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180results about How to "Reduce copper content" patented technology

Method for recovering copper from alkaline etching waste liquid and recycling alkaline etching liquid

InactiveCN102019430AIncrease profitImprove copper yieldRecovery methodHydrazine compound
The invention discloses a method for recovering copper from alkaline etching waste liquid and recycling the alkaline etching liquid, comprising the step of adding a hydrazine hydrate reducing agent and a catalyst into the alkaline etching waste liquid to recover copper powder, wherein the alkaline etching waste liquid can be recycled after the copper powder is recovered. The invention has the optimum conditions of: placing the alkaline etching waste liquid into a reactor; adding hydrazine hydrate with mass percent concentration of 40 percent according to added quantity of 160-200mL / L; adding a solution of various salts of ruthenium, palladium, nickel and cobalt as the catalyst with added quantity of 0.01-0.2g / L (metered by the masses of the ruthenium, the palladium, the nickel and the cobalt), reacting for 30-35 minutes at temperature between 70DEG C and 100DEG C; and separating to obtain the copper powder. The invention has the beneficial effect that after the copper is recovered from the alkaline etching waste liquid, the alkaline etching waste liquid can be regenerated and recycled, therefore, various resources in the alkaline etching waste liquid can be used fully, and the etching cost of a printing plate and the discharge of pollutants can be reduced.
Owner:FUQING BRANCH OF FUJIAN NORMAL UNIV

Dilution treatment method for copper smelting slag

The invention provides a dilution treatment method for copper smelting slag. The dilution treatment method includes the technological steps that firstly, a mechanical stirring device is introduced into a dilution furnace, the high-temperature molten state copper smelting slag at the temperature ranging from 1150 DEG C to 1350 DEG C is guided into the dilution furnace, a stirring paddle is adjusted to stretch to the part from the 1/3 position of the liquid level of the copper smelting slag to the 1/2 position of the liquid level of the copper smelting slag, heating and stirring are started, the temperature of the copper smelting slag is controlled to range from 1200 DEG C to 1350 DEG C, the stirring speed ranges from 50 r/min to 200 r/min, and a vortex with the diameter height ratio ranging from 0.5 to 3 is formed; secondly, a vulcanizing agent is carried through carrier gas and injected to the position, close to the center of the vortex, of the surface of a copper smelting slag pool through a nozzle above the liquid level of the high-temperature molten state copper smelting slag, the adding amount of the vulcanizing agent is 0.3-8% of the mass of the copper smelting slag, and heat-preservation stirring is conducted for 10-60 min; and thirdly, standing layering is conducted, and copper matte on the lower layer and diluted slag on the upper layer are collected. The copper content of the diluted slag obtained after treatment is below 0.3%.
Owner:NORTHEASTERN UNIV

Process of efficiently recovering copper from lead matte according to oxygen pressure acid leaching and vortex electrolysis techniques

The invention belongs to the field of nonferrous metal hydrometallurgy and discloses a process of efficiently recovering copper from lead matte according to oxygen pressure acid leaching and vortex electrolysis techniques. The method includes: taking lead matte as a raw material, crushing and grinding the lead matte, screening through a 100-mesh sieve, adding into a high-pressure autoclave along with sulfuric acid and a dispersing agent, feeding oxygen for leaching, carrying out liquid-solid separation to obtain solution containing copper sulfate, subjecting the solution containing copper sulfate to vortex electrolytic decopperation to obtain cathode copper, and returning after-electrodeposition liquid to the leaching procedure to replace sulfuric acid serving as the leaching agent. High efficiency in copper recycling can be realized, electrodeposition of copper can be selectively carried out according to the vortex electrolysis techniques, and high current level and current efficiency, low reagent consumption, reduction of production cost and improvement of enterprise benefits are realized. In addition, due to closed cycle of solution, harmful gas emission is avoided, and current concepts of circular economy and environment protection are met.
Owner:XIANGNAN UNIV +1

