The invention relates to A-site double-
rare earth ion co-doped antiferroelectric
ceramic as well as a preparation method and application thereof. The general formula of the
ceramic structure is Pb (1.01-1.5 n-y) MnCay (Zr < 1-x > Snx) 0.995 O3, wherein M comprises a
rare earth element, and 0.3 lt; x is less than or equal to 0.5, 0.02 lt; n is less than or equal to 0.04, 0lt; y < = 0.03; the
ceramic is constructed by multi-element A-site substitution, so that the stability of the antiferroelectric phase of the ceramic is improved, the densification growth is also promoted, and the breakdown
electric field of the antiferroelectric ceramic is improved; meanwhile, the growth size of ceramic
crystal grains can be inhibited, and the breakdown
electric field of the ceramic is improved; the thickness of the anti-ferroelectric ceramic is 25-40 [mu] m, the
energy storage density is 23-35 J / cm < 3 >, and the
energy storage efficiency is up to 70% or above; compared with the prior art, the
energy storage density of the prepared ceramic material is increased by 6-25 J / cm < 3 >, and the
discharge time is remarkably shortened.