1782 results about "Organic phosphorus" patented technology

The present invention discloses excellent flame-retardant polyester and preparation method of the flame-retardant polyester. The product comprises polyester and the organic silicone copolymer as well as organic phosphorus copolymer contained in the polyester. The preparation process comprises the synthesis of the polyester, etherifying of the synthesized polyester or the polycondensation phase during which organic silicon monomer and organic phosphor monomer are added. The present invention takes use of silicon monomer and organic phosphor monomer for copolymerization with the polyester. The polyester is endowed with excellent flame-retardant performance. The polyester can meet the no-drop requirements during the flame-retardant process. The product by the present invention is no-drop-typed flame-retardant polyester, which can be used to manufacture polyester fiber and correspondent woven fabric or weaving fabric textile or nonwoven cloth and so on.

The invention belongs to the technical field of the farm chemical, and in particular relates to a plant insecticidal protective agent and an application thereof. The invention provides the plant insecticidal protective agent which is recomposed by food suppressing hydrazine and organic phosphorus (I), pyrethroids insecticides (ii), insect growth regulation agent (III), Macrolides (IV), heterocyclic insecticidal component (V), carbamates (VI) or Nereistoxin pesticide and the application thereof. The recomposed insecticidal composite remarkably improves the insecticidal effect, at least has four acting ways at the same time such as touch out, stomach toxicity, internal absorption and antifeedant so as to adequately protect the plant, favors the delay of the production of the drug resistanceof the insects through different acting ways, and enlarges the pest control spectrum. The composite can be widely applicable to the control of different chewing mouthparts, piercing-sucking mouthparts, lapping mouthparts and rasping mouthparts pests.

The invention relates to a bio-organic fertilizer special for improving saline-alkali lands and a preparation method thereof. The bio-organic fertilizer is prepared from the following raw materials by weight: 5-20% of bean pulp, 64-70% of vinegar dregs, 10-25% of humic acid, 5-7% of calcium magnesium phosphate, 0.1-0.3% of zinc sulfate, 0.1-0.2% of borax and 0.05-0.1% of compound microbial strains. The preparation method of the bio-organic fertilizer comprises the steps of compound microorganism selecting, activating, primary expanding, secondary expanding and expanding by tabling, material mixing, fermenting, turning, finished product preparing, low-temperature drying, detecting and measuring and packaging. The organic matters and the humus in the bio-organic fertilizer can adsorb the free ions fixed in the soil of the saline-alkali lands, reduce the solution concentration of the soil and neutralize the alkali in the soil of the saline-alkali lands, thus alleviating or eliminating the saline-alkali harms, and simultaneously release the potassium ions and increase the contents of the organic phosphorus and the inorganic phosphorus, thus improving the effectiveness of the fertilizer.

The invention relates to a method for preparing a lithium iron phosphate material, which is characterized in that: a dispersant in an amount which is 0.01 to 20 percent based on the mass of the precursor used for preparing the lithium iron phosphate is added into the precursor; and after, mixing, dispersing, drying and heat treatment, the high-performance lithium iron phosphate nano material is obtained; the dispersant is one or more of polyaminoamidophosphate, product of addition of fatty acid and epoxyethane, polyethylene glycol polyol, phosphate, polycarboxylic acids, organic phosphorus single-preparation antiincrustation corrosion inhibitors, organic phosphate, polycarboxylic acid antiscale dispersants, water treatment dispersant and dye dispersant; and the precursor may be a lithium-containing precursor, an iron-containing precursor or phosphor-containing precursor. When the method is adopted, the solid content of the precursor of the lithium iron phosphate material can be improved to over 35 percent, the high flowability of the precursor of the lithium iron phosphate material is maintained, and after the heat treatment, the impurity content is controllable. The lithium iron phosphate nano material has a spherical micro-nano structure, high tap density and high material processing performance.

