652results about How to "Excellent curability" patented technology

The present invention has its object to provide a curable composition which comprises a guanidine compound as a non-organotin type catalyst, is less discolored, has good surface curability, depth curability, strength rise and adhesiveness, and can retain the curability even after storage; the above object can be achieved by a curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): —SiX3 (1) (wherein X represents a hydroxyl group or a hydrolyzable group and the three X groups may be mutually the same or different), (B) a guanidine compound (B-1) as a silanol condensation catalyst, and (C) a plasticizer, wherein the content of the component (B-1) is not lower than 0.1 part by weight but lower than 8 parts by weight per 100 parts by weight of the component (A), and a non-phthalate ester plasticizer accounts for 80 to 100% by weight of the (C) component plasticizer.

The present invention has its object to provide a curable composition which comprises an amidine compound as a non-organotin catalyst and shows good elongation, flexibility, surface curability, depth curability and adhesiveness; the above object can be achieved by a non-organotin curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): —SiR1X2; (B) an amidine compound (B-1) as a silanol condensation catalyst; and (C) a carboxylic acid, wherein the ratio between the number of moles (b) of all nitrogen atoms in the (B-1) component of the composition and the number of moles (c) of all carboxyl groups in the (C) component of the composition, namely the ratio (b) / (c), is higher than 2.

The present invention provides a photocurable ink composition for ink jet recording with excellent curability. The photocurable ink composition for ink jet recording includes polymerizable compounds, a photopolymerization initiator, and a colorant, wherein the polymerizable compounds include a vinyl ether group-containing (meth)acrylate represented by general formula (I):CH2═CR1—COOR2—O—CH═CH—R3  (I)(wherein R1 is a hydrogen atom or a methyl group, R2 is a divalent organic residue having 2 to 20 carbon atoms, and R3 is a hydrogen atom or a monovalent organic residue having 1 to 11 carbon atoms) and phenoxyethyl (meth)acrylate.

The present invention relates to a process for producing a three-dimensional model in which a binder has good discharge properties and curability. The process for producing a three-dimensional model is a process for producing a three-dimensional model that includes a step (layer formation step) of forming above a support a layer of a powder material, the layer having a predetermined thickness, a step (cross-sectional shape formation step) of imagewise bonding the powder material layer by a binder according to sliced cross-sectional data of a modeled object so as to give a cross-sectional shape, and sequentially repeating the above steps, the binder having a viscosity at 25° C. of 5 to 100 mPa·s.

The invention relates to a solvent-free organic silicon pressure-sensitive adhesive. The organic silicon pressure-sensitive adhesive comprises the following components in part by mass: 100 parts of polydimethylsiloxane of which the end group is alkenyl; 1 to 300 parts of polydimethylsiloxane of which the end group is hydroxyl; 1 to 50 parts of MQ resin, 1 to 30 parts of polyisobutylene, 20 to 200 parts of diluting agent, 0.1 to 5 parts of crosslinking agent and a platinum catalyst capable of curing the organic silicon pressure-sensitive adhesive. The invention also relates to a preparation method of the organic silicon pressure-sensitive adhesive. The organic silicon pressure-sensitive adhesive has the characteristics of high initial tack, long residual action, proper peeling strength, drug penetration and the like, is nontoxic, environmentally-friendly and reusable, and can be prepared into pressure-sensitive adhesive tapes, medical pressure-sensitive adhesive strips and other functional materials requiring the pressure-sensitive performance.

Provided is a UV curable type ink-jet ink composition containing a monomer A which is expressed by the following general formula (I):CH2═CR1—COOR2—O—CH═CH—R3  (I)(in the formula, R1 is a hydrogen atom or methyl radical, R2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), a compound B containing five or more (meth)acryloyl radicals per molecule, and a monofunctional (meth)acrylate C having an aromatic ring skeleton, wherein the monofunctional (meth)acrylate C which is in a range of 5 to 35 wt % with respect to the total weight of the ink composition is contained.

The present invention has its object to provide a curable composition which has good curability and adhesiveness while containing an organotin-free catalyst. The present invention provides a one package curable composition which comprises (A) a polyoxyalkylene polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a (meth)acrylic ester polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond and compatible with the component (A), and (C) (c1) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and / or (c2) a metal carboxylate of which the carbon atom adjacent to a carbonyl group is a quaternary carbon.

