272 results about "Phosphate product" patented technology

This invention relates to a novel method of decreasing porosity of ceramics produced by sol-gel processing. The process of preparing chemically bonded sol-gel ceramics comprises phosphating a sol-gel derived oxide or hydrated oxide and polymerizing the phosphated product with heat treatment. Such combined sol-gel/chemical bonding process can be used to fabricate dense, thick ceramics or ceramic coatings for a variety of applications, including high temperature corrosion protection, wear resistance, dielectric properties, non-sticky surfaces, bio-active ceramics, thermal barrier ceramics, non-wetted surfaces, and others.

The invention relates to the technical field of chemical engineering, and particularly relates to a production method for monoammonium phosphate. A monoammonium phosphate product is prepared by directly subjecting high pure urea phosphate and ammonia to a double decomposition reaction and reacting for 20-60 min with stirring by controlling a reaction temperature at 40-80 DEG C and a pH value at a reaction endpoint being 4.2-4.6, and through the steps of cooling for crystallization; separating by centrifugation and drying. Measurements of physical and chemical indexes of the produced product show that the physical and chemical indexes of the produced monoammonium phosphate product meet an industrial first level standard. Specifically, the total nutrient content of monoammonium phosphate is higher than 73%; the content of total nitrogen is 12.01-12.23%; the content of phosphorus pentoxide is 61.05-61.25%; the content of moisture is 0.35-0.52%; a pH value is 4.2-4.6; the content of water insoluble materials is 0.090-0.096%; and the content of fluoride is 0.15-0.19%.

The invention relates to a hexatomic-ring alkylsiloxane-phosphate natural gas pipeline corrosion-inhibition drag reducer and a preparation method thereof. The preparation method comprises the following steps: reacting raw materials phosphorus pentoxide and long-chain alkyl alcohol in a mol ratio of 2:1-4:1 to generate the product mainly comprising long-chain monoalkyl phosphate (MAP); reacting long-chain alkylmethyl dimethoxysilane and the MAP product in a mol ratio of 2:1-2.5:1 to generate an alkylsiloxane-phosphate product mixture, wherein the content of the hexatomic-ring long alkylsiloxane-phosphate is 80-85 wt.%, and the content of the linear alkylsiloxane-phosphate is 15-20 wt.%; and dissolving the obtained alkylsiloxane-phosphate product mixture in n-heptane to form a 30-50 wt.% solution, thereby obtaining the hexatomic-ring alkylsiloxane-phosphate natural gas pipeline corrosion-inhibition drag reducer. The invention has the advantages of high corrosion inhibition efficiency, high drag reduction rate and long effective period.

The invention discloses a method for producing phosphoric acid and gypsum whiskers by a wet process, which is used in combination with a wet-process phosphoric acid production device. The method comprises: reacting hydrochloric acid with excessive phosphorus ore pulp to form calcium chloride solution containing hydrochloric acid; reacting the calcium chloride solution with solution of sulfuric acid to obtain a suspended matter; filtering, washing and obtaining dihydrate gypsum whiskers; and heating filtrate, cooling, and absorbing, wherein hydrogen chloride is circularly used, phosphoric acidis purified to be used for producing a phosphate product.

The invention discloses a method for preparing industrial grade monoammonium phosphate from wet-process phosphoric acid. In the method, the industrial grade monoammonium phosphate is prepared by neutralizing ammonia with low-cost wet-process phosphoric acid serving as raw materials; a pickling procedure is adopted, so that volatile gas materials are recycled, crystallization mother liquor is recycled or concentrated for recycling, the industrial grade monoammonium phosphate product is obtained, and the product yield is improved; meanwhile the by-products in the production process are used as compound fertilizer materials. The method has the advantages of greatly reducing the production cost of the industrial grade monoammonium phosphate, guaranteeing the stability of the product quality, and avoiding secondary pollution, along with low energy consumption and better economic benefit and social benefit.

