1323 results about "High surface area" patented technology

Preferred embodiments of the present invention provides a sublimation system employing guidance structures including certain preferred embodiments having a high surface area support medium onto which a solid source material for vapor reactant is coated. Preferably, a guidance structure is configured to facilitate the repeated saturation of the carrier gas with the solid source for a vapor reactant. Methods of saturating a carrier gas using guidance structures are also provided.

This invention relates to rigid porous carbon structures and to methods of making same. The rigid porous structures have a high surface area which are substantially free of micropores. Methods for improving the rigidity of the carbon structures include causing the nanofibers to form bonds or become glued with other nanofibers at the fiber intersections. The bonding can be induced by chemical modification of the surface of the nanofibers to promote bonding, by adding "gluing" agents and / or by pyrolyzing the nanofibers to cause fusion or bonding at the interconnect points.

This invention discloses a cost-effective process for separating contaminants and a wide-range of fouling material from surface water, ground water and from industrial effluents. Having undergone effective pre-treatment, the water can be purified further by using high-surface area spirally wound micro-filtration (MF), ultra-filtration (UF), nano-filtration (NF) or reverse osmosis (RO) membranes. High-quality potable water free from pathogen and other contaminants is thus produced at low-cost from the pre-treated surface water and ground-water. Conversely, pre-treated industrial effluents are further purified at a relatively low-cost using NF or RO membranes, thus producing water suitable for recycle or surface discharge. The process of this invention uses cationic inorganic and / or polymeric flocculants to coagulate and flocculate the water-borne colloidal matter (e.g. clays, iron hydroxides, naturally occurring matter (NOM's), etc.), followed by filtration using a multi-media filter, charge neutralization and reversal and final filtration using a 5-micron cartridge filter. These pre-treatment steps provides a good quality water having a low Silt Density Index and a significant negative zeta potential, thereby ensuring against irreversible chemical fouling of the spirally-wound membranes.

A process for selective formation of ethanol from acetic acid includes contacting a feed stream containing acetic acid and hydrogen at an elevated temperature with catalyst comprising platinum and tin on a high surface area silica promoted with calcium metasilicate. Selectivities to ethanol of over 85% are achieved at 280° C. with catalyst life in the hundreds of hours.

Pressure swing adsorption separation of a feed gas mixture, to obtain a purified product gas of the less strongly adsorbed fraction of the feed gas mixture, is performed in a plurality of preferably an even number of adsorbent beds, with each adsorbent bed communicating at its product end directly to a variable volume expansion chamber, and at its feed end by directional valves to a feed compressor and an exhaust vacuum pump. For high frequency operation of the pressure swing adsorption cycle, a high surface area layered support is used for the adsorbent. The compressor and vacuum pump pistons may be integrated with the cycle, reciprocating at twice the cycle frequency. Alternative configurations of the layered adsorbent beds are disclosed.

A nanowire-based Li-ion rechargeable battery having superior performance with little capacity fade for use in applications including consumer electronics and medical devices is made by incorporating nanowire construction of the cathode. The nanowire-based battery system includes a nanostructured high surface area cathode structure fabricated by electrodeposition using alumina nanopore templates.

The present invention concerns a method and an apparatus for removing substances from gases discharged from gas phase reactors. In particular, the invention provides a method for removing substances contained in gases discharged from an ALD reaction process, comprising contacting the gases with a “sacrificial” material having a high surface area kept at essentially the same conditions as those prevailing during the gas phase reaction process. The sacrificial material is thus subjected to surface reactions with the substances contained in the gases to form a reaction product on the surface of the sacrificial material and to remove the substances from the gases. The present invention diminishes the amount of waste produced in the gas phase process and reduces wear on the equipment.

New low-cost CO2 sorbents are provided that can be used in large-scale gas-solid processes. A new method is provided for making these sorbents that involves treating substrates with an amine and / or an ether so that the amine and / or ether comprise at least 50 wt. percent of the sorbent. The sorbent acts by capturing compounds contained in gaseous fluids via chemisorption and / or physisorption between the unit layers of the substrate's lattice where the polar amine liquids and solids and / or polar ether liquids and solids are located. The method eliminates the need for high surface area supports and polymeric materials for the preparation of CO2 capture systems, and provides sorbents with absorption capabilities that are independent of the sorbents' surface areas. The sorbents can be regenerated by heating at temperatures in excess of 35° C.