The invention relates to a latent microcapsule curing agent initiating thermosetting epoxy resin curing at medium temperature and a preparation method of an adhesive thereof. The latent microcapsule curing agent is technically characterized in that the high-activity medium temperature curing agent is taken as a core material, thermoplastic high polymer microspheres are taken as a wall material, the solvent evaporation technology is adopted for preparing the latent microcapsule curing agent with better curing performance and latent performance, and the latent microcapsule curing agent can be applied to an epoxy resin system for preparing the single-component medium temperature curing epoxy resin adhesive. Microcapsules prepared by the method are high in capsule core content, smooth in surfaces, narrow in particle size distribution and good in compatibility with matrix epoxy resin and can be better dispersed in the epoxy resin; and the prepared single component adhesive can realize curing at the medium temperature, the storage period at room temperature is longer and the tensile shear strength performance can be further improved.

The sealing composition for liquid crystal displays according to the invention is characterized by consisting of a one-pack type photo- and thermo-setting resin composition comprising (1) a solid epoxy resin having a softening point of 40 DEG C or above as determined by ring and ball method, (2) an acrylate ester monomer and / or a methacrylate ester monomer or an oligomer thereof, (3) a thermoplastic polymer obtained by copolymerizing an acrylate ester monomer and / or a methacrylate ester monomer with a monomer copolymerizable therewith and having a softening point of 50 to 120 DEG C as determined by ring and ball method, (4) a photoradical polymerization initiator, and (5) a latent epoxy curing agent. The photo- and thermo-setting sealing composition for liquid crystal displays is applicable to the dispenser method, can give a cured product having excellent characteristics through photosetting in the first step, and permits the formation of stable cell gaps. Further, the sealing composition is inhibited from polluting liquid crystal in thermosetting in the second step and attains excellent setting properties in the shaded areas and high adhesion reliability.

There is a tin-free curable composition having (A) one or more organic polymers having a reactive-silicon-containing group, wherein at least one polymer has a main chain skeleton selected from the group consisting of polyoxyalkylene polymers, saturated hydrocarbon polymers, and (meth)acrylic acid ester polymers; (B) from 0.001 to 20 parts by weight for 100 parts by weight of the organic polymer(s) (A) of a silanol condensation catalyst consisting of one or more metal amidine complexes and one or more amine carboxylate salts, (C) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an epoxysilane, an epoxysiloxane, an aminosilane, a carboxysilane, a carboxysiloxane, an alkylamidosilane, an alkylamidosiloxane, an arylamidosilane, an arylamidosiloxane, an alkoxyaminosilane, an alkaryaminosiloxane, an alkoxycarbamatosilane, an alkoxycarbamatosiloxane, and combinations of two or more thereof; and (D) at least one adhesion promoter chosen from a silane or siloxane other than the compounds listed under (C). There is also a cured polymer formed from the tin-free curable composition.

A piezoelectric structure includes a vibrational plate; a piezoelectric film; the vibrational plate including a layer of a monocrystal material, a polycrystal material, a monocrystal material doped with an element which is different from an element constituting the monocrystal material, or a polycrystal material doped with an element which is different from an element constituting the polycrystal materials, and oxide layers sandwiching the aforementioned layer, the piezoelectric film has a single orientation crystal or monocrystal structure.

A surface treatment agent, which contains: (A) a hydrolyzable metal alkoxide or a hydrolyzate thereof, (B) a fluorocompound containing a perfluoroalkyl group and a functional group reactive with the hydrolyzable metal alkoxide (A), and (C) an adhesion improvement agent, can provide a film having transparency and durability while maintaining excellent soil releasability and low refractive index.

An ink composition is provided that includes a perfluoroalkyl group-containing polymer, a polymerizable monomer, and a radical polymerization initiator, in which at least 80 wt % of the polymerizable monomer is a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes a step of discharging the ink composition onto a recording medium and a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material obtained by the inkjet recording method, and a process for producing a molded printed material that includes a step of forming an image by discharging the ink composition onto a support by an inkjet method, a step of irradiating the image thus obtained with actinic radiation so as to cure the ink composition and obtain a printed material having the image cured on the support, and a step of molding the printed material.

