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76 results about "Methyl radical" patented technology

Methyl (also systematically named trihydridocarbon) is an organic compound with the chemical formula CH•₃ (also written as [CH₃]•). It is a metastable colourless gas, which is mainly produced in situ as a precursor to other hydrocarbons in the petroleum cracking industry. It can act as either a strong oxidant or a strong reductant, and is quite corrosive to metals.

Organic working fluids

The present invention provides an improved, commercially available organic working fluid, which is operable under a broad range of temperatures, is thermally stable, has a high auto-ignition temperature, low freezing point and high critical temperature and is benign to the environment, and safe for human use. Such an organic working fluid is useful in organic Rankine cycle (ORC) power plants or units and other systems of the like; as an intermediate fluid for heat-recovery wherein heat from various heat sources is transferred using the intermediate fluid to a further working fluid and converted into work, and the intermediate fluid is also exploited to produce electricity. Such organic working fluids are also operable as heat transfer fluids either in ORC power plants or units or in other heat transfer systems. For this purpose the present invention presents a working fluid comprising at least one highly branched, heavy iso-paraffin hydrocarbons, or a mixture of two or more of such hydrocarbons. Preferably, at least one highly branched iso-paraffin hydrocarbon is present as the major component (i.e. at least 50% by volume) in the working fluid. A preferred sub-class of the class of the branched iso-paraffins which are suitable to be incorporated in organic working fluids of the present invention includes 8 to 20 carbon atom-containing hydrocarbons having at least one methyl radical (CH3) arranged to achieve a highly stable compound.
Owner:ORMAT TECH INC

Method for preparing 3-methyl-4-nitrobenzoic acid by oxidizing with nitric acid

InactiveCN104447348AReasonable control of reaction temperatureReasonable control of reaction pressureOrganic chemistryOrganic compound preparationChromium trioxideReaction temperature
The invention relates to a method for preparing 3-methyl-4-nitrobenzoic acid by oxidizing with nitric acid. The method comprises the steps of carrying out oxidation reaction, neutralizing, extracting, decolorizing and acidifying, wherein diluted nitric acid serves as an oxidant, and 2,4-dimethyl-nitrobenzene serves as a basic raw material. The feed ratio, the reaction temperature, the reaction pressure and the reaction time are controlled reasonably, thus the problems of low reaction conversion rate and generation of many by-products are solved. Because the diluted nitric acid serves as the oxidizing agent and replaces potassium permanganate, potassium dichromate, chromium trioxide and other strong oxidizing agents which are high in cost and are difficult to recover, and the generated waste acid can be recycled, the cleanness of industrial synthesis reaction can be improved, and the pollution to environment can be reduced. The method provided by the invention has the advantages that the reaction yield is improved to over 50% from the initial 27%, the reaction condition is mild, the production and operation safety is high, the reaction equipment is simple, and the raw materials including nitric acid and 2,4-dimethyl-nitrobenzene are wide in supply and low in cost and are suitable for large-scale industrial production.
Owner:GANSU YINGUANG CHEM IND GRP CO LTD

Thermal desorption, gas-phase separation and thermal cracking system based on ethylation derivation of methyl mercury

The invention discloses a thermal desorption, gas-phase separation and thermal cracking system based on ethylation derivation of methyl mercury, comprising a thermal desorption part, a gas-phase separation part, a thermal cracking part, a gas flowmeter, a Teflon FEP pipeline and a pressure regulating and temperature control switch chamber, wherein the thermal desorption part comprises a thermal desorption heater strip switch, a thermal desorption heater strip time control switch, a thermal desorption heater strip pressure regulator, a pressure regulating knob of the thermal desorption heater strip pressure regulator, a thermal desorption heater strip and a Tenax adsorption pipe; the gas-phase separation part comprises a heater jacket, a heater jacket switch, an OV-3 packed column and a heater jacket temperature control plate; and the thermal cracking part comprises a thermal cracking heater strip switch, a thermal cracking heater strip time control switch, a thermal cracking heater strip pressure regulator, a pressure regulating knob of the thermal cracking heater strip pressure regulator, a thermal cracking heater strip and a quartz pipe. The system realizes the aim of integration of thermal desorption, gas-phase separation and thermal cracking devices, and simultaneously, each part can be individually operated, thereby saving the analysis time, having low manufacturing cost and greatly reducing experiment cost.
Owner:OCEAN UNIV OF CHINA

