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72results about How to "Increase the effective reaction area" patented technology

Proton exchange membrane water electrolyser structure and anode plate

The invention discloses a proton exchange membrane water electrolyser structure and an anode plate. The proton exchange membrane water electrolyser structure comprises the anode plate, an anode diffusion layer, a CCM membrane electrode, a cathode diffusion layer and a cathode plate. The anode plate comprises a fluid distribution area, an arc flow channel reaction area and a dotted flow field reaction area; and an anode plate fluid distribution area is an arc-shaped stepped flow field area which is gradually reduced from two sides to the circle center, an ellipse-like distribution structure is arranged in the middle of the area, the part, close to a water inlet, of the anode plate is an arc-shaped flow channel reaction area, and a flow field tail end area is a dot-shaped flow field reaction area. According to the invention, uniform diffusion of reaction water in each flow channel after entering a flow field is ensured by arranging the ellipse-like distribution structure in a fluid distribution area; the flow resistance of reaction water is reduced through an arc-shaped flow channel of the arc-shaped flow field, and the transmission efficiency of the reaction water is improved; and through the dot-matrix type structure of the dot-shaped flow field, formation of bubble plugs is reduced, the mass transfer capacity of reaction water is enhanced, and then the performance of the electrolytic cell is improved.
Owner:WUHAN UNIV OF TECH

Air-breathing membrane-free fluid fuel cell provided with integrated cylindrical anode

The invention discloses an air-breathing membrane-free fluid fuel cell provided with an integrated cylindrical anode. The air-breathing membrane-free fluid fuel cell comprises a cathode cover plate, arunner and a cell base plate, a cathode air breathing hole is formed in the cathode cover plate, and an air-breathing cathode is arranged below the cathode air breathing hole. The air-breathing membrane-free fluid fuel cell is characterized in that the runner is arranged between the cathode cover plate and the cell base plate; a cylindrical metal tube is arranged in the runner; a catalyst layer is coated on the outer surface of the cylindrical metal tube; the cylindrical metal tube is arranged parallel to the air-breathing cathode; the front part of the cylindrical metal tube is a hollow tube, and the rest part is a solid tube; a plurality of overflow ports are formed in the tube wall at a junction of the hollow tube and the solid tube along the circumferential direction; a fuel inlet isformed in the front end of the cylindrical metal tube; a waste liquor outlet is formed in the cell base plate; and the waste liquor outlet is communicated with the runner. The air-breathing membrane-free fluid fuel cell disclosed by the invention can enhance fuel transmission, system integration is facilitated, and cell performance is improved; and the air-breathing membrane-free fluid fuel cell can be widely applied to the fields of energy sources, chemical industry and environmental protection.
Owner:CHONGQING UNIV

High-activity hollow-out silver powder and preparation method thereof

The invention relates to high-activity hollow-out silver powder and a preparation method thereof and belongs to the field of preparation for high-activity silver powder. The silver powder particles are of hollow-out sphere-like shapes; the diameters of the particles are 35-150 micrometers; the specific area of the particles is not smaller than 25 square meters / gram. The silver powder disclosed by the invention is hollow-out sphere-like powder; in addition, a large quantity of nano holes exist in each particle; the inside of each particle is of a three-dimensional mesh structure; the holes are mutually communicated; by using a prepared silver oxide anode, the effective reaction area of the electrode can be effectively increased, the electric current density is reduced, further the polarization of the electrode is reduced and output performances (current and voltage) of a battery are improved; the voltage of the battery and the utilization rate of active substances are improved; in addition, under the condition that the porosity is ensured, compared with the traditional silver powder, the high-activity silver powder has the advantages that the thickness of the pressed silver oxide electrode is thinner under the condition of equal quantity, further the mass transfer efficiency is improved and the utilization rate of anode active substances is improved.
Owner:GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS BEIJNG

Porous flow field fuel cell monomer without bipolar plate and series-parallel electric pile structure