The invention discloses a preparation method of ferric phosphate and a product thereof. The preparation method comprises the following steps of: (1) introducing a ferric iron source solution into an acid resistant reaction kettle by using a metering pump, and then adding a certain dosage of phosphoric acid solution and stirring for 1h; (b) adding a certain dosage of organic solvent to the acid resistant reaction kettle, and preserving heat at 15-98 DEG C and aging for 0.5-24h; and (c) carrying out washing, filtering and spray drying on the obtained ferric phosphate slurry to obtain a final ferric phosphate product, wherein the proportion by weight of the water to the iron to the phosphoric acid to the organic solvent is 100:1-20:1-30:1-500. In the method, the traditional alkali is replaced by the organic solvent to prepare the ferric phosphate; and because the organic solvent has milder property and no harm to the human body, and the operating environment is beneficially improved after mass production. The ferric phosphate of two different crystal forms of amorphism and orthorhombic systems can be prepared by adopting the method.

The invention relates to a method for producing potassium dihydrogen phosphates, in particular to a method for producing potassium dihydrogen phosphate with a double decomposition method. The invention is characterized by further improving the quality of a potassium dihydrogen phosphate product and enhancing the concentration of byproduct hydrochloric acid on the basis of the work of the previous period. The method comprises the following steps of: mixing potassium chloride powder with a phosphoric acid solution, carrying out double decomposition reaction in a spray tower, dissipating hydrogen chloride gas generated by the reaction along with hot air for preparing hydrochloric acid or chlorate; and hydrolyzing, neutralizing and crystallizing double decomposition reaction materials after the hydrogen chloride gas is dissipated to prepare a potassium dihydrogen phosphate product. By adopting the method, it is unnecessary to dissolve potassium chloride into phosphoric acid, it is only necessary for adequately mixing the potassium chloride solid powder with phosphoric acid, therefore, the reaction time is shortened, the production energy consumption is reduced, the production efficiency is improved, and the conversion rate is higher up to more than 99%; meanwhile, the concentration of by-product hydrochloric acid can reach above 25%, and can reach as high as 33%, and the recycling value is greater.

A method for preparing battery-level ferric phosphate using pyrite cinders uses pyrite cinders as raw materials. The dissolution of iron element in the pyrite cinders is improved by using a composite acidic medium, a soluble organic-acid ferric-salt is extracted and separated synchronously and selectively, and a high-purity ferric phosphate is obtained through replacement in situ under a weak-acid condition, so that the pyrite cinders are transformed into a high-additional ferric phosphate product, thereby realizing the resource utilization of bulk industry solid-wastes in a more economical manner. The ferric phosphate materials prepared by using the method have advantages of a controlled iron-phosphorus ratio, a low impurity content and a high reaction activity, thereby being favorable to insert lithium ion in a subsequent sintering process to form a lithium ferric phosphate crystal suitable for a lithium ion battery positive material.

The invention discloses a method for producing industrial grade monoammonium phosphate through combination of wet process phosphoric acid and high-purity phosphoric acid. The method comprises the steps of performing neutralization reaction for two times on filtrate and ammonia gas or ammonia water to obtain ammonium phosphate slurry, wherein the filtrate is obtained by performing desulfurization reaction on phosphate rock powder and wet process phosphoric acid; performing concentration, crystallization and drying by using filtrate which is obtained by adjusting the pH value with high-purity phosphoric acid to obtain an industrial grade monoammonium phosphate product; removing most of impurity ions when the pH value is neutralized to 4.0-5.0 by the first neutralization reaction, then performing the second neutralization reaction to remove impurities in the wet process phosphoric acid, finely adjusting the pH value to 3.9-4.4 by using the high-purity phosphoric acid, and performing concentration and crystallization to obtain the industrial grade monoammonium phosphate. The method disclosed by the invention reduces the production cost and energy consumption and is environment-friendly and pollution-free; the obtained product is stable in quality, the process flow is short, the device construction investment is saved, the needed operators are less, the energy consumption is reduced, the pollution is reduced, and the quality of monoammonium phosphate is ensured through effective impurity removal, so that the method has a very good economic benefit.