Bi-radical compound composed of triaryl methyl radical and nitroxide radical and salt thereof and preparation method and application of bi-radical compound composed of triaryl methyl radical and nitroxide radical and salt thereof

ActiveCN108794510AExcellent frequency matchingHigh CE efficiencyOrganic chemistryWater resource assessmentMagic angle spinningSolubility
The invention provides a bi-radical compound composed of a triaryl methyl radical and a nitroxide radical and salt thereof and a preparation method and application of the bi-radical compound composedof the triaryl methyl radical and the nitroxide radical and the salt thereof. A structural formula of the bi-radical compound is as shown in the formula 1; the formula is shown in the description; thepreparation method comprises the steps that a compound A1 and a compound A2 are subjected to acid amide condensation reaction to obtain a compound A3; the compound A3 and a compound A4 are subjectedto acid amide condensation reaction to obtain the bi-radical compound and the salt thereof. The portion, provided with both the nitroxide radical and the triaryl methyl radical, of a bi-radical polarization agent has the following advantages that the frequency matching ability is better, and the CE efficiency is higher; under a magic angle spinning condition, a depolarization effect does not exist, and a high field DNP enhancing effect is better; exchange interaction is stronger; the water solubility is good, so that the DNP enhancing multiple is high; by modifying R1, R2, R3, R4, R5 and R6 groups, exchange interaction can be improved moderately, bi-radical relaxation time can be prolonged moderately, and the bi-radical water solubility can be improved moderately, so that the DNP propertyof the polarization agent is improved.
Owner:TIANJIN MEDICAL UNIV

Multi-bed reaction device for preparing hydrogen by sodium borohydride alcoholysis

The invention discloses a multi-bed reaction device for preparing hydrogen by sodium borohydride alcoholysis. The multi-bed reaction device comprises a sodium borohydride storage tank, a flow controller, a sprayer, a catalyst reaction bed, a heat exchanger and a product recovery tank; the sodium borohydride storage tank is used for storing an alkaline sodium borohydride methanol solution; the flow controller is used for adjusting the flow velocity and flow rate of the solution; the sprayer is arranged at the top of the hydrogen production reaction tank; the catalytic reaction bed comprises at least two layers of catalyst reaction beds; the heat exchanger is used for regulating and controlling the temperature of the reaction tank. The product recovery tank is placed at the bottom of the reaction tank to collect the reactants sodium tetramethylborate for following recovery and reuse. The multi-bed reaction device is capable of improving the utilization rate of the reactants and realizing the precise control over hydrogen production quantity. The contact of the reactants with the catalyst is expanded, the liquid-solid separation is more thorough, the influence of concentration difference gradient is eliminated, furthermore the catalyst utilization rate is improved, and the cost of precious metal is reduced.
Owner:XUZHOU NORMAL UNIVERSITY

Sodium borohydride alcoholysis hydrogen production device with bidirectional spraying feeding

The invention discloses a sodium borohydride alcoholysis hydrogen production device with bidirectional spraying feeding. The sodium borohydride alcoholysis hydrogen production device comprises a sodium borohydride storage tank, a flow controller, an upper sprayer, a lower sprayer, a catalyst reaction bed, a heat exchanger and a product recycling tank, wherein the sodium borohydride storage tank is used for storing an alkali sodium borohydride methanol solution; the flow controller is used for adjusting the flow velocity and the flow of a reaction solution; the sprayers are arranged at the top end and the lower end of a hydrogen production reaction tank; the catalyst reaction bed comprises a catalyst and a fixed bed; the heat exchanger is used for regulating and controlling the temperature of the reaction tank; the product recycling tank is arranged at the bottom of the reaction tank; and a reaction product, namely methyl boron sodium, is collected for later use. By adopting the device, a precise controllable hydrogen production amount is achieved, influence of concentration difference gradients of reaction solutions is eliminated, an effective contact area of reactants with catalysts is increased, relatively thorough gas-liquid-solid separation is achieved, the utilization rates of reaction raw materials and catalysts are increased, and the hydrogen production cost is lowered.
Owner:XUZHOU NORMAL UNIVERSITY
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