The invention discloses a core-shell synergistic flame retardant polyurethane microencapsulation expandable graphite and the application of the expandable graphite in rigid polyurethane foaming plastic. The core-shell synergistic flame retardant polyurethane microencapsulation expandable graphite comprises polyether and/ or polyester polyol, a foaming agent, a foam stabilizer, a catalyst, an organic phosphorus-based flame retardant, a halogen-free intumescent flame retardant, an organic modified nano inorganic filler, core-shell synergistic flame retardant polyurethane microencapsulation expandable graphite, polyisocyanate compound and isocyanate index, wherein the polyisocyanate compound has two or more isocyanate groups; the core-shell synergistic flame retardant polyurethane microencapsulation expandable graphite takes expandable graphite particles as a capsule core and takes cyclodextrin or polyurethane as a capsule shell, wherein the cyclodextrin or polyurethane is formed by crosslinking cyclodextrin/ modified resin and toluene diisocynate. The expandable graphite microcapsule can effectively improve the initial decomposition temperature, the heat stability and the flame retardant effect of a material and remarkably reduces the heat release rate and the total heat release quality during combustion.

The invention relates to a compounded herbicide composition for rice fields, which contains the following two effective components: component (A): pyribenzoxim; component (B): a herbicide which is one of the following compounds: triazines compounds, heterocyclic compounds, phenoxy compounds, amide compounds, diphoenyl ether compounds, sulfonylurea compounds, phenoxyalkanoic acid compounds, botanical compounds, organic phosphorus compounds, urea compounds, dinitroaniline compounds, benzamide compounds and carbamate compounds; and wherein, the weight ratio of the component (A) to the component (B) is 1-50: 1-50.

The invention provides an olefin polymerization catalyst, which contains titanium, silicon, magnesium, phosphorus, an internal donor compound and halogen. The invention further provides a method for preparing the olefin polymerization catalyst disclosed by the invention. The invention further provides an olefin polymerization method. Silicon is introduced into the olefin polymerization catalyst, so that the catalytic activity of the olefin polymerization catalyst for olefin polymerization is 1.1-1.5 times higher than that of a catalyst into which silicon is not introduced in the prior art. According to the method for preparing the olefin polymerization catalyst disclosed by the invention, a silane compound is introduced in the contacting process of a magnesium compound, an organic epoxy compound and an organic phosphorus compound in a solvent, so that the activity of the prepared catalyst is much higher than that of a catalyst obtained with a method in which a silane compound is not introduced in the prior art. The method disclosed by the invention has the advantages of readily-available raw materials and low production cost.

The invention discloses a poly-phosphate flame retardant containing a DOPO side-chain structure and a preparation method thereof, belonging to the technical field of polymeric organic phosphorus flame retardant structures and the preparation method thereof. The flame retardant is characterized by comprising the following repeating unit structure: wherein n=5-50. The preparation method of the poly-phosphate flame retardant comprises the following steps of: reacting an intermediate I containing the DOPO structure with phosphorus oxychloride to obtain an intermediate II containing phosphorus oxychloride, and fusing and polymerizing the intermediate II and a bisphenol compound to obtain the poly-phosphate flame retardant containing the DOPO side-chain structure. The preparation method is simple, and through adjusting Ar categories and ratios, the phosphorus content can be controlled at 11.5-15.5% and the sulfur content can be controlled at 0-5.9%. The flame retardant has the characteristics of favorable thermal stability, high decomposition temperature, favorable char-forming property, and the like, and can be used for flame retardance modification of materials, such as polyester, polyamide, polycarbonate and blends thereof, and the like, with higher processing temperature.

The invention relates to a halogen-free flame-retardant epoxy resin composite, the flexible copper clad laminate made from the epoxy resin composite and the production method. The halogen-free flame-retardant epoxy resin composite is composed of solid components and organic solvents, wherein, the solid components include: phosphorus epoxy resin, synthetic rubber, rubber-modified epoxy resin and composite curing agent. The flexible copper clad laminate made from the halogen-free flame-retardant epoxy resin composite is a three-layer flexible copper clad laminate, including a polyimide insulation film, a coating of halogen-free flame-retardant epoxy resin composite coated on the polyimide insulation film, and a copper foil pressed on the coating of halogen-free flame-retardant epoxy resin composite. The resin composite of the invention is halogen-free and dispenses with other organic phosphorus flame retardants; the flexible copper clad laminate made from the composite has the flame retardancy up to UL94 V-0-level and has the advantages of high peeling strength, excellent dimensional stability, softness, good ion migration resistance and processing performance.