The invention provides a method for preparing potassium dihydrogen phosphate. In the method, phosphate ores, sulphuric acid and potassium chloride are taken as base materials and subjected to phosphoric acid extraction, filtering, neutralization and separation, concentration and crystallization to obtain a full water-soluble potassium dihydrogen phosphate product, and the potassium dihydrogen phosphate solution prepared is high in concentration, the solid content reaches 40 percent, thereby reducing the load of the concentration process; in particular, the method adopts a process of neutralization first and concentration second, so that the corrosivity of concentration liquids is small, the boiling point is low, and the conventional multi-effect concentration by evaporation can be performed by the common equipment, and the equipment investment and the energy consumption are greatly lowered; because in the phosphoric acid extraction process, the potassium bisulfate is added, thereby effectively lowering the emission of fluorine-containing exhaust gases and facilitating the environmental protection; adding with the development and the utilization of potassium-containing phosphogypsum, the method of the invention can avoid the environmental pollution caused by the phosphogypsum, improve the material utilization ratio and make the material utilization ratio reach 100 percent.

The invention relates to a method for extracting ferric phosphate from phosphorized waste residues. The method comprises the following steps: adding water into powdery phosphorized waste residues, and uniformly stirring; then, slowly adding concentrated hydrochloric acid into a reaction device till the white solids are fully dissolved; filtering the solution and removing undissolved substances; slowly dropwise adding sodium hydroxide solution into the filtrate, controlling the pH of the solution to 1.0-2.0, reacting for 3+/-0.5 hours, and filtering; washing with distilled water to neutral; and drying and smashing to obtain a battery-grade ferric pyrophosphate product. According to the process of recovering and purifying ferric phosphate provided by the invention, the recovery rate of ferric phosphate reaches 90%, the content of Fe<3+> in the ferric phosphate product is greater than or equal to 29% (dihydrate), and Fe/P is equal to 0.97-1.0. According to the method provided by the invention, waste is turned to wealth, the problem that waste residues are discharged to cause the environmental pollution is solved, and the ferric phosphate product with a wide market prospect is extracted from phosphorized waste residues.

The invention discloses a method of producing dihydric phosphate, which essentially comprises steps as follows: firstly, chloride is mixed with excessive phosphoric acid in order to obtain material liquid; secondly, the material liquid is added into the spray dryer to atomize into tiny droplets; thirdly, the droplets are instantaneously contacted and heated with as much hot air as is sufficient to enable double decomposition reaction between chloride and phosphoric acid to happen, so that hydrogen chloride gas escapes through the double decomposition reaction between chloride and phosphoric acid, and the remaining reaction products are hydrolyzed, the pH value thereof is regulated, and a dihydric phosphate product is obtained after cooling and crystallization. The production method has technical advantages that the shortcomings of prior art can be overcome, the spray dryer is adopted as a core reactor to atomize the material liquid into small droplets to be contacted with the high-temperature hot air, the specific surface area of evaporation is maximum, so that the escaping time of HCl and the water vapor is 3 to 8 seconds only, the reaction conversion rate reaches up to 97 percent, the cost of raw materials can be significantly reduced, the material liquid continues to be in and out, the reaction device is simple and practical, so that large-scale industrialization production can be achieved.

The invention relates to a method for preparing battery grade lithium dihydrogen phosphate with a high-purity lithium carbonate lithium depositing mother solution. The method comprises the steps of: conducting preliminary lithium extraction and deep lithium extraction to a lithium carbonate lithium depositing mother solution with phosphoric acid and phosphate so as to obtain a mixture of lithium phosphate and dilithium hydrogen phosphate, reacting the mixture with phosphoric acid to generate a lithium dihydrogen phosphate solution, then carrying out concentration and evaporation, cooling and crystallization, centrifugation, saturation washing, drying, air-stream crushing and packaging, thus obtaining the battery grade lithium dihydrogen phosphate. The method of preparing battery grade lithium dihydrogen phosphate in the invention fully makes use of the mother solution generated during high-purity lithium carbonate production, and has the advantages of simple process, easy operation, low production cost, over 90% of lithium recovery rate, and stable quality of the obtained battery grade lithium dihydrogen phosphate product, and is also suitable for preparing the lithium ion battery positive material lithium iron phosphate. Therefore, the method provided in the invention boasts broad market prospects, as well as good economic and social benefits.