The invention discloses a porous flow field fuel cell monomer without a bipolar plate. Themonomer comprises an anode porous layer, an anode gas diffusion layer, a membrane electrode, a cathode gas diffusion layer, a cathode porous layer, a cathode baffle plate, a cooling porous layer and an anode baffle plate, the anode porous layer or the cathode porous layer or the cooling porous layer is formed by embedding a porous material into a solid frame, and the cathode baffle separates the cathode porous layer from the cooling porous layer. The invention also provides a series-parallel electric pile structure of a fuel cell. Through reasonable design of the structure, porosity and permeability, the flow resistance of a porous flow field is effectively reduced, and the fluid distribution uniformity is improved, so that the effective utilization rate of an electrode reaction area is increased, and the performance of the fuel cell is improved. By using the design of sharing the anode porous layer or sharing the cooling porous layer, fuel cell monomers are connected in parallel to form the Ns x Np section series-parallel electric pile structure, so that the size of an electric pile is reduced, and the power density of the electric pile is improved.
Owner:GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI

Crystal silicon dioxide/carbon porous composite material and preparation method thereof

The invention discloses a crystal silicon dioxide/carbon porous composite material and a preparation method thereof. Three-dimensional network-shaped crystal silicon dioxide is evenly distributed on the surfaces of carbon particles, so that the crystal silicon dioxide/carbon porous composite material is formed. The silicon dioxide is tetragonal crystals and belongs to a P41212 space group, a=b=4.973, and c=6.924. The porosity of the crystal silicon dioxide/carbon porous composite material is 40%-80%, the peso-position hole diameter is 100-2000 nm, and the electrical resistivity is 0.10-80 ohmcm. The crystal silicon dioxide/carbon porous composite material comprises, by mass, 30%-90% of silicon dioxide and 10%-70% of carbon materials. The preparation method at least includes the following steps of mixing, forming and sintering. According to the step of mixing, the silicon dioxide particles, the carbon materials and a fluxing agent are evenly mixed, so that a powder-like mixture is obtained. According to the step of forming, the powder-like mixture is formed so that a porous block body can be obtained. According to the step of sintering, the obtained porous block body undergoes high-heat treatment in an inert atmosphere, and after the fluxing agent is removed, the three-dimensional network-shaped crystal silicon dioxide/carbon porous composite material is obtained.
Owner:GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS BEIJNG

Preparation method of ruthenium-iridium-titanium ternary metal mesh electrode containing nano tip structure

The invention belongs to the field of preparation of electrochemical electrodes, and discloses a preparation method of a ruthenium-iridium-titanium ternary metal mesh electrode containing a nano tip structure; the method comprises the following steps: (1), performing pretreatment of a titanium wire mesh substrate, including removal of a substrate oxide film and removal of oil stains; (2), performing acid etching; (3), forming a nano tip; (4), performing preparation, coating and thermal oxidation of middle-layer coating liquid; and (5), performing preparation, coating and thermal oxidation of an active layer coating solution. The surface of the prepared electrode channel contains a large number of nano tip structures, the effective reaction area of the electrode is increased, the collision opportunity of reactants and the surface of the electrode is increased, and mass transfer is promoted. The method is low in equipment requirement, low in production cost, simple to operate and easy to regulate and control. Meanwhile, the invention also discloses application of the ruthenium-iridium-titanium metal mesh electrode containing the nano-tip structure prepared by the invention to total nitrogen removal performance evaluation and control experiments in actual production wastewater, and high total nitrogen removal efficiency and low cost and energy consumption of wastewater treatment are realized.
Owner:DALIAN UNIV OF TECH

Three-phase fluidized bed for sewage treatment

The invention relates to the field of sewage treatment equipment, and discloses a three-phase fluidized bed for sewage treatment. The three-phase fluidized bed for sewage treatment comprises a separator pipe body, a flow isolating pipe, a three-phase separator, an exhaust pipe, a water inlet pipe, an air inlet pipe and a blow-off pipe; the flow isolating pipe is fixedly arranged in the middle of an inner cavity of the separator pipe body, the top end of the flow isolating pipe is fixedly connected with the bottom of the three-phase separator in a sleeving mode, and the three-phase separator isarranged at the top of the inner cavity of the separator pipe body. According to the three-phase fluidized bed for sewage treatment, through the design of the water inlet pipe located in the flow isolating pipe, a spiral packing auger is driven to rotate by the air intake power of the air inlet pipe; fluid in the flow isolating pipe upwells under the rotating action of the spiral packing auger, so that the fluid in the flow isolating pipe overcomes the gravity and resistance of the fluid to keep an up-flow state, the lifting efficiency of the fluid in the inner cavity of the flow isolating pipe is effectively guaranteed, the effective reaction area of the fluid is guaranteed to be kept in a large state, and the treatment effect of the three-phase fluidized bed is good.
Owner:曾新凤

