The invention relates to a positive flotation method of low grade
refractory phosphate ores. The method comprises the following specific steps: 1. crushing and
grinding ores:
grinding raw ore according to the
grinding density of 1:1 to -0.074mm of 55-60%
tailings discarding
fineness; 2. performing positive flotation: firstly, roughing, namely adding
depressant sodium carbonate, big modulus sodiumsilicate and collector ZJ
oleic acid composite, stirring to obtain roughing concentrate, roughing middlings and roughing
tailings; secondly, concentrating, namely adding big modulus
sodium silicate in the roughing concentrate to perform 3-4 times of concentrations and obtain concentrating middlings and
phosphorus product concentrate; thirdly,
scavenging, namely adding ZJ
oleic acid composite in the roughing
tailings to perform 2-3 times of scavengings and obtain
scavenging middlings and tailings; and 3. regrinding and reprocessing, namely further dissociating ores, and reprocessing to obtain tailings and
residual phosphorus concentrate. The invention is characterized in that the ore grinding cost is low, the dosage of reagents is low, the ZJ
oleic acid composite is easy to prepare and is convenient to use, the separating effect of
phosphorus ores and
gangue mineral is obvious, the separation indexes are good, etc; and the method is especially suitable to be used in the flotation of
silicon-poor deposition-
calcium phosphorite type
phosphate ores with a concentration of P2O5 of less than 20%.