats to the
roasting temperature and roasts at a constant temperature to generate high-temperature
flue gas, and the high-temperature
flue gas is recycled by a
dust collection system to recover tin-containing
smoke dust, and the dust-removed
smoke is discharged into the
atmosphere after washing to remove harmful gases. SO2 and HCl generated by the reduction and
decomposition of the Na2SO4 component in the crystalline miscellaneous salt of the invention realize
sulfidation and chlorination of tin in the tin-iron concentrate, converts tin into SnS and SnCl2, and utilizes the volatilization of SnS and SnCl2 to realize efficient recycling of tin resources therein through dust collection, and simultaneously realizes resource disposal of the crystalline miscellaneous salt.