Method for producing iron oxyhydroxide particle
A technology of iron oxyhydroxide and manufacturing method, which is applied in chemical instruments and methods, iron oxide/iron hydroxide, carbonyl iron, etc., and can solve problems such as easy growth and large iron oxyhydroxide
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Embodiment 1
[0056] Use ferrous sulfate heptahydrate (FeSO 4 ·7H 2 O) Ferrous salt as an iron raw material An aqueous solution of ferrous sulfate was prepared such that the concentration (Fe concentration) of the ferrous suspension was 0.05 mol / L. Prepare sodium bicarbonate (NaHCO) that is respectively 4 times of equivalents and 2 times of equivalents relative to the iron raw material 3 ) and sodium hydroxide (NaOH) as neutralizers. The neutralizer and ion-exchanged water were mixed and stirred to obtain an alkaline aqueous solution with a pH of 12, and an aqueous ferrous sulfate solution was added to the alkaline aqueous solution to neutralize and precipitate to obtain a suspension (step A). In addition, the temperature was controlled such that the liquid temperature at the time of this neutralization and thereafter was kept constant at 0°C. The concentration of Fe in the suspension containing ferrous iron was 0.05 mol / L. This neutralization produces ferrous carbonate, ferrous hydroxi...
Embodiment 2
[0061] Iron oxyhydroxide particles were obtained in the same manner as in Example 1, except that the pH of the alkaline aqueous solution was set to 10 in step A.
[0062] For the iron oxyhydroxide particles, the same measurement as in Example 1 was carried out. The results are shown in Table 1.
Embodiment 3
[0064] Iron oxyhydroxide particles were obtained in the same manner as in Example 1, except that the pH of the alkaline aqueous solution was set to 10 in step A, and the oxygen-containing gas was blown in bubbles with a diameter of 1.7 mm in step B.
[0065] For the iron oxyhydroxide particles, the same measurement as in Example 1 was carried out. The results are shown in Table 1.
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