Described are agrochemical compositions which comprise of one or more one agrochemical active ingredient(s) and alkylenediol -modified polysiloxanes of the general formula (I), wherein R<1> are alkyl radicals having 1 to 4 carbon atoms or aryl radicals, wherein at least 80% of the radicals R<1> are methyl radicals, R<2> in the molecule are identical or different and can have the following definitions (a), in which R<3> is a hydrogen or alkyl radical, R<4> is a hydrogen, alkyl or carboxyl radical, c is a number from 1 to 20, d is a number from 0 to 50, e is a number from 0 to 50 or b) correspond to the radical R<1>, with the proviso that in the average molecule at least one radical R<2> has the definition (a), a is a number from 1 to 200; b is a number from 0 to 10; and optionally one or more other agrochemically acceptable ingredients. The agrochemical compositions of the invention have enhanced efficacy, enhanced hydrolytic stability and / or decreased foaming properties.