2035 results about "Chloride sodium" patented technology

The invention discloses piggy creep feed containing composite flavone. The piggy creep feed is prepared from the following raw materials in parts by weight: 13 to 20 parts of expanded corn, 10 to 25 parts of corn, 6 to 13 parts of broken rice, 8 to 12 parts of flour, 8 to 15 parts of whey mist, 3 to 8 parts of soy protein concentrate, 5 to 10 parts of extruded soybean, 0.7 to 3 parts of soya-bean oil, 7 to 12 parts of 46.5-percent bean pulp, 2 to 5 parts of fish meal, 2 to 5 parts of plasma protein powder, 0.3 to 0.7 part of mountain flour, 0.5 to 1.0 part of calcium hydrophosphate, 0.05 to 0.5 part of lysine, 0.05 to 0.3 part of threonine, 0.1 to 0.3 part of sodium chloride, 0.1 to 0.8 part of compound flavone premix compounds, 0.15 to 0.3 part of zinc oxide, 0.03 to 0.06 part of calcium propionate, 0.02 to 0.04 part of ethoxyquin and 1.0 part of suckling pig premix compounds. The invention also discloses a preparation method. The intestinal tract health and the production performance of weaned pigs can be improved.

The present disclosure relates to the field of sodium-ion battery technology, and specifically, to a method for preparing carbon-coated sodium iron fluorophosphate from waste lithium iron phosphate and the application thereof. The method for preparing carbon-coated sodium iron fluorophosphate from waste lithium iron phosphate includes: mixing a waste lithium iron phosphate material with an alkaline solution for reaction, followed by solid-liquid separation, to obtain an aluminum-containing filtrate and a lithium iron phosphate filter residue; mixing the lithium iron phosphate filter residue, aluminum chloride and sodium chloride uniformly, followed by vacuum calcination, to obtain a calcination material; and mixing the calcination material with at least one of a sodium source, an iron source and a phosphorus source uniformly to obtain a mixture to which a fluorine source, a carbon source and a solvent are added for uniformly mixing, followed by drying and calcination sequentially to obtain the carbon-coated sodium iron fluorophosphate. The method has the advantages of low costs, a high added value, a short process, and a high recovery rate, and the carbon-coated sodium iron fluorophosphate obtained from the method has excellent electrochemical performance.

The invention provides a preparation method of an acid-resistant and chlorine-corrosion-resistant porous composite electrode and a device constructed on the basis of the electrode and used for preparing hydrogen and chlorine by electrolyzing a sodium chloride solution, two cavities are provided, an acid or neutral saturated sodium chloride solution is filled in the cavities, the cavities are separated by a proton exchange membrane or a diaphragm, and the proton exchange membrane or the diaphragm is filled in the cavities. And in the electrolysis process, the cathode generates high-purity hydrogen, the anode generates high-purity chlorine, the chlorine is absorbed by sodium hydroxide in the gas collection bottle and generates sodium hypochlorite, or the chlorine is introduced into a sodium bromide / sodium iodide solution to replace bromine / iodine elementary substances, and the chlorine is discharged from the gas collection bottle. The sodium hypochlorite solution and the bromine / iodine water are used for disinfection and sterilization experiments. The corrosion-resistant porous composite electrode for electrolysis of an acidic or neutral saturated sodium chloride solution is prepared, the electrolysis voltage of the corrosion-resistant porous composite electrode is further reduced by loading a cathode / anode catalyst, and an acidic or neutral saturated sodium chloride solution electrolysis device constructed based on the electrode can be used for preparing high-purity hydrogen and chlorine.

