525results about "Phosphoric acid" patented technology

An equipment for recovering and utilizing the heat energy generated by burning yellow phosphorus and a system for preparing phosphoric acid by the hot method are disclosed. It is composed of steam manifold and burning tower with heat energy recovering function. The burning tower consists of ring-shaped membrane heat exchanger with fins, heat-insulaitng enclosed casing, P2O5 gas outlet tube, connecting tube of phosphorus sprayer, etc.. Its advantages include low consumption of coal, water and energy, low cost and reduced environmental pollution.

The invention relates to a process for preparaing electronic phosphoric acid with melt crystallization method. It comprises following steps: removing arsenic from industrial phosphoric acid; heating crystal tube to minus two Deg. C to ten Deg. C; putting phosphoric acid of 21-28 Deg. C into crystal tube for circultion, the crystal layer growing to 2-4 cm; stewing crystal tube for 15-25 minutes and keeping the temperature, then heating crystal tube at speed of 2-5 Deg. C per hour, stopping when quality of melted crystal is 10-40% of thant of initial one; cleaning crystal layer with cleaning liquid with its tempeature near at temperature of fusible point of phosphoric acid hemi-crystalline. The certificated electronic phosphoric acid can be got after crystallization and perspiration; and electronic phosphoric acid of high purity reaching to FCC4 standard can be got after cleaning. The invention is characterized by high removal rate for foreign matter, low energy consumtion, wide range for treating raw material with different purity, high purity of geot product and sound economic benefit.

The invention relates to a method for preparing electronic grade phosphoric acid through liquid membrane crystallization. The method comprises the following steps: slowly pouring seed crystals which are prepared in advance, in a column crystallizer, wherein the temperature of the wall of the column crystallizer is controlled to 10-20 DEG C; (2) adding liquid phosphoric acid in the column crystallizer form the top of the crystallizer while using cooling medium in the jacket of the column crystallizer to reduce the temperature of the column crystallizer to 5-10 DEG C, wherein raw material crystallizes and grows on the seed crystals to form a crystal film and uncrystallized liquid flows out from the bottom of the column crystallizer; stopping adding materials when the thickness of the crystal film is 1/4-1/3 of the diameter of the column crystallizer, keeping temperature for 15-30min to discharge feed liquid which does not form film; heating the column crystallizer to 15-29 DEG C and keeping temperature for 0.5-2h so as to melt the film layer, collecting the discharged liquid as a product; and (4) repeating the step (1), (2) and (3) by using the obtained product as raw material to perform secondary liquid film crystallization and obtaining the electronic grade phosphoric acid product. The method has simple operation, short production time, low energy consumption and high impurity removal rate, and the electronic grade phosphoric acid product with a concentration of 87-90% can be directly obtained.

The invention discloses a method for pre-treating phosphorite of wet process phosphoric acid by using acidic waste water in the production process of titanium pigment, which comprises the following steps: (1), collecting the acidic waste water into an acidic waste water storage groove, controlling the acid degree to be 2 to 5 percent and the total iron concentration to be 0.3 to 0.5 percent; (2), adding the acidic waste water and the milled phosphorite in a solid-to-liquid ratio of 2-5:1 into a reaction groove for reaction; and (3), performing solid-liquid separation on the slurry which is obtained in the step (2) to obtain a solid phase, namely the required phosphorite. The content of magnesium in the phosphorite which is treated by the method is reduced by over 70 percent, the loss ratio of the phosphorus is controlled to be within 1 percent; when the phosphorite which is treated by the process is used for producing the phosphoric acid by a wet method, the consumption of the sulfuric acid for mine per ton is reduced by about 10 percent; and the acidic waste water pretreats phosphorite and then is delivered to a sewage station for treatment, the consumption of lime or other alkaline substance is reduced by 60 percent compared with the mode of directly delivering the waste water to the sewage station, so the economical efficiency of the process is high.