Method for depleting refining slag of copper

The invention discloses a method for depleting refining slag of copper. The method comprises the following steps of: adding recovered waste copper into a reverberatory furnace, heating and melting, inserting a blast pipe into molten copper to blow air, and stirring for oxidization with blasting to ensure that impurities are oxidized and partial copper is oxidized into cuprous oxide; taking a molten copper sample for observation, and adding quartz sand in an amount which is 1.2 to 1.4 percent of the weight of the total charging material for slagging when the section is brick red so as to ensure that the oxidized impurities in the molten copper such as Fe, Pb, Sn and the like and quartz react to form silicate slag; covering a carbonaceous reducing agent in an amount which is 0.13 to 0.17 percent of the total amount of the charged waste copper on the slag, inserting the blast pipe into the molten copper to blow the air, and stirring for 5 to 10 minutes, wherein a considerable amount of copper which enters a slag phase is reduced and enters a molten copper phase because copper is reduced more easily than other impurity elements. About 35 percent of copper content in the slag is reduced, and the method is favorable for recycling reclaimed copper resources. The production process is easy to operate, and the conventional production equipment can be directly utilized.
Owner:NINGBO JINTIAN SMELTING +1

Submerged arc welding wire for superstrength pipeline steel and production method thereof

The invention relates to a submerged arc welding wire for superstrength pipeline steel and a production method thereof. The technical scheme is that: the submerged arc welding wire comprises the following components in percentage by weight: 0.04 to 0.06 percent of C, 1.40 to 2.00 percent of Mn, 0.70 to 1.10 percent of Mo, 2.00 to 2.60 percent of Ni, 0.80 to 1.20 percent of Cr, 0.10 to 0.30 percent of Cu, less than or equal to 0.0005 percent of B, less than or equal to 0.01 percent of S, less than or equal to 0.01 percent of P and the balance of Fe and inevitable impurities. The production method comprises the following steps of: adding 0.01 to 0.5 weight percent of composite additive when the components are smelted, forming a square billet in a pouring way, hot-rolling the square billet to form a steel wire rod with the diameter of Phi 5.5 to Phi 7.5mm, removing oxide skin from a surface, drawing the steel wire rod to form the welding wire with the diameter of Phi 3.2 to Phi 4.0mm and performing copper plating, wherein the composite additive is added in form of cored wire. The welding wire produced by the method is welded together with an SJ105 welding flux so as to achieve the tensile strength sigmab of more than or equal to 910MPa and the impact toughness Akv at -30 DEG C of more than or equal to 84J of a weld metal, and is suitable for the submerged arc welding of X120 pipeline steel with superstrength.
Owner:WUHAN UNIV OF SCI & TECH

Brass alloy coverage slag removal agent and preparation method thereof

The invention provides a brass alloy coverage slag removal agent and a preparation method thereof. The brass alloy coverage slag removal agent is characterized by comprising following components in percent by mass: 10-20% of a chloride, 20-30% of a fluoride, 10-15% of charcoal dust and the balance of a carbonate. The preparation method of the brass alloy coverage slag removal agent comprises the following steps: burdening by means of putting the components from a large ratio to a small ratio; mixing and uniformly stirring; secondly, drying a mixture and controlling a water content within a range of 0.5%; finally, grinding the dried materials in a powder manner, and controlling the particle size of the powder within a range of 80 meshes. The brass alloy coverage slag removal agent provided by the invention has the advantages of good spreading property, coverage property, separation property and purification property and good effect of slag removal. Not only can slag of a furnace wall and a furnace bottom be removed in a furnace cleaning process by using a manual sprinkling and stirring method, but also the brass alloy coverage slag removal agent can be directly and uniformly sprinkled to the surface of a brass alloy molten body. Compared with the traditional slag removal agent, the additive amount of the slag removal agent provided by the invention is only 0.3-0.5% of a processing amount of brass, so that the copper content in the furnace slag can be effectively reduced, and the gas removal and coverage effects can be realized.
Owner:JINTIAN COPPER GROUP CORP NINGBO