The invention discloses a film coating agent for accelerating stabilization of a weathering resistant steel rust layer in a severe atmospheric environment. The film coating agent comprises a film-forming agent and a spraying agent, the film-forming agent comprises a gel agent and a transforming agent; the gel is prepared from one or more of tannic acid, carbomer, chitosan and gelatin; the transforming agent comprises one or more of magnesium sulfate, zinc sulfate and sodium molybdate; the spraying agent comprises an accelerant and an aggressive agent; the accelerant comprises one or more of sodium sulfate, potassium sulfate and chromium sulfate; the aggressive agent comprises one or more of sodium chloride, aluminum chloride and sodium fluoride. The film coating agent provided by the invention can form a stable and uniform rust layer on the surface of the weathering resistant steel, so that the corrosion resistance of the weathering resistant steel is improved.

The invention discloses a method for selectively recycling phosphorus pollutants in low-concentration phosphorus-containing sewage and preparing high-quality blue iron ore and application, and belongs to the technical field of water treatment and recycling thereof. According to the method, the low-concentration phosphorus-containing sewage is adsorbed by a phosphorus specific nano adsorption material HFO-201, and then the material is desorbed by adopting sodium hydroxide and sodium chloride with specific concentrations. The desorbed filtering material and the filtered material can be repeatedly used for adsorbing phosphorus in low-concentration sewage. After the pH value of the filtered desorption solution is adjusted to a certain concentration, FeCl2 with a certain concentration is added, and high-quality blue iron ore (Fe3 (PO4) 2.8 H2O) can be generated by keeping the pH value through sodium hydroxide under an anaerobic condition. The phosphorus product recovered by the process can be used for preparing a high-value phosphate fertilizer and a high-energy-density energy storage material, namely lithium iron phosphate (LiFePO4). The HFO-201 used in the invention can realize low-concentration phosphorus adsorption through an ammonium group combined with a D-201 matrix and loaded HFO nanoparticles. And moreover, after alkali desorption, the damage to the material is very low, and the material can be repeatedly used. And finally, the process of producing the high-quality blue iron ore through phosphorus recovery of the desorption solution is simple and easy to operate. Through XRD, ICP and other detection, it is found that the phosphorus recovery product is determined to be the blue iron ore, and the purity is very high. Through economic analysis and life cycle evaluation, it can be found that the method has remarkable economical efficiency, and the influence on the environment in the production process is small.

A low-carbon near zero emission process of industrial waste water, comprising: S1: entering industrial waste water into a pre-oxidation system to improve biodegradability of organics; S2: after treatment in the pre-oxidation unit, entering the waste water into an anaerobic biological treatment system, sodium chloride and sulfate is deeply removed and carbon sources in the waste water can be used to remove the sulfate and nitrate; S3: entering water output from the anaerobic biological treatment system into a membrane concentration system and membrane concentrated solution enters a nano-filtration salt fractionation system for salt fractionation; and S4: refluxing nano-filtration concentrate solution generated by the nano-filtration salt fractionation system to the anaerobic biologic treatment system for biological desulfurization, or synthesizing the nano-filtration concentrate solution to be sodium persulfate by electro chemical methods, and refluxing proportionately to a waste water pre-oxidation system for use in-situ.

The invention belongs to the technical field of medicines, and particularly relates to a pyruvate-containing composite preparation as well as a preparation method and application thereof. The composite preparation containing pyruvate is prepared from the following components in percentage by mass: 0.02 to 0.04 percent of a compound A, 0.05 to 0.1 percent of pyruvate, 0.2 to 2 percent of sodium dihydrogen phosphate, 0.2 to 2 percent of disodium hydrogen phosphate, 0.7 to 0.9 percent of sodium chloride and the balance of water for injection, the structural formula of the compound A is as follows: # imgabs0 #. The compound A and pyruvate in the compound preparation interact with each other, so that lung inflammatory response can be inhibited, the level of inflammatory factors can be reduced, and lung edema can be relieved.