This invention discloses a method for separating phosphorus and fluorine of kiln process phosphoric acid by absorption. The method comprises: sending relatively high temperature phosphoric acid after hydration in primary and secondary hydration columns to a circulation tank for cooling, pumping into the hydration columns for circulation, sending gases after primary and secondary absorption to a Venturi absorber for re-absorption, collecting the residual acid mist by a collector, sending the absorbed gas and tail gas after fluorine absorption together to a chemical absorption column, and exhausting the tail gas. Besides, qualified fluosilicic acid can be obtained from the fluorine-containing diluted H3PO4 in the collector. The method utilizes the air with residual heat in the kiln, and has such advantages as no extra energy consumption, high phosphorus and fluorine separation efficiency, high concentration and low fluorine content in obtained H3PO4, and low P2O5 content in obtained fluosilicic acid. The obtained fluosilicic acid has a wide concentration range and a high purity, and is easy to utilize.

The invention relates to a co-production method of calcium sulfate whisker and phosphoric acid. The method comprises the following technical steps of: (1) acid-hydrolyzing phosphate rock powder by hydrochloric acid with the mass concentration of 15 to 26% or nitric acid with the mass concentration of 20 to 90%, filtering the acid-hydrolyzed slurry into the acid hydrolysis solution containing Ca2<+>; (2) using the acid hydrolysis solution containing Ca2<+> and the sulfuric acid with the mass concentration of 20 to 90% as the raw materials, wherein the use level of the sulfuric acid is 100% of the needed theoretical amount of the sulfuric acid when the Ca2<+> in the acid hydrolysis solution and the sulfuric acid react completely, adding the sulfuric acid to the acid hydrolysis solution containing Ca<2+> under the stirring condition, reacting the sulfuric acid with the acid hydrolysis solution containing Ca2<+> at the normal pressure and at 50 to 90 DEG, filtering and separating the calcium sulfate whisker after the reaction is finished, and then washing and drying the calcium sulfate whisker; and (3) carrying out the counter-current extraction on the filtrate obtained in the step (2), wherein the extracted water phase is the phosphoric acid, and acid-hydrolyzing the phosphate rock powder by using the hydrochloric acid obtained by the counter-extraction of the soft water to the extracted organic phase which is separated in the counter-current extraction.

The invention discloses a method for producing phosphoric acid and gypsum whiskers by a wet process, which is used in combination with a wet-process phosphoric acid production device. The method comprises: reacting hydrochloric acid with excessive phosphorus ore pulp to form calcium chloride solution containing hydrochloric acid; reacting the calcium chloride solution with solution of sulfuric acid to obtain a suspended matter; filtering, washing and obtaining dihydrate gypsum whiskers; and heating filtrate, cooling, and absorbing, wherein hydrogen chloride is circularly used, phosphoric acidis purified to be used for producing a phosphate product.

Quite unexpectedly, by suitably modifying the crystal structure of hydrogarnets of the general formula M^II₃Mr^I-III₂(OH)₁₂ (where M^II denotes divalent metal ions, especially alkaline earth metal ions, of Group IIA of the periodic table and M^III denotes trivalent metal ions of Group IIIA of the periodic table, especially aluminum) with suitable amounts of incorporated silicate and/or phosphate, flame retardants having both a higher flame retardant efficiency than such traditional mineral flame retardants as ATH and MDH, and a higher thermal stability than ATH can be produced. It has also been found that synthetic hydrogarnets of the general formula M^II₃Mr^III₂(OH)₁₂(where M^II and M^III are as defined above) having cubic crystal and these synthetic hydrogarnets also show high flame retardant efficiency.

The invention is a method for producing phosphoric acid and soluble potassium salt by phosphorus ore and potash feldspar, characterized in that, the method comprises: selecting phosphorus ore containing P2O5 15-30% and potash feldspar containing K2O 10-18% to mix with coke; crushing, ball milling, balling by adding water and drying; calcining for 10-30 minutes under temperature of 1100-1400DEG C; then soaking the calcined product in 1-5% citric acid solution for 12 hours, wherein, the soaking temperature is between room temperature and 60 DEG C; crystallizing and purifying the separated filtering solution; obtaining the soluble potassium salt; P2O5 in the phosphorus ore is reduced into phosphor vapor to be volatilized, the phosphor vapor above the material layer can be oxidized into P2O5 gas by the air introduced into the furnace, in the hydration apparatus, P2O5 gas can be absorbed to obtain the phosphoric acid. the invention solves the problems of waste slag and waste gas emissions during producing phosphoric acid, also alleviates the existing state that in our country, the soluble kalium resources are depended on importation, the method of the invention is economical and environment-protecting.