An epoxy resin mold plastic and its production are disclosed. The mold plastic consists of liquid-crystal epoxy resin, methyl-phenolic epoxy resin, epoxy resin containing biphenyl unit structure, melamine modified linear phenolic resin, silicone micro-powder, imidazo curing improver, toughening agent and silane coupling agent. The process is carried out by treating silicone micro-powder in mixer by coupling agent for 2-5mins, adding into other components, mixing for 3-5mins, melt milling at 95-135 degree for 3-5mins, cooling, crushing, mesh screening, pressing into material cake and storing below 6degree. Its advantages include low thermal expansion coefficient, excellent heat and fire resistances, better toughness and fluidity, no phosphor, no antimony and environmental pollution. It can be used to pack large-scale circuit and electronic devices.

The present invention has its object to provide a curable composition not containing any organotin type curing catalyst of concern because of the toxic feature thereof, or any volatile compound, excellent in curability and storage stability and, further, capable of providing cured products excellent in strength and elongation. The above object can be achieved by a curable composition which includes: an organic polymer (A) containing a hydrolyzable silyl group in a molecule; an amidine compound (B); a plasticizer (C); and an amino group-containing silane coupling agent (D), wherein the amidine compound (B) is preliminarily mixed and dissolved and / or dispersed in the plasticizer (C) and the amino group-containing silane coupling agent (D), and the resultant mixture is added to the reactive silyl group-containing polymer (A).

An ink composition which is used for active energy ray-curable inkjet printing, has excellent curability or adhesiveness to multiple base materials while having low viscosity, and exhibits excellent non-yellowing properties of the printed matter is provided. The composition comprises a polymerizable monomer (A) and photopolymerization initiators (B), the polymerizable monomer comprising 2-(2-vinyloxyethoxy)ethyl acrylate (A-1), and the photopolymerization initiators comprising oligo(2-hydroxy-2-methyl-1-(4-(1-methylvinyl)phenyl)propanone) (B-1) and other initiator (B-2).

The invention relates to a curable leaking stoppage spacer fluid and a preparation method thereof. The spacer fluid comprises the following components according to parts by weight: 450 parts of fresh water, 400-600 parts of curing agent, 3-10 parts of stabilizing agent, 2-20 parts of suspending agent, 10-40 parts of activating agent, 10-60 parts of activating auxiliary agent and 10-700 parts of density regulator, wherein the curing agent is slag powder; the stabilizing agent is clay; the suspending agent is sodium bentonite or calcium bentonite; the activating agent is the mixture of sodium hydroxide and sodium carbonate; the activating auxiliary agent is the mixture of sodium silicate and calcium oxide; and the density regulator can be iron ore powder for well cementation or coal ash hollow microsphere. After the curable leaking stoppage spacer fluid is cured, the lamination capability can reach more than 5MPa, the spacer fluid shows good chemical compatibility with mud and cement paste and good curing performance between 30-130 DEG C; after the spacer fluid is cured, the appearance of a formed cured body has non volume contraction; therefore, the spacer fluid can effectively pack a stratum dropping passage and provides guarantees for the follow-up operation of oil and gas wells.

The invention belongs to the field of UV curable high-molecular materials and in particular relates to castor-oil-based hyperbranched UV curable polyurethane acrylate and a preparation method and application thereof. The preparation method comprises the steps: firstly, dyhydroxyl propionic acid and castor oil are prepared into hydroxyl terminatedend capped polyfunctional hyperbranched resin through decompression esterification reaction; then a mixture of polyisocyanate and a catalyst is added to react for 2 to 3h; then the certain amount of active diluting monomer is added in stirring to dissolve isocyanato terminatedend capped hyperbranched resin; finally, metric (methyl) acrylate hydroxyalkyl ester is added to react with a polymerization inhibitor for 1.5 to 2.5h to obtain the castor-oil-based hyperbranched UV curable polyurethane acrylate. According to the castor-oil-based hyperbranched UV curable polyurethane acrylate, the castor oil is utilized as a polyurethane raw material; thus, the application range of natural renewable biomass grease products are expanded, the added value of the natural renewable biomass grease products is improved, and the positive popularization significance is achieved.

Provided is a curable composition excellent in curability and mechanical properties as well as a cured product thereof. Specially provided is a curable composition containing a vinyl-based polymer (I) having one or more crosslinkable functional groups at a terminus on average and a nucleophilic agent (II) and a cured product obtained by curing the curable composition. Preferably, the curable composition of the invention further contains an epoxy resin (III).