The invention discloses a multi-dimensional rapid evaluation method for snow-melting agent corrosion resistance of stainless steel, and relates to the technical field of stainless steel performance evaluation.The multi-dimensional rapid evaluation method comprises the steps that sodium chloride, calcium chloride and magnesium chloride are weighed by mass and dissolved in deionized water, acetic acid and sodium hydrogen sulfite are added after dissolution, and the pH value is adjusted to 4-6; performing potentiodynamic polarization scanning and electrochemical impedance spectroscopy testing on the stainless steel sample to obtain pitting potential and impedance modulus; the method comprises the following steps: placing a stainless steel sample in a cyclic corrosion experiment box, carrying out a corrosion experiment under the conditions of controlling the cyclic temperature change of an environment temperature and periodically carrying out cyclic switching of a spraying mode, a humid mode and a drying mode, taking out the sample every set time, and measuring the corrosion rate and the maximum pitting depth; and according to the pitting potential, the impedance modulus, the corrosion rate and the maximum pitting depth, carrying out graded judgment on the corrosion resistance of the stainless steel. According to the method, the corrosion resistance of the stainless steel can be accurately evaluated in a short time.

The invention discloses a low-cost large-molecular-weight fish scale collagen extraction method, and belongs to the technical field of fish scale collagen. The method comprises the following steps: (1) pretreatment: repeatedly freezing and storing fish scales and unfreezing and redissolving the fish scales; 2) impurity protein removal: taking out the fish scales, and removing fish silver; soaking in a sodium chloride solution, washing and drying; 3) extracting fish scale collagen, namely extracting the dried fish scales for 1-4 hours at 40-100 DEG C according to a solid-liquid ratio of 1: (5-20) by adopting a hydrothermal extraction mode, carrying out solid-liquid separation, and collecting fish scale collagen extract liquids in different molecular weight intervals; and 4) freeze-drying the collagen extract liquid to obtain a fish scale collagen solid product. According to the method, acid or alkali solution pretreatment is not needed, and a sodium chloride salt solution is used for mildly removing impure protein. And the structure of the fish scale collagen is relatively completely maintained while the relatively high yield is ensured.

The invention relates to the technical field of preparation of metal organic frameworks, and particularly discloses a preparation method and application of a porous MOF (Metal Organic Frame.The method comprises the following steps: dissolving a triblock copolymer PluronicF-127 in ultrapure water, adding acetic acid and sodium chloride, and uniformly stirring to form a solution; adding zirconyl nitrate into the solution, and adjusting temperature and reaction time through a metal ion diffusion optimization model to ensure uniform distribution of metal ions; organic ligands are introduced to adjust the pore size distribution of the MOF; carrying out surface functionalization on the synthesized MOF material, and introducing amino and carboxyl; washing and filtering the synthesized MOF material to remove impurities and residues, and then drying the MOF material under a vacuum condition to remove moisture and an organic solvent. According to the invention, the performance of the MOF material in the application of the electrochemical luminescence sensor is effectively improved.

The invention relates to a method for recovering mixed salts (mainly containing calcium chloride, sodium chloride and potassium chloride) from a household garbage incineration fly ash leaching solution, and particularly provides two separation technical schemes. The traditional separation method generally needs to use a large amount of decalcifying agent, so that the cost is high, calcium chloride cannot be effectively recycled, and the problem of resource waste exists. In order to solve the problems, the invention selectively dissolves calcium chloride in the mixed salt by adopting a specific organic solvent (such as ethanol or methanol) and utilizing the characteristics that the solubility of calcium chloride in the solvent is high, the solubility of sodium chloride and potassium chloride is low, and the boiling point is relatively low. And a calcium chloride product can be recovered after solvent evaporation. Furthermore, the residual mixed salt is further washed using the specific organic solvent to remove entrained calcium chloride, thereby obtaining a mixed salt containing predominantly sodium chloride and potassium chloride. According to the technical scheme 1, the mixed salt subjected to separation and calcium removal is subjected to dissolution treatment under the high-temperature condition, potassium chloride is dissolved, the particle size of sodium chloride crystals is promoted to be increased, the sodium chloride crystals are obtained through solid-liquid separation, and then mother liquor is cooled and crystallized to recover potassium chloride. According to the technical scheme 2, the mixed salt subjected to separation and calcium removal is subjected to aging treatment so as to promote particle size increase of sodium chloride and potassium chloride crystals, then the aged mixed salt is separated by adopting a flotation method, and sodium chloride and potassium chloride products are recycled respectively.