The present invention relates to method of producing phosphoric acid with low and medium grade phosphorous ore. The low and medium grade phosphorous ore is used to produce phosphoric acid through the acidifying reaction with water solution of phosphoric acid, solid-liquid separation and phosphoric acid crystallization reaction. The method has the advantages of high phosphoric acid purity and low production cost.

The invention discloses a technique and device for preparing phosphoric acid by a fluidized bed reactor. The technique mainly comprises the following steps: crushing phosphorite, silica and carbon reducer, screening, adding bentonite, adding water, evenly mixing, drying to solidify, recrushing, screening into a granular material, putting the granular material into a fluidized bed reactor, heating to 1100-1350 DEG C by fuel burning and high-temperature gas heat exchange in the oxidizing zone, and fluidizing and reducing under the actions of N2 and reflux technique tail gas; and after the generated P2 and CO enter the oxidizing zone together with external oxygen-enriched air and are burnt to generate P2O5 and CO2 and the P2O5 gas is purified by dust removal, absorbing with recycle acid to obtain H3PO4. The fluidized bed reactor is effectively divided into a reducing zone and an oxidizing zone through a heat conducting plate, and implements heat coupling; and the phosphorite is fluidized, reduced, and subjected to forced heating and mass transfer, thereby greatly lowering the reduction temperature, shortening the reaction time and solving the problems of plugging and ringing in the rotary kiln, and the like.

The invention discloses a safe phosphorus supply device for thermal phosphoric acid production. A melting material, namely yellow phosphorus is safely conveyed through water level difference in a low melting slot, and then enters a furnace from the bottom of the combustion furnace, so that a dangerous operation step that the melting yellow phosphorus in the high risk state is conveyed to a high slot through a high pressure pump or compressed air, and then is bunt by high pressure spraying in the traditional production line is avoided; and the effects of energy consumption reduction, equipment investment reduction and stable quality are achieved. The safe phosphorus supply device for the thermal phosphoric acid production has the advantages of strong practicability and better economic benefit.

The present invention discloses direct phosphate rock reducing process for preparing high concentration phosphoric acid and coproducing silicate and aluminate products, and may be used in the comprehensive utilization of medium and low grade phosphate rock and phosphate rock tailings with P2O5 content not less than 6 %. The direct phosphate rock reducing process includes mixing phosphate rock powder with silica powder, coke powder, coal powder, kaolin or other additive and water; shaping the mixture and stoving; setting into container of refractory material and heating in a tunnel kiln to obtain phosphorus vapor and CO; absorbing in a hydrating tower to obtain concentrated phosphoric acid and cooling the product inside the container to obtain various kinds of side product. The present invention has simple production process and raised phosphorus reducing rate, and is suitable for industrial production.

Processes and reagents for inhibiting or eliminating scale formation during wet-process phosphoric acid production are provided and include adding to a wet-process phosphoric acid production stream a scale inhibiting amount of a reagent having an aliphatic or aromatic compound containing at least two hydroxy groups, and at least one amine.

A substrate treating apparatus includes a circulating line having a treating tank for storing a phosphoric acid aqueous solution, a circulating pump for feeding the phosphoric acid aqueous solution, a heater for circulation for heating the phosphoric acid aqueous solution, a filter for filtering the phosphoric acid aqueous solution, the circulating line causing the phosphoric acid aqueous solution discharged from the treating tank to flow in order of the circulating pump, the heater for circulation and the filter, and returning the phosphoric acid aqueous solution from the filter to the treating tank. The apparatus also includes a branch pipe branching from the circulating line between the heater for circulation and the filter for extracting the phosphoric acid aqueous solution from the circulating line, and a concentration measuring station connected to the branch pipe for measuring silicon concentration in the phosphoric acid aqueous solution by potentiometry.

A process for preparing industrial phosphoric acid by use of hydrochloric acid to decompose the low-and medium-grade phosphorus ore includes such steps as using hydrochloric acid to decompose phosphorus ore to obtain calcium chlorophosphate, using hydrochloric acid to prepare slurry, dissolving the calcium chlorophosphate in it, extracting by tri-butyl phosphate, concentrating, extracting by tri-butyl phosphate and isopropyl ether, concentrating, and de-coloring to obtain 85% industrial phosphoric acid. Its advantage is no environmental pollution.