Smelting furnace for continuously smelting blister copper through copper sulfide concentrate and smelting method of smelting furnace

The invention provides a smelting furnace for continuously smelting blister copper through copper sulfide concentrate and a smelting method of the smelting furnace. The smelting furnace is an integrated metallurgical furnace with the front-end top-blown smelting function, the middle electric furnace setting function and the tail-end matte continuous converting function and comprises a front-end top-blown smelting furnace, a middle setting electric furnace and a tail-end matte continuous converting furnace with the bottoms communicated sequentially. According to the smelting method, the procedures that the copper sulfide concentrate is continuously smelted into mixed melt of matte and slag through the converting furnace, settling separation of the matte and the slag is performed continuously, and the matte is continuously blown into blister copper are not needed. The three metallurgical processes that the copper sulfide concentrate is smelted into the mixed melt of the matte and the slag, settling separation of the matte and the slag is performed, and the matte is continuously blown into the blister copper can be continuously finished, the equipment structure and the operation process are simple, energy consumption is low, and environmental friendliness and safety are achieved.
Owner:YUNNAN TIN

Two-level copper removing technology for treating low-concentration comprehensive wastewater in PCB electroplating

The invention discloses a two-level copper removing technology for treating low-concentration comprehensive wastewater in PCB electroplating. The two-level copper removing technology comprises a two-level copper removing process: hydrated copper ions in wastewater are removed in a primary cooper removing process; complex cooper irons are removed in a secondary cooper removing process. The two-level copper removing technology specifically comprises the following steps: after being lifted, the wastewater enters a pH adjustment tank; through pumping, an alkaline chemical agent is added to control the pH value of the wastewater to be 8.5-9; the adjusted wastewater I enters a quick mixing tank and a slow mixing tank in sequence; clear water obtained through primary precipitation is lifted through pumping and enters a complex breaking tank; a proper amount of ferrous sulfate is added for complex breaking; the pH value of the primarily treated wastewater is adjusted to be 8-9; the adjusted wastewater II enters the quick mixing tank and the slow mixing tank in sequence; the wastewater subjected to secondary precipitation enters a pH call-back tank for biochemical treatment; the standard wastewater is discharged. The two-level copper removing technology has the advantages that the chemical agent treatment cost is reduced, the discharged water quality is stabilized, the sludge minimization and the recovery value resource utilization are facilitated, and a high popularization value is achieved for wastewater treatment in the conventional PCB industry.
Owner:湖南景翌湘台环保高新技术开发有限公司

Method for reducing gold extraction residual liquid

The invention discloses a method for reducing gold extraction residual liquid, and relates to a process for separating platinum palladium and other metals from the gold extraction residual liquid by using sodium hydrogen sulfite and settling zinc magnesium powder to separate rhodium iridium and base metals; after the acidity of the gold extraction residual liquid is adjusted, the sodium hydrogen sulfite is reduced; the zinc magnetism powder is settled through once reducing liquid; and rhodium refining and iridium refining are respectively performed for produced rhodium iridium slag after the separation of rhodium and iridium to generate rhodium powder and iridium powder accordant with the national standards. The method is simple in process flow, convenient for operation and reasonable in procedure joint. The method can enable the copper content in the subsequently produce once reducing liquid to largely reduce; the platinum and palladium settling rates are both higher than 99%; the once reducing liquid is prepared to secondary reducing liquid by the replacement of zinc magnesium powder; the settling rates of noble metals in the secondary reducing process are higher than 99.95%; the rhodium iridium slag weight generated by secondary reduction is reduced by above 65% compared with a traditional process; the method can shorten the process flow of rhodium and iridium refining; and the product pass percent is largely increased.
Owner:JINCHUAN GROUP LIMITED
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