The present invention is directed to a substrate having a plurality of microfeatures that provide a high surface area and are open to provide ready access to fluids and components therein. Methods of making the high surface area substrates are described and include generating microfeatures and / or microstructures on the surface of the substrate.

The present invention has multiple aspects. In its simplest aspect, the present invention is directed to an intermediate bone block comprising a machined segment of cortical bone, cancellous bone or both, the intermediate having a face comprising one to ten compression surfaces and one to ten cavities, the compression surfaces suitable for compressing soft tissue, the cavities for receiving and holding overflow soft tissue. The cavities are preferably channels, and more preferably channels having an omega cross-sectional profile. Surprisingly, the cavities and channels, which reduced the compressed surface area between the intermediate bone block and the tendon, significantly improved tendon load at failure. In standardized tests, an intermediate bone block of this invention, when combined with high surface area bone blocks of the prior art bone blocks, unexpectedly increased their load at failure. The invention is also directed to bone block assemblies suitable for binding to a soft tissue to form an implantable graft, and to such implantable grafts. A particularly preferred graft is a bone-tendon-bone graft.

A burner assembly includes a catalyzed burner for combusting an anode exhaust stream from a polymer electrolyte membrane (PEM) fuel cell power plant. The catalysts coated onto the burner can be platinum, rhodium, or mixtures thereof. The burner includes open cells which are formed by a lattice, which cells communicate with each other throughout the entire catalyzed burner. Heat produced by combustion of hydrogen in the anode exhaust stream is used to produce steam for use in a steam reformer in the PEM fuel cell assembly. The catalyzed burner has a high surface area wherein about 70-90% of the volume of the burner is preferably open cells, and the burner has a low pressure drop of about two to three inches water from the anode exhaust stream inlet to the anode exhaust stream outlet . The burner assembly operates at essentially ambient pressure and at a temperature of up to about 1,700° F. (646° C.). The burner assembly can combust anode exhaust during normal operation of the fuel cell assembly. The burner assembly also includes an adjunct burner which can combust gasoline or anode bypass gas (the latter of which is a reformed fuel gas which is tapped off of the fuel cell stack fuel inlet line) during startup of the fuel cell power plant. Once start up of the fuel cell power plant is achieved, the burner assembly will need only combustion of the anode exhaust by the catalytic burner to produce steam for the reformer.

A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m2 / g to about 200 m2 / g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh / g at rate of C / 3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg / cm2 to about 3.5 mg / cm2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.

This invention concerns novel compositions, useful as hydrogenation catalyst, said compositions comprising metals and metal ions such as ruthenium (Ru) or palladium (Pd) dispersed in and distributed throughout a matrix comprising an inorganic or silicon oxide network. The catalyst may be prepared by the sol-gel method; a solution of at least one catalytic metal compound is added to a solution of at least one metal alkoxide selected from Al, Ti, Nb, Zr, Ta, Si and other inorganic alkoxides, and then gelling the mixture. Promotors such as rhenium (Re), molybdenum (Mo) and tin (Sn) may be added. The catalyst may be used in the reduction of metallic acid or gamma-butyrolactone to tetrahydrofuran (THF) and 1,4-butanediol (BDO).

A method for forming a battery from via thin-film deposition processes is disclosed. A mesoporous carbon material is deposited onto a surface of a conductive substrate that has high surface area, conductive micro-structures formed thereon. A porous, dielectric separator layer is then deposited on the layer of mesoporous carbon material to form a half cell of an energy storage device. The mesoporous carbon material is made up of CVD-deposited carbon fullerene “onions” and carbon nano-tubes, and has a high porosity capable of retaining lithium ions in concentrations useful for storing significant quantities of electrical energy. Embodiments of the invention further provide for the formation of an electrode having a high surface area conductive region that is useful in a battery structure. In one configuration the electrode has a high surface area conductive region comprising a porous dendritic structure that can be formed by electroplating, physical vapor deposition, chemical vapor deposition, thermal spraying, and / or electroless plating techniques.

Uniform cooling of complex surface shapes in injection mold tooling can be accomplished with cooling channels that conform to the shapes of the mold cavity or mold cone. By conventional methods this can be very difficult to accomplish. By applying methods of material deposition or material sintering, which include but are not limited to, laser metal deposition, where material is deposited on a layer by layer basis, certain cooling or heating passages could be integrated into the manufactured component that follow the contours and profiles of the mold's complex surfaces. These passages would act as internal heat sinks with a much higher surface area for heat transfer than traditional drilled and plugged straight passages. These geometries could also be incorporated into complex geometries such as, but not limited to, turbine blades where the cooling passages can follow the contour of the outer shape, provide a more uniform or controlled heat transfer from the component. Multiple loops of cooling or heating channels could be designed and manufactured into solid objects for small-scale heat exchanger technologies.