The present invention provides an environmentally friendly breeding method of ricefield eels and loaches, belonging to the stereoscopic environmentally friendly agriculture development mode and the matching technology. The technical scheme for solving the problem is as follows: 1, rice field construction; 2, rice field fertilization; 3, rational pesticide application; 4, breeding the ricefield eels and the loaches; 5, feeding management; 6, the ricefield eels and the loaches recapturing; 7, escape-proof technology of the ricefield eels and the loaches. The method has the following beneficial effects: 1, the rate of output is high; the annual rate of output of the ricefield eels and the loaches in each area unit is more than 1/3; 2, the management is convenient; the ricefield eels and the loaches can be placed simply, namely, only the seeds need to be placed into the rice field and the earthworms need to be placed on the ridge; 3, the economic benefit is good: the net profit of the ricefield eels and the loaches in the rice field in each area unit can be more than 3000 Yuan; 4, the environmentally protection effect is good, the soil can be loose and the soil fertility can be enhanced; simultaneously, with lots of organic fertilizers, the dosage of the chemical fertilizer is reduced and there is no need for the pesticide such as organic phosphorus.

Disclosed are an aqueous pigment dispersion containing at least a pigment, water, a high-molecular dispersant, and an alkali. The high-molecular dispersant is a diblock polymer having a formula (1) of A-B or a triblock polymer having a formula (2) of A-B-C. The diblock or triblock polymer is a diblock or triblock polymer obtained by polymerizing addition-polymerizable monomers with a radical generator while using an organic iodide as a polymerization initiating compound and an organic phosphorus compound, organic nitrogen compound or organic oxygen compound as a catalyst. Also disclosed are a production method and use of the aqueous pigment dispersion. With the high-molecular dispersant obtained by a simple living radical polymerization process free of the problems of conventional living radical polymerization and having a precisely-controlled molecular structure, the aqueous pigment dispersion can be obtained with the pigment dispersed in it.

A flame-retardant synthetic resin composition characterized by comprising 1-40 parts by weight of at least one type of organic phosphorus compound represented by the following general formula (1):

(wherein R¹ represents alkyl, aralkyl, etc.)

with respect to 100 parts by weight of a synthetic resin.

The invention provides an ultraviolet light crosslinking low-smoke zero-halogen flame-retardant cable material. The cable material comprises polyolefin, a compatilizer, an inorganic flame retardant, an organic phosphorus-nitrogen-containing flame retardant, a flame-retardant synergist, a photoinitiator, an assistant crosslinker, a surfactant, an antioxidant and a lubricant, wherein polyolefin contains low-density polyethylene, an ethylene-octylene copolymer and an ethylene-vinyl acetate copolymer in the weight proportion being (10-25):(20-35):(55-65); the compatilizer is polyethylene for grafting of maleic anhydride; the inorganic flame retardant is selected from magnesium hydroxide and aluminum hydroxide; the organic phosphorus-nitrogen-containing flame retardant contains polyphosphoric acid, pentaerythritol and melamine in the weight proportion being (10-20): (4-8): (15-30); the flame-retardant synergist contains zinc borate and/or polydimethylsiloxane. The cable material has good thermal resistance and anti-aging performance, can be used at the temperature of 125 DEG C for a long time and is excellent in comprehensive mechanical performance and better in flame retardance.

The invention provides a catalyst component for olefin polymerization or copolymerization and a preparation method thereof. The preparation method comprises the following steps of: dissolving magnesiumhalide in a system containing an organic epoxy compound, an organic phosphorus compound and halohydrocarbon to form a solution; and in the presence of an auxiliary precipitation agent, reacting a titanium compound with the obtained solution, and precipitating the catalyst with magnesium and titanium for sediment. The preparation method of the catalyst active component has the advantages of easy obtaining of raw materials, lower production cost and high catalytic activity during using for propene polymerization or copolymerization, and is suitable for a variety of polymerization processes, such as a serous fluid method, a bulk method, a gas phase method and the like.

The invention provides a preparation method of phosphorous-containing phenol formaldehyde resin. The preparation method comprises the following steps: mixing mixture of two phenols with acidic catalysts and formaldehyde, and increasing the temperature of a reaction system to 50-120 DEG C and reacting for 3-8 hours; 2) adding alcohol for performing etherification reaction, and controlling the etherification temperature to be 100-150 DEG C; 3) adding organic phosphorus compounds, increasing the temperature of the reaction system, and reacting for 2-5 hours. The phosphorous is introduced in a phenol formaldehyde resin and modified to prepare the high-performance phenol formaldehyde resin, the phenol formaldehyde resin is matched with epoxy resin to be used for copper clad plates, and the flame retardation can achieve UL94V-0. The preparation method is simple, and the synthesis pollution is less. The copper clad plate manufactured by the phenol formaldehyde resin can not produce toxic gas in combustion, thereby being incapable of injuring a human body.