An object of the present invention is to provide a curable composition which has good curability and good tensile properties (high elongation), and contains a smaller amount of a dibutyltin compound which is regarded as toxic. The curable composition of the present invention comprises the following components (A) and (B) at a weight ratio of (A) / (B) of 25 / 75 to 75 / 25, (A) a reactive silyl group-containing organic polymer having, as a silicon-containing group cross-linkable by siloxane bond formation, a group represented by the formula (1): —SiX3, and (B) a reactive silyl group-containing organic polymer having, as a silicon-containing group cross-linkable by siloxane bond formation, a moiety represented by the formula (2): —O—R1—CH(CH3)—CH2—Si (R23-a)Xa wherein a is 1 or 2.

This invention provides a multilayer coating film-forming method which comprises applying a first clear paint onto a coating object, applying onto so formed first clear coating film which is either uncured or cured by heating, a second clear paint such that its heat-cured film thickness falls within a range of 2-15 μm, and forming the second clear coating film, (a) the first clear paint and second clear paint comprising hydroxyl-containing resin as the base resin and polyisocyanate compound as the crosslinking agent, and (b) when the coating film formed by applying a paint to a cured film thickness of 40 μm and curing it by heating at 140° C. for 30 minutes is measured of its dynamic viscoelasticity at a frequency of 11 Hz, the first clear paint forming the first clear coating film having a glass transition temperature of lower than 70° C. and tan δ (=loss elastic modulus / storage elastic modulus) at 80° C. of less than 0.4, and the second clear paint forming the second clear coating film having a glass transition temperature of at least 70° C.

There are provided a novel ethylenically unsaturated group-containing isocyanate compound, a process for producing the same, and a reactive monomer produced from the isocyanate compound, a reactive polymer and its use. The ethylenically unsaturated group-containing isocyanate compound according to the present invention is represented by formula (I).

The present invention has its object to provide a curable composition which allows slight bleedout of a liquid compound to occur to the cured product and shows good curability and adhesiveness using a non-organotin catalyst, an amine compound, as a silanol condensation catalyst.The present invention relates to a non-organotin-based curable composition which comprises:(A) an organic polymer having a silicon-containing group capable of crosslinking by siloxane bond formation, and(B) a specific amidine compound and / or a guanidine compound having a melting point of not lower than 23° C., as a silanol condensation catalyst.

A curable resin composition containing a specific vinyl compound obtained by vinylation of a terminal of a bifunctional phenylene ether oligomer having a polyphenylene ether structure in a molecule and a specific bismaleimide compound having at least two maleimide groups in a molecule, a curable film comprising the above composition, a cured product obtained by curing the above composition, and a film obtained by curing the curable film. The above resin composition is excellent in curability even in the presence of oxygen, is curable at a low temperature and is capable of giving a cured product having a low dielectric constant, a low dielectric loss tangent, high heat resistance, excellent mechanical properties, excellent chemical resistance and excellent flame retardancy.

A curable organopolysiloxane composition comprising at least the following components: (A) a linear diorganopolysiloxane with a mass average molecular weight of at least 3,000, (B) a branched organopolysiloxane, (C) an organopolysiloxane having, on average, at least two silicon-bonded aryl groups and, on average, at least two silicon-bonded hydrogen atoms in one molecule, and (D) a hydrosilylation reaction catalyst; has excellent curability and, when cured, forms a flexible cured product of high refractive index, optical transmissivity, excellent adherence to various substrates, high hardness and slight surface tack.

The present invention provides an energy ray-curable inkjet ink composition which is excellent in stretchability for a printed film and, at the same time, is excellent in curability, adherability and the continuous discharge property. The present invention relates to an energy ray-curable inkjet ink composition containing at least a coloring material, 8 to 60% by mass of a monofunctional monomer (A) having a glass transition temperature of lower than −25° C., 25 to 40% by mass of a difunctional oligomer (B) having an elongation rate of 130% or more at 25° C. when a single oligomer is polymerized, at least one kind of a photopolymerization initiator (C) selected from the group consisting of an acylphosphine oxide initiator (C-1), and a mixed initiator (C-2) of an α-aminoalkylphenone initiator and a thioxanthone initiator, and a surface tension conditioner (D).

Provided is an ink jet recording method including: discharging an ultraviolet ray-curable ink, which has a viscosity at 20° C. of 25 mPa·s or less and an average equivalent of polymerizable unsaturated double bond of 100 to 150, from a head onto a recording medium at a discharge temperature of 30° C. to 40° C.; and irradiating the ultraviolet ray-curable ink, attached onto the recording medium, with ultraviolet rays emitted from a light source to cure the ultraviolet ray-curable ink.