Method for producing iron oxyhydroxide particle

A technology of iron oxyhydroxide and manufacturing method, which is applied in chemical instruments and methods, iron oxide/iron hydroxide, carbonyl iron, etc., and can solve problems such as easy growth and large iron oxyhydroxide

Inactive Publication Date: 2008-10-01
TDK CORPARATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the oxidation temperature is set at 10° C. or higher, oxidation at this temperature may cause green rust (green rust), which is the core of iron oxyhydroxide, to grow easily, and the iron oxyhydroxide may become too large.

Method used

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  • Method for producing iron oxyhydroxide particle
  • Method for producing iron oxyhydroxide particle

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Use ferrous sulfate heptahydrate (FeSO 4 ·7H 2 O) Ferrous salt as an iron raw material An aqueous solution of ferrous sulfate was prepared such that the concentration (Fe concentration) of the ferrous suspension was 0.05 mol / L. Prepare sodium bicarbonate (NaHCO) that is respectively 4 times of equivalents and 2 times of equivalents relative to the iron raw material 3 ) and sodium hydroxide (NaOH) as neutralizers. The neutralizer and ion-exchanged water were mixed and stirred to obtain an alkaline aqueous solution with a pH of 12, and an aqueous ferrous sulfate solution was added to the alkaline aqueous solution to neutralize and precipitate to obtain a suspension (step A). In addition, the temperature was controlled such that the liquid temperature at the time of this neutralization and thereafter was kept constant at 0°C. The concentration of Fe in the suspension containing ferrous iron was 0.05 mol / L. This neutralization produces ferrous carbonate, ferrous hydroxi...

Embodiment 2

[0061] Iron oxyhydroxide particles were obtained in the same manner as in Example 1, except that the pH of the alkaline aqueous solution was set to 10 in step A.

[0062] For the iron oxyhydroxide particles, the same measurement as in Example 1 was carried out. The results are shown in Table 1.

Embodiment 3

[0064] Iron oxyhydroxide particles were obtained in the same manner as in Example 1, except that the pH of the alkaline aqueous solution was set to 10 in step A, and the oxygen-containing gas was blown in bubbles with a diameter of 1.7 mm in step B.

[0065] For the iron oxyhydroxide particles, the same measurement as in Example 1 was carried out. The results are shown in Table 1.

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Abstract

First, a ferrous iron-containing suspension solution is obtained by mixing an aqueous ferrous salt solution and an aqueous alkali solution containing one or two of an alkali carbonate and an alkali hydroxide. Then, an iron oxyhydroxide particle precursor is obtained by blowing an oxygen-containing gas having an oxygen component proportion of 0.5 to 0.8 into the suspension solution thus obtained to oxidize the ferrous iron in the suspension solution at an oxidation rate of 30 to 65% while the suspension solution is being controlled to fall in a temperature range of -5 DEG C. or higher and lower than 10 DEG C. Thereafter, the iron oxyhydroxide particles 2 are produced from the iron oxyhydroxide particle precursor by blowing an oxygen-containing gas into the suspension solution containing the iron oxyhydroxide particle precursor while the suspension solution is being controlled to fall in a temperature range of 20 DEG C. or higher and lower than 45 DEG C.

Description

technical field [0001] The present invention relates to iron oxyhydroxide particles suitable for use as a precursor of magnetic particles for high-density and high-capacity magnetic recording tapes, and in particular to fine iron oxyhydroxide particles having a large axial ratio and a narrow particle size distribution Manufacturing method. Background technique [0002] High-density and high-capacity magnetic recording tapes are increasingly required. As the recording density increases, the bit length or track width becomes smaller. That is, high density can be achieved by improving recording density and track density. However, as the bit length and track width become smaller, the number of magnetic bodies per bit decreases and the SN ratio decreases. Furthermore, if the particle size becomes uneven, the distribution state of the magnetic substance will become uneven, and noise will increase. Therefore, in order to achieve high density, it is necessary to form fine and uni...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G49/16
CPCC01G49/02B82Y30/00C01B21/0622C01P2004/10C01P2004/54C01P2004/64
Inventor 河濑美香佐藤守
Owner TDK CORPARATION
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