The invention relates to the field of antiflaming materials and particularly relates to a preparation method for an organic phosphorus copolymerized antiflaming polyamide material used for textile, engineering plastics and thin films. The preparation method of the organic phosphorus copolymerized antiflaming polyamide material specifically comprises the following steps: (1) enabling a fire retardant and a diamine monomer to react in advance to prepare a prepolymer; (2) adding a polymerized monomer, a catalyst and the prepolymer into a reaction kettle to prepare the organic phosphorus copolymerized antiflaming polyamide material. According to the organic phosphorus copolymerized antiflaming polyamide material provided by the invention, a small amount of the reaction fire retardant needs to be added, no synergic fire retardant is needed, the viscosity is controllable in the preparation process, the use property of the polymer finally obtained in the reaction is excellent, and the organic phosphorus copolymerized antiflaming polyamide material can be used in various fields of textile, engineering plastics, thin films and the like. Meanwhile, the use amount of raw materials is small, the process is simple, the cost is low, the actionability is high, and the flame retardant property of the prepared product is high.

The invention discloses a preparation method of a magnetic metal organic framework material and an application of the magnetic metal organic framework material. The preparation method comprises the steps of synthesizing a nano magnetic material Fe3O4 by adopting a coprecipitation method, adding the nano magnetic material Fe3O4, FeCI3.6H2O and terephthalic acid into DMF, carrying out ultrasonic mixing, and synthesizing Fe3O4/MIL-101(Fe) by adopting a hydrothermal method; separating a product by utilizing a magnetic field, washing with hot ethyl alcohol, and drying overnight so as to obtain the Fe3O4/MIL-101(Fe). The Fe3O4/MIL-101(Fe) obtained by the method is applied to separating and enriching organophosphorus in urine. The magnetic metal organic framework material is uniform in particle size, is relatively strong in magnetism, and is good in dispersibility; MIL-101(Fe) formed by the coordination of oxygen bearing carboxylate ligand and a metal ion F3<3+> is adopted as an adsorption separation medium and is combined with a magnetic solid phase extraction technique for being combined with chromatography so as to determine trace organophosphorus residues in urea, and the magnetic metal organic framework material is relatively high in flexibility.

The invention relates to a high-temperature-resistant super retarder with favorable dispersibility and a preparation method thereof. The invention aims to provide a high-temperature-resistant super retarder with favorable dispersibility adaptable to high temperature in summer and a preparation method thereof. The high-temperature-resistant super retarder with favorable dispersibility comprises the following components in parts by weight: 300-450 parts of organophosphorous acid or organic phosphorus salt, 150-300 parts of dispersant and 15-25 parts of surfactant. The preparation method comprises the following steps: proportionally adding raw materials into a reaction kettle, uniformly mixing and stirring, adding 300-400 parts by weight of water, and dissolving by stirring to obtain the product. The high-temperature-resistant super retarder provided by the invention solves the problem of high temperature adaptability of the retarder, is convenient for construction in summer, can adapt to multiple water reducers, is applicable to C40 above high-strength concrete, can prolong the retention time of concrete flowability by more than 0.5 hour, is convenient for concrete transportation, and has the advantages of simple production technique and low cost.

The invention provides a preparation method of N-P-codoping porous biomass carbon catalyst. Cheap and easy-to-get biomass chitosan is taken as carbon source and nitrogen source (as nitrogen-containing ligand at the same time), organic phosphorus compound triphenylphosphine is taken as phosphorus-containing ligand, the nitrogen-containing ligand and the phosphorus-containing ligand form a coordination compound together with metal ions in metallic salt solution, ZnCl2 is taken as activating agent, the coordination compound is subjected to high-temperature pyrolysis in a nitrogen atmosphere to form holes, and finally diluted hydrochloric acid is used to remove metals for secondary hole formation, so as to prepare the N-P-codoping porous biomass carbon catalyst with rich micropores and a mesopores structure as well as a high specific surface area. The N-P-codoping porous biomass carbon catalyst is comparable to commercial Pt/C (20%) in catalytic performance in an alkaline environment, has good methanol poisoning resistance and stability, and can regulate components and performance of catalyst in molecular level. The N-P-codoping porous biomass carbon catalyst disclosed by the invention is expected to replace cathode oxygen reduction catalyst of the commercial Pt/C, and has a very good industrial application prospect.