The invention mainly discloses a method for preparing orthophosphates from polyphosphates, and in particular relates to a method for preparing orthophosphate products from an orthophosphate-containing material recycled from phosphorus wastes as the raw material through hydrolysis.

The invention discloses a system and a method for increasing a nitric phosphate product P2O5 dissolvability in water, belonging to the field of nitric phosphate production. Phosphorite is subjected to acidolysis, acid non-soluble substance separation, crystallization, filtering, neutralization, nitrogen and phosphorus evaporation, prilling, drying, screening, cooling and packing; mother liquor and potassium sulphate are added into a neutralizing tank according to a ratio, a small part of residual Ca<2+> are converted into calcium sulfate, generation of citric acid-soluble calcium hydrophosphate salt and insoluble phosphate is reduced, and K<+> is added in slurry. After the system is used, the production method is energy-saving and environment-friendly, a nutrient element kalium needed by plants is supplemented in a product while the dissolvability in water of a finished product P2O5 is increased, the material viscosity in a low temperature state in a neutralization process is reduced, and the quality of nitric phosphate is comprehensively improved.

The invention discloses a deep purification method of feed-grade wet-process phosphoric acid. According to the deep purification method, inorganic salt I, inorganic salt II, inorganic salt III and inorganic salt IV are combined with aluminum and magnesium ions in wet-process phosphoric acid to generate indissolvable compound inorganic salt to be precipitated, aluminum and magnesium impurities are removed, and then fluorine is removed, thereby realizing the deep purification of wet-process phosphoric acid. According to a novel deep purification process of feed-grade wet-process phosphoric acid, aluminum, magnesium and fluorine can be removed from phosphoric acid by a wet process, so that the index requirements of raw material acid for producing feed calcium salt or high-concentration phosphatic fertilizers, soluble fertilizers and industrial grade phosphate products are met; and no new impurity ion is introduced into purified phosphate.

A closed cyclic utilization method for production water of monoammonium phosphate, is suitable for a dihydrate pulp wet-process phosphoric acid technology and an ammonia neutralization fluidized drying phosphate fertilizer production system. A production water cyclic system mainly comprises a clear water recovery pond, a sewage settling basin, a settlement and overflow groove, a water flushing and distribution tank, a thick slurry groove, a round plate filter, an extraction tail gas washing tower, a dried tail gas washing tower. Multi stage closed cyclic utilization is preformed on sewage, and primary water consumed by per ton product is 2.5-2.8t, in order to supplement water entering into the product or phosphogypsum and lost by evaporation. The method provided by the invention resolves problems of a lot of sewage and difficult treatment, which puzzles a monoammonium phosphate production enterprise for a long time. The method has advantages of simple technology process, good sewage treating effect, small technology equipment and investment, low personnel labor intensity and high water utilization rate. The method can effectively save water resource, the water consumption of monoammonium phosphate product is reduced to 2.5-2.8t per ton product from 20t per ton product. The method implements closed cyclic utilization for production water of monoammonium phosphate, and zero discharge of sewage.

The invention discloses a method for producing food-grade monoammonium phosphate from wet-process phosphoric acid. The low-cost wet-process phosphoric acid is adopted as a raw material, is subjected to impurity removal and undergoes neutralization reaction with ammonia to prepare the food-grade monoammonium phosphate; a pickling procedure is adopted, so that volatile gas materials are recycled, crystallization mother liquor is recycled or concentrated for recycling, the food-grade monoammonium phosphate product is obtained, and the product yield is improved; meanwhile, byproducts in the production process are used as compound fertilizer materials. The method greatly reduces the production cost of the food-grade monoammonium phosphate, ensures the stability of product quality, avoids secondary pollution, and has low energy consumption and good economic and social benefits.