Metal-organic framework (MOF)-polymer mixed matrix membranes (MOF-MMMs) have been prepared by dispersing high surface area MOFs (e.g. IRMOF-1) into a polymer matrix (e.g. Matrimid 5218). The MOFs allow the polymer to infiltrate the pores of the MOFs, which improves the interfacial and mechanical properties of the polymer and in turn affects permeability. Pure gas permeation tests show the incorporation of 20 wt-% of IRMOF-1 in Matrimid 5218 polyimide matrix results in 280% improvement in CO2 permeability without a loss of CO2 / CH4 selectivity compared to those of the pure Matrimid 5218 membrane. This type of MOF-MMMs has significantly improved gas separation performance with dramatically high CO2 permeability (>35 barrer) and higher than 29 CO2 / CH4 selectivity at 50° C. under 100 psig pressure, which are attractive candidates for practical gas separation applications such as CO2 removal from natural gas.

A dimensionally stable, highly resilient, hybrid copolymer solid-solution electrolyte-retention film for use in a lithium ion battery in one preferred embodiment has a predominantly amorphous structure and mechanical strength despite contact with liquid solvent electrolyte. The film is a thinned (stretched), cast film of a homogeneous blend of two or more polymers, one of which is selected for its pronounced solvent retention properties. A very high surface area inorganic filler dispersed in the blend during formation thereof serves to increase the porosity of the film and thereby enhance electrolyte retention. The film is soaked in a solution of liquid polymer with liquid organic solvent electrolyte and lithium salt, for absorption thereof. Use of a cross-linked liquid polymer enhances trapping of molecules of the electrolyte into pores of the film. The electrolyte film is sandwiched between flexible active anode and cathode layers to form the lithium ion battery. Novel methods are provided for forming the electrodes, the polymer substrate, and other elements of the battery.

An apparatus for purifying water, such as for desalinization, includes a source of a heated air stream, the heated air stream having a temperature above an ambient temperature. A diffusion tower having high surface area material therein receives a water stream including at least one impurity and creates at least one region having thin films of water therein from the water stream. The heated air stream is directed over the thin films of water to create a humidified air stream that is at least substantially saturated. At least one direct contact condenser is in fluid communication with the humidified air stream for condensing the humidified air stream, thus producing purified water. A power plant can include the apparatus for purifying water, where energy to heat the air stream is provided by low pressure condensing steam.

The present application is generally directed to ultrapure synthetic carbon materials having both high surface area and high porosity, ultrapure polymer gels and devices containing the same. The disclosed ultrapure synthetic carbon materials find utility in any number of devices, for example, in electric double layer capacitance devices and batteries. Methods for making ultrapure synthetic carbon materials and ultrapure polymer gels are also disclosed.

This invention provides a continuous process for the growth of vapor grown carbon fiber (VGCNT) reinforced continuous fiber preforms for the manufacture of articles with useful mechanical, electrical, and thermal characteristics. Continuous fiber preforms are treated with a catalyst or catalyst precursor and processed to yield VGCNT produced in situ resulting in a highly entangled mass of VGCNT infused with the continuous fiber preform. The continuous process disclosed herein provides denser and more uniform carbon nanotubes and provides the opportunity to fine-tune the variables both within an individual preform and between different preforms depending on the characteristics of the carbon nanotubes desired. The resulting continuous fiber preforms are essentially endless and are high in volume fraction of VGCNT and exhibit high surface area useful for many applications. The invention also provides for composites made from the preforms.

