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499 results about "Environmental water" patented technology

Method of preparing three-dimensionally ordered macroporous chelate resin with hydrophilic-structure framework

The invention relates to a method of preparing three-dimensionally ordered macroporous chelate resin which has a hydrophilic-structure framework and can absorb precious metal irons in aqueous solution, belonging to the field of the chelate resin. The method of preparing the three-dimensionally ordered macroporous chelate resin comprises the following steps: (1) preparing 80-1000nm silica colloidal crystal template; (2) preparing three-dimensionally ordered Poly(N-vinylformamide) or poly(n-vinylacetamide) macroporous material; and (3) preparing hydrophilic three-dimensionally ordered macroporous chelate resin. Compared with the traditional macroporous or gel-type polyvinylamine resin, the novel three-dimensionally ordered macroporous chelate resin prepared with the method has the advantages that the regularly-arranged porous channel system has small diffusion resistance, which is good for the metal irons enter the absorption center from all directions. In addition, the novel three-dimensionally ordered macroporous chelate resin is easy to synthesize, has stable performance, good hydrophilic performance and high selectivity, contains many functional groups, can absorb a large number of metal irons and has better development and utilization values in the aspect of avoiding heavy metal pollution and protecting the environmental water.
Owner:HEBEI UNIV OF TECH

Long-acting protective liquid self-secreting super-lubricity coating and preparation method thereof

The invention discloses a long-acting protective liquid self-secreting super-lubricity coating and a preparation method thereof, and belongs to the anti-corrosion, anti-fouling and anti-icing fields and the like. A coating body is an elastic porous film layer and is divided into a bottom layer, an upper layer and a surface layer. The bottom layer is of a large pore structure, the porosity is as high as 60%-95%, the pore diameter ranges from 100 microns to 2000 microns, and the oil storage amount is increased; the upper layer pore diameter ranges from 10 nm to 100 microns, the thickness rangesfrom 50 microns to 1000 microns, oil is prevented from being lost too fast, and the secretion process is controlled; and the surface layer is of a micro-nano-level convex structure, the roughness ranges from 10 nm to 50 microns, and the lyophobic and oil storage effects are achieved. Lubricating oil is stored in the porous structure, when surface oil dries, the oil can be gradually diffused to thesurface layer through upper-layer small holes to form a liquid protective oil film. Corrosion inhibitors, bactericides and the like added into the lubricating oil are released along with the oil, andthe protective function of the coating is enhanced. When environmental water flow impact, external force extrusion, friction and the like lead to losing of the surface oil film, the external force effect will also promote deformation of the elastic porous structure to secrete oil, it keeps that a stable oil layer is formed on the surface, and the service life of the coating is significantly prolonged.
Owner:UNIV OF SCI & TECH BEIJING

Preparation method of polyvinyl alcohol/hydroxyapatite (PVA/HA) composite microspheres

A preparation method of polyvinyl alcohol/hydroxyapatite (PVA/HA) composite microspheres belongs to preparation methods of composite water-in-oil emulsion system microspheres. PVA and HA precursors are used as raw materials to prepare a clear and transparent mixed solution; the clear and transparent mixed solution is dispersed into an oil phase containing a surfactant to form a homogeneous water-in-oil microemulsion; and the PVA/HA composite microspheres can be finally obtained by successive crosslinking reaction under acid-catalyzed conditions, HA deposition under alkaline conditions, product centrifugation, washing, drying and other processes. The method has the advantages of simple process, good repeatability, low energy consumption and low cost, and effectively solves the problems that inorganic nanoparticles are easy to agglomerate in the microspheres to cause uneven structures and poor comprehensive performances and the like. The composite microspheres prepared by the method have the advantages of regular morphology, high dispersibility, uniform microstructure, good biocompatibility, biological activity and adsorption performance, and can be used as drug carrier materials, bone repair materials, environmental water treatment materials, cosmetics or food additives and the like.
Owner:CHINA UNIV OF MINING & TECH

Preparation method of chitosan-grafted beta-cyclodextrin bonded silica gel absorbent