The invention relates to the technical field of industrial production wastewater treatment, and particularly provides a resource utilization method of calcium chloride high-salt water containing high-concentration organic matters. The method comprises the steps of pretreatment, wet catalytic oxidation, salt type conversion, softening filtration, deep oxidation, nanofiltration purification and targeted adsorption, no residual mother liquor exists, no secondary pollution is generated, organic matters in effluent are stable and reach the standard, the water quality and water quantity fluctuation resistance is high, heterogeneous and homogeneous catalysts are combined for catalysis, and the purification effect is good. According to the method, the sodium chloride solution is used as a raw material, the homogeneous catalyst is recycled, in addition, most of salt in the homogeneous catalyst is also recycled, resource reutilization is fully achieved, the treatment cost is reduced, and the treated sodium chloride solution can be used as primary saline water for subsequent ion membrane electrolysis.

The invention discloses a fermentation medium for regulating and controlling a clostridium aerovorans target product and a fermentation method of the clostridium aerovorans target product. The medium comprises a basic component and a regulating component, the basic components comprise ammonium chloride, potassium chloride, magnesium sulfate heptahydrate, sodium chloride, monopotassium phosphate, yeast powder, calcium chloride dihydrate, sodium selenite, nickel chloride hexahydrate, biotin, folic acid, pyridoxine hydrochloride, thiamine, riboflavin, nicotinic acid, D-calcium pantothenate, cobalamin, para aminobenzoic acid and lipoic acid; the adjusting component comprises sodium tungstate, ferrous sulfate and sodium molybdate, sodium tungstate and ferrous sulfate have a forward adjusting effect on increasing the yield of acetic acid, ethanol and butanol in the target product, and sodium molybdate has a reverse adjusting effect on the target product. By optimizing the proportion of trace elements in the culture medium, the clostridium metabolism efficiency is improved, synthesis of a target product is regulated and controlled, and the method is particularly suitable for industrial production of acetic acid, ethanol, butanol and the like.

The invention discloses a preparation method for preparing a biomass porous carbon material through high-temperature carbonization of molten salt and application of the biomass porous carbon material, and belongs to the technical field of synthesis of inorganic functional materials. According to the technical scheme, the method is characterized in that sodium chloride and potassium chloride are mixed into mixed salt according to different proportions, then the mixed salt is mixed with enteromorpha biomass according to a certain proportion, the mixture is placed in a porcelain crucible, the mixed salt is added for covering, the porcelain crucible is placed in a muffle furnace to be heated and carbonized, and the porous biomass carbon material is obtained after water washing and drying. The enteromorpha biomass is selected as the raw material, the operation is simple and controllable, the cost is low, batch production can be realized, and the prepared novel porous biomass carbon material has a complex porous structure, a large specific surface area, a very good catalytic effect, strong adsorption capacity and good conductivity, and shows excellent performance when being applied to the field of advanced oxidation.

The invention discloses a technological method for extracting lithium, rubidium and cesium through a lepidolite chlorate method. The technological method comprises the steps that lepidolite, calcium chloride, sodium chloride and calcium oxide are mixed and then roasted, and clinker is obtained; leaching the clinker under an acidic condition to obtain brine; performing impurity removal treatment on the brine to obtain purified clear liquid; performing lithium precipitation on the purified clear liquid through sodium carbonate liquid; the method comprises the following steps: extracting filtered waste liquid subjected to lithium precipitation through an extracting agent and a dispersing agent, washing a rubidium and cesium oil phase obtained by extraction by adopting two-section multi-stage cross flow of different detergents to obtain an organic phase, and carrying out reverse extraction on the obtained organic phase to reversely extract rubidium and cesium into reverse water; and preparing salt from the reverse water in an evaporation drying manner. According to the method, after the lepidolite is subjected to roasting transformation leaching, the leaching rate of lithium can reach 94% or above, the leaching rates of rubidium and cesium can reach 98% or above, the process of extracting lithium, rubidium and cesium from the lepidolite to prepare corresponding salt products is environmentally friendly, energy-saving, low in energy consumption, low in cost and high in extraction rate, and wide industrial application prospects are achieved.