This invention discloses a method for recovering phosphorite to prepare highly concentrated phosphoric acid and by-product Portland cement clinkers, which increases proportion of Ca and Si of various levels of phosphorite P2O5>=6%, utilizes the Ca, Si, Al and Fe oxides contained in the phosphorite and adds carbon reducers and small amount of Si or Si correction material to be mixed and added with water to process balls or other shapes to be dried and put into a container of fireproof material then enters into a tunnel stove to get phosphor vapour and CO to be asorbed by a hydrate tower to get densed phosphor, and materials in the container are cooled to become Portland cement clinkers.

The invention relates to a high concentration phosphoric acid producing method by directly deoxidized phosphorite. The process that the stock produced by phosphorus ore, diatomite, coke or coal accomplishes a reduction-oxidation to produce phosphoric acid consists of a preheating zone, a reducing zone and an oxidation combustion zone which are composed of different equipment modules. The preheating zone is under 1150 DEG C to 1200 DEG C; the reducing zone is under 1250 DEG C to 1450 DEG C, the coke or the coal in the stock performs a reduction reaction with phosphorite; phosphorus vapor that is P4 and carbon monoxide gas which are produced enter into the oxidation combustion zone again; air is added into the oxidation combustion zone, thus the phosphorus vapor that is P4 and the carbon monoxide gas are oxidized to produce a mixed kiln gas which is composed of P2O5 and CO2; the mixed kiln gas with high temperature is sucked out and led into a hydration absorption tower after dust abatement, and the phosphoric acid is produced by recycle acid absorption. The stock after the reduction reaction is exported from the reducing zone, and is formed into cement clinker or building materials after cooling and heat transfer. The invention has the innovative points that the processes of preheating, deoxidizing and oxidizing of reducing gas of the stock are separated, and the reactions are not mutually interfered. The control of the action process is simple, in addition, the percent reduction of the phosphorite is high, and the high yield of total phosphorus can be gained.

The invention discloses a hemi-hydrate process wet process phosphoric acid production process which comprises the following steps of: 1) crushing commercial-grade phosphate ore to be 60% ground phosphate rock and screening by using a sieve of 100 meshes; 2) adding the crushed phosphate ore into phosphoric acid which is 50-55% in mass concentration, controlling the liquid-solid ratio to be 12:1 and the reaction temperature to be 60-80 DEG C, carrying out decomposition reaction for 60-90 minutes; 3) adding reaction slurry into concentrated sulfuric acid (93-98%) to carry out rapid chemical reaction to generate hemi-hydrate gypsum and phosphoric acid; 4) filtering the generated hemi-hydrate gypsum by using a filtering machine, washing by using hot water, drying and grinding so as to obtain a product hemi-hydrate building gypsum powder; 5) using the filtrate obtained through filtration as another objective product, i.e., the wet process phosphoric acid. By using the process, the problem that the hemi-hydrate gypsum is hard to filter and wash is solved, and moreover the cost on ardealite resource application is greatly lowered.

The invention provides a method for directly preparing electronic grade phosphoric acid by yellow phosphorus, relating to a preparation method of phosphoric acid, in particular to the preparation method of electronic grade phosphoric acid applied to the electronic industry; in the invention, industrial yellow phosphorus is used as the raw material, the method has the following steps: a. placing the industrial yellow phosphorus going through purifying pretreatment in a combustion tower; b. injecting air going through multilevel oil removal, edulcoration and humidity control into the industrial yellow phosphorus to facilitate sufficient burning thereof; c. sending P2O5 air generated by burning into an absorption tower, using ultrapure water for cycling absorption; d. sending a phosphoric acid purifying post treatment equipment for carrying out anion and cation desorption, aeration and multi-stage filtration purifying treatment after the concentration of the phosphoric acid generated by absorption reaches 85.0-87.0%; and d. purifying the processed phosphoric acid in the 10000-level or 1000-level air purification environment and packing product acid with a clean pail pack. The invention features easy control of production operation, good and relatively stable quality and low production cost.