Electrochemical filter for removing total nitrogen in water

The invention belongs to the technical field of water treatment, and discloses an electrochemical filter for removing total nitrogen in water. A water body to be treated is continuously pumped into a cathode reaction chamber through a water inlet, sequentially flows through a three-dimensional nano tip porous cathode and an anode under certain current and voltage, and reacts for a certain period of time, and finally, nitrate nitrogen, ammonia nitrogen and nitrite nitrogen in the water body are converted into nitrogen. The mass transfer distance from a substance to the surface of an electrode can be shortened by utilizing a micron-sized aperture electrode, the collision opportunity of pollutants and the electrode in the liquid flowing process is increased by the nano-tip structure in the pore channel, and meanwhile, reaction ions are limited in the internal channel of the three-dimensional nano-tip porous electrode; and the repulsive interaction of like ions under the action of electric field force is weakened, and the problems that a traditional electrochemical reactor electrode is small in effective reaction area, too large in distance between two electrodes, low in mass transfer efficiency and low in reaction efficiency, reactants are rejected by the electrode, reactant gas is accumulated, and the reactor is difficult to amplify are solved.
Owner:DALIAN UNIV OF TECH

Method for preparing aluminum/hydrogen peroxide monomer batteries

The invention discloses a method for preparing aluminum/hydrogen peroxide monomer batteries, and the method is used for hermetically and fixedly assembling an anode part and a cathode part into an integral monomer battery, wherein the anode part and the cathode part are successively prepared; and the method is characterized in that granular spacers are fully adhered to one surface of the anode part at a certain interval, and the interval is used as an anode channel; and a through trough is pressed on one surface of a cathode substrate of the cathode part and used as a cathode channel. In the invention, an anode channel is formed by using granular spacers, thereby reducing the weight of the battery, reducing the pressure loss of an electrolyte flowing through the anode part, better facilitating the discharge of hydrogen and reaction products AlO2<->, and improving the specific energy and energy density of the battery; a cathode channel is pressed on the cathode part so as to form a catalyst layer-flow field plate two-in-one structure, thereby reducing the thickness and weight of the battery; an oxidizing agent can directly flow in the three-dimensional catalyst layer, and the mass transfer of hydrogen peroxides is smooth, thereby improving the specific energy of the battery; and an ion exchange membrane achieve an effect of transformation between a double chamber structure and a single chamber structure of the battery, and is suitable for energy type power battery packs of low speed underwater equipment.
Owner:CHINA ELECTRONIC TECH GRP CORP NO 18 RES INST

Plate-frame immobilized cell membrane bioreactor and application thereof

The invention discloses a plate-frame immobilized cell membrane bioreactor. The bioreactor is characterized in that cover plates are arranged on the outmost layers; the middle part is formed by successively arranging and assembling frames and flat-shaped immobilized cells; the frames include W frames and a C frame; the W frames represent the frames for the underground water to flow; the C frame represents the frame for the ethanol water to flow; the arrangement sequence of the cover plates, the frames and the flat-shaped immobilized cells is as follows: one cover plate, one W frame, one flat-shaped immobilized cell, the C frame, the other flat-shaped immobilized cell, the other W frame and the other cover plate; the lower and upper ends of the W frames and the C frame are respectively provided with inlets and outlets; and bolt holes are arranged around the cover plates and the frames. The bioreactor has the following advantages: the oxygen in the air is avoided from being dissolved in the underground water and ethanol water in the reactor, thus reducing the adverse effects of the dissolved oxygen on denitrification; at the same time, the effective reaction area of the immobilized cell in unit volume and the treatment capability in unit volume are obviously improved; and besides, recycling of the carbon source of denitrification is also realized, thus reducing waste of the carbon source of denitrification.
Owner:EAST CHINA UNIV OF SCI & TECH
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