The invention discloses a chitosan-grafted beta-cyclodextrin bonded silica gel absorbent as well as a preparation method and application of the chitosan-grafted beta-cyclodextrin bonded silica gel absorbent, and belongs to the technical field of the absorbent material preparation. The preparation method of the chitosan-grafted beta-cyclodextrin bonded silica gel absorbent comprises the steps of (1) activating silica gel, (2) bonding the silica gel with gamma-aminopropyl, (3) carrying out silica gel formyl group modification reaction, and (4) bonding chitosan with glutaraldehyde and grafting beta-cyclodextrin with the chitosan. According to the chitosan-grafted beta-cyclodextrin bonded silica gel absorbent provided by the invention, the activated silica gel surface is chemically modified by gamma aminopropyl triethoxy silane, and then, cyclodextrin-grafted chitosan is taken as a functional monomer to compound a solid-phase extraction material. By combining cyclodextrin recognition performance and a chitosan absorbing function, the chitosan-grafted beta-cyclodextrin bonded silica gel absorbent has the advantages of firmness in bonding, stable property, favorable reproducibility and selection, and large enrichment multiple, and the chitosan-grafted beta-cyclodextrin bonded silica gel absorbent can be used in a wide pH scope. The absorbent can be used in the enrichment pretreatment of trace Cu (I) and Cd (II) in an environmental water sample.
Owner:FUZHOU UNIV

Fluorescent magnetic nanoparticle for hypochlorous acid detection and synthetic method thereof

The invention discloses a fluorescent magnetic nanoparticle for hypochlorous acid detection and a synthetic method thereof. The synthetic method comprises the following steps: preparing a ferroferric oxide magnetic nanoparticle as a magnetic core material by adopting a solvent thermal method, coating the outer part of the magnetic core with a layer of nonporous silicon dioxide and a layer of mesoporous silicon dioxide in sequence by adopting a sol-gel method, and finally covalently modifying a magnetic mesoporous material obtained in the previous two steps with an organic fluorescent molecule capable of specifically identifying hypochlorous acid through a silane coupling agent, thus obtaining the fluorescent magnetic nanoparticle for the hypochlorous acid detection. The nanoparticle is simple in a preparation process and low in cost; the detection of high sensitivity and high selectivity of the hypochlorous acid can be realized by utilizing the remarkable enhancement of a fluorescent signal of the nanoparticle before and after recognition; and the magnetic control and separation of the magnetic nanoparticle can be realized by additionally arranging a magnetic field. The fluorescent magnetic nanoparticle and the synthetic method thereof have an important application prospect in the fields of visual tracing and imaging of the hypochlorous acid in living organisms, quantitative detection of hypochlorous acid in environmental water, clearing and the like.
Owner:XI AN JIAOTONG UNIV

Detection method of residual quantities of various veterinary drugs in culturing or slaughtering environment

The invention provides a detection method of residual quantities of various veterinary drugs in a culturing or a slaughtering environment. With the method, rapid screening and quantitative detection can be carried out upon 61 drugs of 9 categories. The drugs include chlormycetin, beta lactams (penicillins), quinolones, sulfonamides, trimethoprims, macrolides, tetracyclines, and nitroimidazoles. According to the invention, a soil sample or an environmental water sample is added into a phosphate buffering solution; a filtrate obtained through centrifugation is extracted in a solid phase extraction column, and is eluted; the extraction column is dried by blowing, and is washed by using a methanol solution; an obtained eluent is titrated by using a methanol solution; a chromatogram peak of the sample is detected by using liquid chromatography-tandem mass spectrometry; the chromatogram peak is compared with a standard chromatogram peak, such that a specific variety of the detected drug is accurately determined. According to the invention, the sample solution is subject to liquid chromatography-tandem mass spectrometry multi-reaction monitoring selected ion analysis. Through internal standard correction, the recovering rate is 70-120%, and a relative standard deviation RSD is no larger than 18%. Compared with existing technologies, the analysis efficiency is improved by at least 5 times, and the detection cost is 30% of that of existing technologies.
Owner:ANIMAL AND PLANT & FOOD DETECTION CENTER JIANGSU ENTRY EXIT INSPECTION AND QUARANTINE BUREAU