The invention discloses a low-temperature multi-effect evaporation-based impurity salt treatment process method, and relates to the technical field of industrial waste salt treatment in the chemical industry. According to the scheme, firstly, impurity salt is dissolved and then pretreated by a fluorine removal tank and a multi-medium filter, and pretreated saline water is obtained; then, organic matters and dissolved substances are removed through a catalytic oxidation and nanofiltration device, and a monovalent salt solution and a divalent salt solution are separated out; then, the monovalent salt solution is subjected to reverse osmosis concentration and then enters a low-temperature multi-effect evaporation system for sodium chloride crystallization, and the divalent salt solution is subjected to catalytic oxidation and then enters low-temperature multi-effect evaporation for sodium sulfate crystallization. And finally, the mother liquor subjected to low-temperature multi-effect evaporation is refluxed and retreated, and resources are further concentrated. According to the invention, the waste salt treatment efficiency is effectively improved by optimizing the chemical addition of the sedimentation tank. By adopting a low-temperature multi-effect evaporation technology, the energy efficiency is optimized, the energy loss is reduced, the crystallization efficiency is improved, and the resource recovery rate is increased. And a mother liquor backflow retreatment mechanism reduces waste liquid discharge and reduces environmental burden.

The invention discloses a method for rapidly and accurately determining the content of organochlorine pesticides in water, and belongs to the field of organochlorine pesticide content determination, and the method comprises the following steps: adding a regulator into a water sample, uniformly shaking, adding a substitute, and uniformly shaking again; adding sodium chloride into the water sample treated in the step S1, putting the water sample into a liquid-liquid extraction oscillator, and oscillating until the water sample is completely dissolved; s2, adding an extracting agent into the water sample treated in the step S2, vigorously oscillating, standing for layering, putting the lower-layer water sample into a reagent bottle, transferring an upper-layer extracting solution into a drying column, washing and dehydrating, and then transferring into a concentration bottle; the step S3 is executed again on the remaining water sample in the step S3; and S4, combining the eluents in the steps S3 and S4, transferring into a full-automatic nitrogen blowing instrument, concentrating to 1ml, adding an internal standard solution, and performing gas chromatography-mass spectrometer analysis after volume metering to obtain the content of the organochlorine pesticide in the water sample. The method has the beneficial effects that the method has the advantages of high efficiency, rapidness and accurate detection, and the method is simple to operate, low in cost and high in concentration efficiency and recovery stability.

The invention relates to a rapid detection kit for large yellow croaker pyramidal worm, and belongs to the field of pathogen biological diagnosis in aquaculture. The kit comprises a nucleic acid releasing agent and further comprises a primer and a probe which are used for detecting the large yellow croaker pyramidal worm. The kit comprises a nucleic acid releaser; the formula of the nucleic acid releasing agent comprises tris (hydroxymethyl) aminomethane hydrochloride with the final concentration of 100 mM, sodium chloride with the final concentration of 100 mM, sodium dodecyl sulfate with the final concentration of 1 wt%, sodium alpha-olefin sulfonate with the final concentration of 3 wt%, sodium lauroyl glutamate with the final concentration of 1.2 wt%, betaine with the final concentration of 1 wt% and water as a solvent. The sequences of the primer and the probe for detecting the Pseudosciaena crocea pyramidal are 5 '-TATGGGCAATTCTGAATCCT-3', 5 '-TCTTTTCTGATCCCTGAAT-3' and 5 '-FAM-GTCGGTGGAGTGATTTGTTTG-3'. The kit disclosed by the invention is simple to operate, provides a tool for diagnosis, prevalence monitoring, prevention and control of the Pseudosciaena crocea pyramidal, and has a very high application value.

