The invention belongs to the technical field of preparation of green
hydrogen by electrolyzing water, and discloses a
molybdenum disulfide loaded
platinum nanoparticle composite
electrocatalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving
ammonium molybdate,
thiourea and
polyvinylpyrrolidone in deionized water, and carrying out heat treatment to obtain MoS2; and adding a Na2 [PtCl6]. 6H2O
aqueous solution into the dispersion liquid of MoS2, and carrying out annealing treatment to obtain the
molybdenum disulfide loaded Pt particle composite
electrocatalyst. Wherein the
molybdenum disulfide nanosheets are of a vertical arrangement structure and have abundant edge
sulfur sites, and the high-activity edge
sulfur sites and Pt particles have a synergistic effect, so that the reaction potential barrier of water molecule dissociation is effectively reduced. Meanwhile, the
generation rate of
hydrogen is increased through the active
sulfur sites. The
overpotential of the material is only 35 mV under the
current density of 10 mA cm <-2 >, and the material can stably operate for more than 110 h under the
current density of 20 mA cm <-2 >. By combining
metal active sites and high-activity non-
metal sites, dissociation of water molecules and generation of
hydrogen are promoted, and the
hydrogen evolution reaction performance in an alkaline medium is remarkably improved.