OLED (Organic Light-Emitting Diode) display panel

The invention provides an OLED (Organic Light-Emitting Diode) display panel, which comprises an array substrate, an OLED functional layer and a thin-film packaging layer, and is characterized in thatthe OLED display panel is internally provided with an opening area to be cut and removed, a blocking dam surrounding the opening area is arranged between the array substrate and the OLED functional layer at the periphery of the opening area, the blocking dam includes a blocking unit with the cross section being in the shape of an inverted trapezoid around the opening area, and the OLED functionallayer above the blocking dam is disconnected at two sides of the blocking dam during film forming as the cross section of the blocking unit is in the shape of an inverted trapezoid. According to the invention, the structure of the blocking dam at the periphery of the opening area is optimized, and the cross section of the blocking unit is enabled to be in the shape of an inverted trapezoid, so that the whole common film layer deposited by a common mask plate can be cut off at two sides of the blocking dam, thus environmental water and oxygen can be prevented from invading into a light-emittingpixel area of the panel from the cutting section of the opening area along the continuous common film layer after the opening area is cut, and the service life of the panel is prolonged.
Owner:WUHAN CHINA STAR OPTOELECTRONICS SEMICON DISPLAY TECH CO LTD

Preparation method and Cu<2+> detection application of rare earth ratiometric fluorescent probe

The invention discloses a preparation method and a Cu<2+> detection application of a rare earth ratiometric fluorescent probe, and belongs to the technical field of environmental detection. The preparation method of the luminol-Tb-GMP fluorescent probe is established through the self-polymerization coordination effect among luminol, GMP and Tb<3+> by using luminol and guanosine monophosphate (GMP)as dual ligands and using a rare earth ion Tb<3+> as a luminescent center ion. The luminol-Tb-GMP fluorescent probe combines the dual fluorescent signals of luminol and Tb<3+>, and simultaneously emits dual fluorescent signals of the luminol and Tb<3+> under the same excitation wavelength. When Cu<2+> exists, the luminol and GMP have a strong coordination effect on the Cu<2+> in order to preventelectrons from being transferred from the amino group of the GMP to Tb<3+>, so fluorescence quenching of the Tb<3+> is caused, and the fluorescence intensity of the luminol is unchanged, thereby a Cu<2+> detection method based on the fluorescence signal ratio of the luminol and Tb<3+> is established. Additionally, the green fluorescence of the Tb<3+> gradually weakens and the blue fluorescence ofthe luminol gradually appears with the increase of the Cu<2+> concentration, so the visual detection of the Cu<2+> can be achieved. The luminol-Tb-GMP fluorescent probe also can be applied to the sensitive detection of the Cu<2+> in an environmental water samples and a biological sample.
Owner:RUIJIN SHENGYUAN METAL NEW MATERIAL CO LTD

Method for preparing water-soluble mercury ion fluorescence probe on basis of rhodamine and application of water-soluble mercury ion fluorescence probe

The invention discloses a method for preparing a water-soluble mercury ion fluorescence probe on the basis of rhodamine and application of the water-soluble mercury ion fluorescence probe. A structural formula of the Hg<2+> fluorescence probe are shown, and the water-soluble mercury ion fluorescence probe is synthesized from 1, 2, 4-trimellitic anhydride, 3-diethylamino phenol and hydrazine hydrate. The method and the application have the advantages that the water-soluble Hg<2+> fluorescence probe prepared by the aid of the method is simple in structure, is based on rhodamine derivatives and is the first fluorescence probe for detecting Hg<2+> in 100% aqueous solution by the aid of rhodamine lactam derivatives; ring opening of rhodamine lactam structures can be carried out under the induction effects of the Hg<2+> in systems, intense fluorescence can be generated, and the water-soluble mercury ion fluorescence probe is high in Hg<2+> detection sensitivity; the fluorescence probe is excellent in Hg<2+> selectivity and is almost free of interference of other positive ions; the Hg<2+> can be measured by the fluorescence probe without disturbance when pH (potential of hydrogen) values range from 5.0-8.0, the fluorescence probe and the Hg<2+> can act quickly, and the response time is shorter than 3 minutes; the probe further can be applied to measuring Hg<2+> in environmental water samples and carrying out fluorescence imaging on Hg<2+> in biological cells.
Owner:XIANGTAN UNIV
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