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Mine water glass reinforced water shutoff material

A technology of mining water and water glass, which is applied in the field of mine reinforced water blocking materials, can solve the problems of high reaction heat of grouting materials, unadjustable curing time, large particle size of cement grouting, etc., and achieve low reaction heat and solidification Time-adjustable, penetrating effect

Inactive Publication Date: 2013-05-22
SHANXI YUBANG NEW POWER SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. The geological cracks in the coal mine are fine, the cement grouting particle size is large, the diffusion radius is small, the tiny cracks cannot be injected, and the curing time cannot be adjusted;
[0005] 2. The underground environment of the coal mine is humid and watery, and polyurethane foams when it encounters water, and its strength decreases;
[0006] 3. Organic (polyurethane, epoxy) grouting materials have high heat of reaction and low flame retardancy, which can easily cause coal mine fires

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A mineral water glass reinforced water blocking material, which is prepared according to the following weight ratio of raw materials:

[0032] A component material: Weigh 51 kg of sodium water glass with a modulus of 1.5 in water glass A, 34 kg of sodium potassium water glass with a modulus of 1.5 in water glass B, and 0.15 kg of catalyst C pentamethyldiethylenetriamine , 0.25 kg of trimerization catalyst 2,4,6-tris(dimethylaminomethyl)phenol and 0.1 kg of dibutyltin dilaurate, 14.5 kg of plasticizer D 52# chlorinated paraffin. Put the weighed water glass A and water glass B into a mixing tank and stir, then add the weighed catalyst C and plasticizer D respectively, stir evenly at room temperature, and seal the package after sampling and testing pass.

[0033] Component B: Weigh 51 kg of curing agent A polyphenyl polymethylene polyisocyanate (Yantai Wanhua PM-200), 26 kg of curing agent B triacetin, and polyether polyol C is 2 functional 23 kg of polyoxypropylene diol ...

Embodiment 2

[0036] A mineral water glass reinforced water blocking material, which is prepared according to the following weight ratio of raw materials:

[0037] A component material: Weigh 70 kg of sodium water glass with a modulus of 2.6 in water glass A, 15 kg of sodium potassium water glass with a modulus of 2 in water glass B, and 0.2 kg of catalyst C pentamethyldiethylenetriamine , 0.3 kg of dimethylethanolamine, 0.5 kg of dimethylcyclohexylamine, plasticizer D is 10 kg of 52# chlorinated paraffin and 4 kg of dibutyl phthalate. Put the weighed water glass A and water glass B into a mixing tank and stir, then add the weighed catalyst C and plasticizer D respectively, stir evenly at room temperature, and seal the package after sampling and testing pass.

[0038] B component material: Weigh 70 kg of curing agent A Yantai Wanhua PM-200 polyphenyl polymethylene polyisocyanate, 15 kg of curing agent B glycerol triacetate, polyether polyol C is 2 functional molecular weight 15 kg of polyo...

Embodiment 3

[0041] A mineral water glass reinforced water blocking material, which is prepared according to the following weight ratio of raw materials:

[0042] A component material: Weigh 80 kg of sodium water glass with a modulus of 3 in water glass A, 10 kg of sodium water glass with a modulus of 2.5 in water glass B, and 0.25 kg of N, N-dimethylbenzylamine as catalyst C , 0.15 kg of trimerization catalyst 2,4,6-tris(dimethylaminomethyl)phenol and 0.1 kg of dibutyltin dilaurate, plasticizer D is 5 kg of 52# chlorinated paraffin and dibutyl phthalate 4.5 kg. Put the weighed water glass A and water glass B into a mixing tank and stir, then add the weighed catalyst C and plasticizer D respectively, stir evenly at room temperature, and seal the package after sampling and testing pass.

[0043] Component B: Weigh 85 kg of curing agent A Yantai Wanhua PM-200 polyphenyl polymethylene polyisocyanate, 3 kg of glycerin triacetate of curing agent B, and polyether polyol C with a molecular weigh...

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PUM

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Abstract

The invention relates to a mine water glass reinforced water shutoff material which is composed of two independent components, namely component A and component B, wherein the component A comprises following raw materials by weight: 51-99.9% of water glass A, 0-50% of water glass B, 0.1-2% of catalyst C and 0-50% of plasticizer D; and the component B comprises the following raw materials by weight: 51-100% of curing agent A, 0-50% of curing agent B and 0-50% of polyether polyol C. The mine water glass reinforced water shutoff material has the effects of high flame resistance, low reaction heat and adjustable curing time; and environmental water basically does not influence the reaction. By utilizing the mine water glass reinforced water shutoff material, the safety of production of a coal mine can be improved to a great extent.

Description

technical field [0001] The invention belongs to the field of reinforced water blocking materials for mines, and in particular relates to a water blocking material reinforced with mineral water glass. Background technique [0002] Under the action of mine pressure and when encountering geological faults and subsidence columns, the coal mass on the roof of the roadway and working face will scatter, resulting in deformation of the roadway, roof caving, and coal side flakes, which will bring hidden dangers to safe production. [0003] Coal mines encounter the above problems in the production process and usually use flow cement slurry, polyurethane, epoxy and other materials to maintain the roof of the roadway working face, but the above materials bring many problems to safe production in practical application. As described below: [0004] 1. The geological cracks in the coal mine are fine, the cement grouting particle size is large, the diffusion radius is small, the tiny crack...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/26
Inventor 柏广峰
Owner SHANXI YUBANG NEW POWER SCI & TECH
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