The invention relates to a high-activity olefin polymerization catalyst, a preparation method and an application and belongs to the field of olefin polymerization. The high-activity olefin polymerization catalyst is composed of a main catalyst and a cocatalyst and characterized in that the main catalyst is composed of a magnesium halide carrier, a transition metal halide, alcohol which is smaller than C5, alcohol which is larger than C5, an organosilicon compound and an organic phosphorus compound; the mole ratio of the magnesium halide carrier, the transition metal halide, the alcohol which is smaller than C5, the alcohol which is larger than C5, the organosilicon compound and the organic phosphorus compound is 1: (1-40): (0.01-5): (0.01-10): (0.01-10): (0.05-5); and the cocatalyst is an organic aluminum compound. Particles of the catalyst are good in shape, spherical and free from adhering to the wall of a container; and the catalyst is high in activity, good in hydrogen regulation performance and applicable to a slurry polymerization process, a loop polymerization process, a gas phase polymerization process or a combined polymerization process, and a melt flow rate (MFR) of polyethylene can be regulated within a range of 0.1g/10min-600g/10min.

The invention provides a phosphorous removing agent for wastewater produced during producing organophosphorus pesticides and a preparation method thereof. The solid phosphorous removing agent which can effectively remove total phosphorus from the wastewater produced during producing the organophosphorus pesticides is prepared by mixing a mineral with a metal compound and supporting the metal compound with the mineral. The phosphorous removing agent and the preparation method have the following beneficial effects: the production process is simple; the production cost is low; no harmful gas or sewage is generated in the production process; and the phosphorous removing agent can be widely used for removing phosphorous from the wastewater produced during producing various organophosphorus pesticides and has an obvious phosphorous removal effect.

The invention discloses a halogen-free flame retardant, high-temperature resisting and rapidly solidified deacetone silicon rubber and a preparation method thereof. Hydroxy-end-capped polydimethylsiloxane is used as the main body and is compounded with a thermal-resisting additive and a flame retardant additive, wherein the halogen-free flame retardant, high-temperature resisting and rapidly solidified deacetone silicon rubber comprises the following ingredients by weight: 100 parts of the hydroxy-end-capped polydimethylsiloxane serving as a main body, 1-50 parts of polydimethylsiloxane, 5-18 parts of silicon oxide, 5-15 parts of thermal-resisting additive, 50-200 parts of flame retardant additive, 0.5-2.5 parts of tackifier, 0.5-1 part of organic guanidine catalyst and 5-8 parts of deacetone siloxane cross-linking agent; the thermal-resisting additive is one or a mixture of several of iron oxide red, cerium oxide of which the purity is not less than 90% and tin oxide of rutile structure; and the flame retardant additive is one or a mixture of several of aluminum hydroxide, magnesium hydrate, zinc borate, phosphate ester, phosphonate, phosphine oxide and organic phosphorus. The deacetone silicon rubber has good thermal resistance, flame retardant effect and mechanical properties at 250-300 DEG C, and is simple in preparation method and high in production efficiency.

The invention relates to preparation and application of a magnetic ferroferric oxide nanoparticle modified carbon nanotube composite material. The preparation method includes: mixing a divalent iron salt and a trivalent iron salt, adding NH3.H2O, conducting water bath and centrifugal separation, washing the precipitate, and carrying out drying and grinding to obtain magnetic Fe3O4 nanoparticles; adding concentrated nitric acid and concentrated sulfuric acid into pretreated carbon nanotubes, conducting heating refluxing, carrying out filtering, deionized water washing and vacuum drying, thus obtaining purified multiwalled carbon nanotubes; adding the purified multiwalled carbon nanotubes into a triethylene glycol solution, conducting ultrasonic treatment, adding magnetic Fe3O4 nanoparticles, performing stirring and heating, conducting heat preservation and cooling, separating the product, and conducting vacuum drying, thus obtaining the magnetic Fe3O4 nanoparticle modified carbon nanotube composite material. The composite material is used for detecting the residue amount of organophosphorus pesticides in food. The preparation method utilizes magnetic Fe3O4 nanoparticles to modify carbon nanotubes, and greatly improves the dispersibility and adsorption properties of carbon nanotubes in water. The prepared magnetic Fe3O4 nanoparticle modified carbon nanotube composite material hasgood stability, and the maximum recovery rate can reach 89.6%.