The invention relates to the technical field of chemical preparations, in particular to a sodium hypochlorite stabilizer, a preparation method and a use method thereof and a stable sodium hypochlorite solution. The sodium hypochlorite stabilizer is prepared from the following components in percentage by mass: 2.5 to 3.5 percent of sodium diethylenetriamine pentaacetate, 2.5 to 3.5 percent of disodium ethylene diamine tetraacetate, 1.0 to 1.25 percent of sodium silicate, 3.5 to 5.0 percent of sodium bicarbonate, 2.5 to 3.0 percent of sodium chloride and the balance of water. The stable sodium hypochlorite solution prepared by adopting the sodium hypochlorite stabilizer disclosed by the invention is higher in stability and longer in validity period.

The invention belongs to the technical field of organic synthesis of ethers, and particularly relates to a method for continuously synthesizing ethylene glycol dimethyl ether. The method comprises the following steps that ethylene glycol, sodium hydroxide and methane chloride serve as raw materials, multi-stage continuous reaction is carried out in liquid membrane reactors to synthesize ethylene glycol dimethyl ether, ethylene glycol, sodium hydroxide and methane chloride are introduced into the first-stage liquid membrane reactor, sodium hydroxide and methane chloride are introduced into the subsequent stages of liquid membrane reactors, and the first-stage liquid membrane reactor and the second-stage liquid membrane reactor are connected with the second-stage liquid membrane reactor. A byproduct sodium chloride is separated from a reaction product in the previous-stage liquid membrane reactor and then enters the next-stage liquid membrane reactor, a byproduct sodium chloride is separated from a reaction product in the last-stage liquid membrane reactor and then clear liquid is obtained, and ethylene glycol dimethyl ether is obtained through rectification treatment. The invention develops a novel process mode for continuously synthesizing an ethylene glycol dimethyl ether product, and provides a new idea for large-scale continuous production of ethylene glycol dimethyl ether.

The invention discloses a waste incineration fly ash coupling sodium-based waste salt harmless treatment resource utilization method, which comprises the following steps: preparing household waste incineration fly ash and sodium-based waste salt according to a dry basis molar content ratio of (1-1.05): 1, uniformly mixing, and carrying out heat treatment at 450-500 DEG C to obtain an ash-salt mixture; washing with water to remove chlorine salt and heavy metal to obtain a chlorine salt solution and a mud cake; treating the chlorine salt solution to obtain industrial regenerated salt sodium chloride and potassium chloride; pulping the mud cake, adding a flotation agent for flotation to obtain flotation residues and industrial dihydrate gypsum, and preparing alpha gypsum from the industrial dihydrate gypsum by using a dry method; and after flotation, feeding residues into a grinding unit for grinding to obtain the desulfurizer. According to the method, the fly ash and the sodium-based waste salt are subjected to coupling treatment in one set of equipment, potassium chloride, sodium chloride, gypsum, calcium carbonate, calcium hydroxide and the like in the waste incineration fly ash and the sodium-based waste salt are effectively and respectively treated into products for all purposes, recycling of all valuable components is achieved, and the resource utilization value is high.

The invention provides a method for detecting diastereoisomers in a nerofloxacin malate sodium chloride injection. The method comprises the following steps: separating optical isomers of the nerofloxacin malate sodium chloride injection by adopting a liquid chromatography; wherein the chromatographic condition of the liquid chromatography comprises a mobile phase, the mobile phase comprises a mobile phase A and a mobile phase B, the mobile phase A is a trifluoroacetic acid solution, and the mobile phase B is methanol-tetrahydrofuran. According to the technical scheme, a trifluoroacetic acid solution is adopted as a mobile phase A, methanol-tetrahydrofuran is adopted as a mobile phase B, tetrahydrofuran is added in the mobile phase B, the peak pattern of a main peak is improved, the trailing factor is 1.06, the operation time can be shortened, and the peak pattern of the main peak is improved.