An anaerobic digester system has a vertically upright vessel, a matrix arranged in the vessel supporting a microorganism biomass thereon, an input for supplying an input slurry of liquid and suspended solids at an upper portion of the vessel above the matrix, a gas output at the top of the vessel for withdrawing gas generated by anaerobic digestion of solids, and an effluent output at the bottom of the vessel for withdrawing liquid and remaining solids. The vessel has a preferred liquid height to diameter ratio of 2 to 1, and is constructed of inert fiberglass-reinforced plastic coated with a translucent blue gel pigment layer for filtering light at wavelengths that promote biomass cultivation. The matrix is formed as an array of panels mounted to a spindle with wheels fixed at spaced intervals along its vertical height, and the panel are made of a polyethylene grass matting providing a high surface area to volume ratio of at least 20 to 1. Gas from the top of the vessel is recycled to the bottom to generate bubbles for mixing the feedstock. The related method of anaerobic digestion includes comminuting input wastes with a slurry grinder into a pumpable slurry 8-10 % by weight solids, and providing as the biomass hydrolytic bacteria, and fermentative bacteria including acetogenic and methanogenic bacteria to produce a methane gas product. Other products include an organic soil additive, bacterial solids plant food, and a filtrate used as plant tonic.

A bio-implantable electrochemical cell system for active implantable medical devices. In one embodiment, the fuel cell includes an electrode structure consisting of immobilized anode and cathode enzymes deposited on nanostructured high-surface-area metal nanowires or carbon nanotube electrodes. The anode enzyme comprises immobilized glucose oxidase and the cathode enzyme comprises immobilized laccase. Glucose is oxidized at the surface of the anode and oxygen is reduced at the surface of the cathode. The coupled glucose oxidation-oxygen reduction reactions provide a self-generating current source. In another embodiment, the nanowires or carbon nanotubes, along with the adjacent surface anode and cathode electrodes, are coated with immobilized glucose oxidase and immobilized laccase containing biocolloidal substrates, respectively. This results in the precise construction of an enzyme architecture with control at the molecular level, while increasing the reactive surface area and corresponding output power by at least two orders of magnitude.

Ionomeric polymer sensors, actuators, and transducers and methods for fabricating them are disclosed. One embodiment of the sensors, actuators, and transducers possess a high surface area electrode layer that is applied by hot pressing and a highly conductive surface layer. Another embodiment of these sensors, actuators, and transducers possess a high surface area electrode layer that is penetrated by electronically conductive nanowires. Methods for fabricating these sensors, actuators, and transducers are disclosed. These methods involve the formation of the high surface area layer from a liquid mixture that contains ionomeric polymer, electronically conductive particles, and possibly diluent. This mixture is formed into layers either directly on an ionomeric polymer, on a separate transfer decal, or on an electronically conductive layer. This electronically conductive layer may also include an array of nanowires. These electrode layers are then attached to an ionomeric polymer membrane by hot pressing. The ionomeric polymer membrane may be swollen with a diluent either prior to the hot pressing or after the hot pressing step. Also, the ionomeric polymer membrane may be formed by casting from a liquid mixture containing ionomeric polymer and diluent.

A method of hydroprocessing a heavy hydrocarbon feedstock using a hydroprocessing catalyst having specific properties making it effective in the hydroconversion of at least a portion of the heavy hydrocarbon feedstock to lighter hydrocarbons. The hydroprocessing catalyst comprises a Group VIB metal component (e.g., Cr, Mo, and W), a Group VIII metal component (e.g., Ni and Co) and, optionally, a potassium metal component that are supported on a support material comprising alumina. The alumina has novel physical properties that, in combination with the catalytic components, provide for the hydroprocessing catalyst. The hydroprocessing catalyst is particularly effective in the conversion of the heavy hydrocarbon feedstock. The alumina is characterized as having a high pore volume and a high surface area with a large proportion of the pore volume being present in the pores within a narrow pore diameter distribution about a narrowly defined range of median pore diameters. The support material preferably does not contain more than a small concentration of silica. The alumina component is preferably made by a specific method that provides for an alumina having the specific physical properties required for the hydroprocessing catalyst.

A process for producing-vapor grown carbon fiber (VGCF) reinforced continuous fiber performs for the manufacture of articles with useful mechanical, electrical, and thermal characteristics is disclosed. Continuous fiber preforms are treated with a catalyst or catalyst precursor and processed to yield VGCF produced in situ resulting in a highly entangled mass of VGCF infused with the continuous fiber preform. The resulting continuous fiber preforms are high in volume fraction of VGCF and exhibit high surface area useful for many applications. Furthermore, this invention provides for a continuous fiber preform infused with VGCF so that the carbon nanofibers are always contained within the fiber preform. This eliminates the processing steps for isolated carbon nanofibers reported in other carbon nanofiber composite approaches and therefore greatly reduces risk of environmental release and exposure to carbon nanofibers.