The invention discloses equipment for producing high-nutrient monoammonium phosphate through a double-tubular-reactor process. The equipment comprises a strong phosphoric acid clarifying tank, a tubular-reaction acid mixing tank, a granulator, tubular reactors, a drying machine, a bucket elevator, a screening machine, a crushing machine, a belt conveyor, a cooling fluidized bed, a wrapping barrel, a cyclone separator, a dust exhausting fan and a tail gas washing system. The equipment runs stably during the process switching and normal production period and can extract a granular monoammonium phosphate product with uniform grain size and nutrients and water meeting the standard through the main processes of mixing acid in a tubular-reaction manner, spraying and granulating, drying, screening and crushing (collecting returning charge), cooling and wrapping and the like; the product is high in water solubility, free from blocking and stable in performance in the air, contains available phosphorus (P2O5) more than 52% and nitrogen (N) more than 11%, is a high-quality base raw material for preparing an N, P and K three-element compound fertilizer and has strong market competitiveness.

The invention discloses a wet process phosphoric acid purification technology of nonphosphate precipitation and belongs to the field of phosphorus chemical industry. According to the wet process phosphoric acid purification technology of nonphosphate precipitation, an agent is combined with anions and cations in diluted phosphoric acid to generate an indissolvable double salt which is precipitated in a form of nonphosphate, so that a purpose of wet process phosphoric acid purification is achieved, thereby satisfying the demand of producing a high-concentration phosphate fertilizer, a water soluble fertilizer and an industrial phosphate product. The method can remove iron, magnesium, aluminum, arsenic, lead, sodium, potassium, sulfate radicals and the like stably in wet process phosphoric acid and has characteristics of being simple in reaction condition, short in a process flow, wide in an agent source, low in a treatment cost, high in a P2O5 recovery rate and the like, so that sesquioxide-removal, heavy metal removal and desulfuration by a one-step method are realized. The removal rates of iron, magnesium and aluminum in the treated wet process phosphoric acid separately reaches above 97%, 70% and 15%; arsenic and lead in diluted acid are less than 5 ppm; sodium (calculated by NaO) and potassium (calculated by K2O) are separately lower than 0.025% and 0.083%; sulfate radicals are lower than 0.16%; and the P2O5 recovery rate is higher than 98.5%.

The invention provides a method for preparing lithium carbonate from lithium phosphate. According to the technical scheme, the method comprises steps as follows: cleaning, dissolution, impurity removal, lithium settlement, extraction of a phosphate product and recovery. During production, lithium elements are cyclically utilized, the loss is low, the yield is high, and the produced lithium carbonate has high purity and good quality and can reach the battery level. A large quantity of harmful chemical waste lithium phosphate can be utilized, and lithium carbonate urgently needed in the market can be produced.

The invention discloses a preparation method of dimethylmorphinan phosphate used as a cough medicine. The method comprises the following steps: removing L-mandelic acid from (S)-l-(4-methylbenzyl)-1,2,3,4,5,6,7,8-octahydroisoquinoline-L-mandelate to obtain (S)-l-(4-methylbenzyl)-1,2,3,4,5,6,7,8-octahydroisoquinoline, performing methylation by using the (S)-l-(4-methylbenzyl)-1,2,3,4,5,6,7,8-octahydroisoquinoline chiral material as a raw material, and then performing cyclization reaction together with phosphoric acid under the conditions of heating and decompression to obtain (9S,13S,14S)-3,17-dimethylmorphinan monophosphate with three chiral centers, namely dimethylmorphinan phosphate; and desalting, rectifying, crystallizing, salifying, drying, and packaging to obtain the refined dimethylmorphinan phosphate product. The method has the characteristics of simple process, low cost, high yield, high product purity, short production cycle and the like, thereby being a synthetic route suitable for industrial mass production.