6results about How to "Reduce interface contact resistance" patented technology

The application discloses a method for improving the metalization connection strength of n-type Bi2Te3-based thermoelectric elements based on anchoring effect, and comprises the following steps: configuring a n-type Bi2Te3-based wafer surface treatment agent, the composition of which comprises 40-50% sulfuric acid (volume), 1-2% nitric acid (volume), and the rest is water; immersing a clean n-type Bi2Te3-based wafer into the surface treatment agent to perform surface etching; then immersing the etched n-type Bi2Te3-based wafer into ultrapure water to perform ultrasonic treatment; performing metalization connection on the ultrasonically treated n-type Bi2Te3-based wafer through electroplating or chemical plating, the plated metal is easy to form anchoring effect with the n-type Bi2Te3, the metalization connection strength is improved; and finally performing scribing and cutting to obtain the Bi2Te3-based thermoelectric elements with high metalization connection strength. The application makes the n-type Bi2Te3-based wafer have high surface roughness before electroplating, which is beneficial to forming anchoring effect with the plated metal such as nickel, so that the Bi2Te3-based thermoelectric elements with high metalization connection strength are obtained, and the thermoelectric elements are not physically damaged, and the product qualification rate can be improved.

This application relates to the field of lithium-ion battery manufacturing technology and discloses a method for preparing a stabilized positive electrode sheet for all-solid-state batteries. The method includes: dispersing positive electrode active material, sulfide solid electrolyte, and binder in a non-polar solvent under an inert atmosphere to obtain a positive electrode slurry; coating and drying to obtain a precursor layer; simultaneously applying pressure and temperature to the precursor layer for interface stabilization heat treatment; and cooling to obtain the positive electrode sheet. This invention utilizes a temperature-pressure coupling process to reduce the yield stress of the electrolyte and promote binder rheology through thermal effects, achieving electrode densification under relatively low mechanical pressure, effectively avoiding the problem of active material particle breakage caused by traditional high-pressure cold pressing processes. This method reduces the positive electrode interface impedance and enhances the interfacial bonding force, thereby significantly improving the structural integrity and cycle life of all-solid-state batteries.

The application discloses a kind of supercapacitor negative high-efficiency composite electrode and preparation method thereof, including the block body iron of substrate and the outer layer PrNi x Fe 1‑x O3 conductive active layer, and Fe2O3 active layer between the two, by wet chemical etching and transient high temperature joule heat method in-situ synthesis active layer, and further utilize wet chemical brush coating and transient high temperature joule heat method in-situ synthesis conductive active layer, two are asymmetric sandwich structure, it is favorable to build charge transport path, improve charge transport efficiency, at the same time, can effectively relieve the volume change generated in the process of charge and discharge of iron oxide, unlike the characteristics of particle composite structure easy to collapse, inhibit the occurrence of electrode material pulverization, wherein, using transient high temperature joule heat preparation technology, layered in-situ build heterostructure, not only simple and fast, also make the structure compact and dense, maintain the stability of overall electrode structure, improve the long-period cycle charge and discharge capacity of electrode.

This invention provides a two-dimensional MOF / MXene heterojunction, its preparation method, and its applications, relating to the fields of nanomaterial preparation and sensing technology. The method involves transferring large-size two-dimensional MXene nanosheets to a substrate and fixing them on a rotating platform. Under rotation and illumination, a metal salt solution and an organic ligand solution are sequentially added to the MXene surface through a layer-by-layer assembly process. Centrifugal force is used to spread the solution and remove excess liquid. After cyclic reaction, a MOF layer is grown in situ on the MXene surface, forming a MOF / MXene heterojunction. This invention also provides the two-dimensional MOF / MXene heterojunction obtained by the above preparation method. Furthermore, this invention provides the application of the two-dimensional MOF / MXene heterojunction prepared by the above method in the field of sensing and detection. The sensor constructed based on this invention exhibits high sensitivity, low detection limit, and good stability, making it suitable for high-precision sensing and detection.

The invention discloses a binder-free transition metal sulfide composite nitrogen-doped graphene negative electrode material and a preparation method thereof, and belongs to the technical field of secondary battery negative electrode materials. According to the technical scheme, the preparation method comprises the following steps: 1) dissolving zinc nitrate, cobalt nitrate and nitrogen-doped graphene in a mixed solution of ethanol and water, uniformly mixing, adding ammonium fluoride and urea, and continuously stirring; 2) adding foamed nickel and the uniformly mixed solution into a high-pressure reaction kettle for hydrothermal treatment, cooling, washing and drying to obtain a Zn-Co-precursor; (3) calcining the Zn-Co-precursor in an inert atmosphere, and (4) adding the Zn-Co-precursor into a high-pressure reaction kettle containing a sulfur source for hydrothermal vulcanization treatment, washing and drying to obtain the ZnCo2S4-coated NGr / NF negative electrode material.The graphene negative electrode material can improve the overall performance and stability of a secondary battery.

The invention belongs to the technical field of electrochemical energy storage, and relates to a positive and negative differential integrated electrode for a static filmless zinc-bromine battery and a battery stack. The electrode comprises a flexible graphite composite bipolar plate, one side of the flexible graphite composite bipolar plate is compounded with a non-conductive negative electrode thin pre-oxidized felt subjected to oleophobic modification, the other side of the flexible graphite composite bipolar plate is compounded with a positive electrode thick activated graphite felt which has a gradient pore structure and is loaded with a bromine oxidation reduction catalyst, the contact side of the bipolar plate and the negative electrode felt is activated, and the three layers are compounded into an integrated structure. The stack is horizontally placed, positive and negative electrode felts of adjacent electrodes are directly attached and compressed, no diaphragm exists, and the compression ratio is controlled by a limiting column. Three-dimensional uniform deposition of zinc is guided through the negative electrode non-conductive felt, the bromine oil phase is locked through cooperation of positive electrode gradient pores and gravity settling, the contact resistance is reduced through the integrated structure, non-film static operation is achieved, the cycle life exceeds 500 times, the self-discharge rate is lower than 0.45%, the energy efficiency is higher than 80%, the structure is simplified, and the lithium ion battery is suitable for large-scale production.