The invention discloses a method for removing iron impurities in regenerated aluminum alloy, and belongs to the field of non-ferrous metal regeneration, recovery and impurity removal. The method comprises the following steps: weighing an iron removal flux (25-45 wt.% of boron-containing potassium fluoride, 20-30 wt.% of sodium chloride and 20-35 wt.% of potassium chloride) according to the mass percentage, stirring, mixing and drying; according to the method, the aluminum scrap is put into the smelting furnace to be smelted, then the iron removal flux and the permanganate catalyst are added into the aluminum scrap melt, stirring and standing are carried out, the aluminum melt with the iron impurity element removed is obtained, the method does not affect the aluminum obtaining rate, meanwhile, the iron content is remarkably reduced, and the method is applied to aluminum ingots obtained through green regeneration smelting of the aluminum scrap and has the beneficial effects that the cost is low; the environment is not damaged and the steps are simple.

The invention discloses a saline-alkaline tolerant compound microbial agent and application thereof, and particularly relates to the technical field of microbial soil treatment. The microbial agent comprises Klebsiella, Enterobacter hormaechei and humic acid, the ratio of the components is as follows: Klebsiella: Enterobacter hormaechei: humic acid = 1: (0.5-2): (1-3), and both Klebsiella and Enterobacter hormaechei are obtained by fermentation culture. According to the present invention, the specific pH gradient is adopted for the Klebsiella and the Enterobacter hormaechei, and the segmented fermentation process combining the specific pH gradient with the corresponding gradually-increased sodium chloride concentration is adopted, such that the strain is effectively subjected to the directional domestication so as to maintain the activity and the function in the high-salt and high-alkali extreme environment.

The invention discloses a method for improving the crystallinity and catalytic water decomposition performance of a polyheptazine imino carbon nitride photocatalyst, and belongs to the technical field of photocatalytic material preparation. The preparation method comprises the following steps: firstly, by taking melamine as a precursor, carrying out thermal polymerization to obtain an oligomer melt consisting of heptazine units; then carrying out high-temperature fused salt calcination treatment in a nitrogen atmosphere to obtain carbon nitride with a certain crystallinity; and adding sodium chloride as a structure regulator, fully grinding, calcining in vacuum, washing with water, and drying to obtain the crystalline-phase carbon nitride photocatalyst with high crystallinity. The method is simple, the cost is low, the actual production requirement is met, and the synthesized photocatalyst has good polymerization degree and light absorption performance, has excellent activity of fully decomposing water to produce hydrogen and oxygen under the condition of no sacrificial agent, and has the potential of realizing photocatalytic full-decomposition water diversion and the prospect of industrial application.

The invention discloses a comprehensive utilization method of high-salinity wastewater produced by hydrometallurgical treatment of bastnaesite, which comprises the following steps: A, mixing alkaline wastewater and acidic wastewater, neutralizing and clarifying to obtain calcium fluoride and sodium chloride wastewater; b, mixing the sodium chloride wastewater with the precipitation wastewater, adding lime water in an aeration manner to adjust the pH value, hydrolyzing heavy metal ions in the wastewater, and performing solid-liquid separation to obtain filter residues and filtrate which is sodium chloride high-salinity wastewater; and C, adding oxalic acid into the sodium chloride high-salinity wastewater, stirring, standing, carrying out solid-liquid separation, pressurizing, concentrating, recovering hydrochloric acid, and crystallizing to obtain a crystal substance, namely a sodium chloride product. According to the method, fluorine in the wastewater is removed firstly, then the wastewater is recovered into wastewater containing sodium chloride, oxalate is dissolved into the high-salinity wastewater to separate out sodium oxalate and recover hydrochloric acid, so that the content of sodium chloride in the system is greatly reduced, and the recovery efficiency of sodium ions in the wastewater is improved.

