Method for treating fly sh by sludge

A technology for sludge treatment and fly ash, which is applied in the field of resource utilization of fly ash, can solve problems such as hindering the hydration process of the silicate system, increasing the leaching rate of harmful substances, and reducing the strength of solidified bodies, so as to benefit subsequent resources Utilization, realization of curing and detoxification, and improvement of long-term stability

Active Publication Date: 2017-02-22
INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This not only has high processing costs, occupies land resources, and is prone to secondary pollution
The main reason is that the solidification and stabilization of fly ash mainly depends on the hydrated silicate system, but the high chlorine content in the fly ash (the average mass percentage is higher than 15%) directly hinders the hydration process of the silicate system and reduces the strength of the solidified body. As a result, the leaching rate of harmful substances becomes higher, so when the hydrated silicate system is used to solidify and stabilize fly ash, it is necessary to pre-wash the fly ash to remove chloride ions in the fly ash, which makes the treatment process more complicated
In terms of fly ash recycling, some researchers have proposed to use fly ash as an additive in the production of building materials, but my country’s cement standards have strict control standards for chlorine content, and chloride ions will cause serious electrochemical corrosion and corrode reinforced concrete. In the middle of the steel structure, it will also reduce the strength of the cement
Therefore, dechlorination and solidification of heavy metals are a bottleneck problem in the harmless and resourceful utilization of fly ash

Method used

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  • Method for treating fly sh by sludge
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Examples

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Effect test

Embodiment 1

[0075] Mix a certain amount of sludge with fly ash accounting for 5% of the sludge mass, and vigorously stir at a speed of 100r / min at a temperature of 35°C for 3 hours to obtain a mixed slurry; the mixed slurry is subjected to hydrothermal treatment, and the process conditions of the hydrothermal treatment are : The temperature is 100° C., the pressure is 2 bar, and the time is 60 min to obtain a hydrothermal treatment product. The hydrothermally treated product is subjected to solid-liquid separation through press filtration to obtain a hydrothermally press-filtered liquid and a hydrothermally press-filtered solid. The hydrothermal pressure filtration liquid is placed in an anaerobic fermentation tank for anaerobic fermentation to produce biogas and stored; the fermentation liquid produced after fermentation is put into the sewage treatment system of the sewage treatment plant for treatment and discharged after reaching the standard. Mix the hydrothermal press-filtered solid...

Embodiment 2

[0078] Mix a certain quality of sludge with fly ash accounting for 10% of the sludge mass, and vigorously stir at a temperature of 50°C at a speed of 250r / min for 2 hours to obtain a mixed slurry; the mixed slurry is subjected to hydrothermal treatment, and the process conditions of the hydrothermal treatment are : The temperature is 160° C., the pressure is 6 bar, and the time is 100 min to obtain a hydrothermal treatment product. The hydrothermally treated product is subjected to solid-liquid separation through press filtration to obtain a hydrothermally press-filtered liquid and a hydrothermally press-filtered solid. Anaerobic fermentation is performed on the hydrothermal pressure filtration liquid to generate biogas, which is stored; the fermented liquid produced after fermentation is recovered by ion flotation to recover heavy metal ions in the fermented liquid, and then the waste water is discharged after reaching the standard. Mix the hydrothermal press-filtered solid w...

Embodiment 3

[0081] Mix a certain quality of sludge with fly ash accounting for 20% of the sludge mass, and vigorously stir at a temperature of 65°C at a speed of 400r / min for 1 hour to obtain a mixed slurry; the mixed slurry is subjected to hydrothermal treatment, and the process conditions of the hydrothermal treatment are : The temperature is 220° C., the pressure is 23 bar, the time is 140 min, and the hydrothermal treatment product is obtained. The hydrothermally treated product is subjected to solid-liquid separation through press filtration to obtain a hydrothermally press-filtered liquid and a hydrothermally press-filtered solid. Anaerobic fermentation is performed on the hydrothermal pressure filtration liquid to generate biogas, which is stored; the fermented liquid produced after fermentation is recovered by ion flotation for heavy metal ions in the fermented liquid, and then the waste water is discharged after reaching the standard. The pyrolysis mixture was obtained by mixing ...

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Abstract

The invention discloses a method and equipment for treating fly sh by sludge. The method comprises the following steps: a mixture of the fly ash and the sludge is forcedly stirred to obtain mixed mud; the mixed mud is hydrothermally treated to obtain a hydrothermal treatment product; the hydrothermal treatment product performs solid-liquid separation through a pressing filter mode to obtain hydrothermal pressing filter liquid and a hydrothermal pressing filter solid; a biomass is added in the hydrothermal pressing filter solid to form a pyrolysis mixture; the pyrolysis mixture is pyrolyzed to obtain pyrolysis residues; the pyrolysis residues serve as general solid wastes for backfilling or serve as inorganic materials for use; the hydrothermal pressing filter liquid performs anaerobic fermentation to generate gas and fermentation liquid; the fermentation liquid generated by fermentation is purified; and the treated water is qualified for emission. The invention further provides equipment for realizing the method. The method uses the sludge for realizing detoxification of the fly ash and stabilization, thoroughly eliminates dioxin substances in the fly ash to prevent secondary pollution, and realizes harmless treatment of the fly ash.

Description

technical field [0001] The invention relates to resource utilization of fly ash, in particular to a method for treating fly ash with sludge and equipment for realizing the method. Background technique [0002] At present, the domestic waste incineration process has become the mainstream technology for waste disposal in large and medium-sized cities in my country. Incineration fly ash accounts for 1%-5% of the total mass of incinerated waste. If the dosage of slaked lime and other chemicals added in the flue gas purification treatment is added, it accounts for 3-7% of the total mass of incinerated waste. According to statistics, my country's domestic waste incineration and disposal capacity has exceeded 55.05 million tons, and 2.2 million tons of domestic waste incineration fly ash will be produced every year. Fly ash has been included in the National Hazardous Waste List (HW18). The conventional method is to use cement solidification and other methods to stabilize the harmf...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B09B3/00C02F11/12C02F11/10C10B53/00
CPCB09B3/00C02F11/10C02F11/122C10B53/00Y02W10/40
Inventor 余广炜汪印尤甫天潘兰佳李杰唐晓达王兴栋邢贞娇
Owner INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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