The invention belongs to the field of secondary resource recycling, and discloses a method for preferentially extracting lithium from a waste lithium iron phosphate battery positive electrode material through salt leaching, the waste lithium iron phosphate battery positive electrode material is leached by adopting a soluble chloride and metal sulfate mixed solution, and a lithium-containing leaching solution and ferrophosphorus slag are obtained, the soluble chloride solution is selected from at least one of a potassium chloride solution, an ammonium chloride solution or a sodium chloride solution, and the metal sulfate comprises at least one of ferric sulfate, copper sulfate and high-valence manganese sulfate. According to the method, the valuable metal is recycled from the waste lithium iron phosphate battery powder by adopting a novel salt leaching process, the use of a large amount of acid and alkali reagents in a conventional wet process is avoided, the whole recycling process is green, environment-friendly and low in cost, and the lithium-extracted liquid is recycled after being blended, so that the input cost of a production reagent is reduced, and the efficient utilization of the reagent is realized; no waste water is generated, and cleaning and environment-friendly effects are achieved.

The invention discloses low-temperature coagulation-accelerating anion styrene-butadiene latex for oil field well cementation and a preparation method of the low-temperature coagulation-accelerating anion styrene-butadiene latex. The low-temperature coagulation-accelerating anion styrene-butadiene latex comprises the following components in parts by mass: 100 parts of anion styrene-butadiene latex raw stock; 4 to 10 parts of a nonionic surfactant I; 2 to 4 parts of a nonionic surfactant II; 10 to 20 parts of water glass; 0.5 to 1 part of a defoaming agent; and 15-20 parts of deionized water. The low-temperature coagulation-accelerating anionic styrene-butadiene latex prepared by the invention is used in cement paste, has short thickening time at low temperature, can resist sodium chloride brine to reach semi-saturation, and can effectively control the water loss of the cement paste, improve the anti-channeling performance of a cement paste system, reduce the elastic modulus of set cement, increase the density of the set cement and improve the stability of the set cement. Therefore, formation gas is effectively prevented from invading cement stone, and well cementation quality is guaranteed.

The invention relates to a cold precipitation-salting-out integrated ammonium chloride preparation method and system, which comprises the following steps: reducing the temperature of an ammonium chloride-containing solution generated in a combined alkali production process to below 10 DEG C, then adding sodium chloride into the solution while stirring until an ammonium chloride saturated salt solution is formed, standing, then cooling in a stepped manner, and after ammonium chloride crystals are completely separated out, obtaining ammonium chloride. And centrifuging to obtain an ammonium chloride product. Compared with a traditional separation preparation method of cold precipitation and salting-out in sequence, the method has the advantages that the ammonium chloride-containing solution generated in the combined alkali production process is subjected to cold precipitation and salting-out at the same time through one-step operation, so that the process flow is simplified, the time is greatly saved, the production efficiency and the yield are improved, the equipment investment is reduced, and the process operation cost is reduced; and the yield is improved.

The invention relates to the field of stripping hanger liquid processing, in particular to environment-friendly stripping hanger liquid and a preparation process thereof. The cleaning agent is prepared from the following raw materials in percentage by weight: 10-15% of sulfuric acid, 3-6% of tetrasodium hydroxyethylidene diphosphate, 4-6% of sodium alcohol ether sulphate, 4-8% of N-methyl-2-pyrrolidone, 4-9% of cyclohexanol, 1-2% of phenolsulfonic acid, 4-7% of sodium hypochlorite, 5-9% of hydrogen peroxide, 3-4% of ferrous sulfate, 1-3% of sodium chloride, 4-8% of a wetting agent, 0.5-0.8% of a stabilizer, 2-3% of a thickening agent, 2-3% of a penetrant and the balance of pure water. Mild chemical components adopted in the formula replace strong nitric acid and strong alkali components in a traditional hanger stripping solution, the corrosivity of the hanger stripping solution is reduced, all the raw materials meet the environment-friendly requirement, and harmful substances cannot be generated in the production and use process, and the environment cannot be polluted.