204 results about "Functionalized polymer" patented technology

The invention discloses a mesoporous solid acid composite catalyst as well as preparation and application thereof, and particularly relates to a preparation method and application of an acid-functionalized COF polymer and Beta molecular sieve composite catalyst. The solid acid composite catalyst is prepared from an acid functionalized COF polymer and a molecular sieve material through mechanical grinding, and the preparation method is simple and convenient. The solid acid composite catalyst has the advantages of high crystallinity, large specific surface area, rich pore structure, good chemical stability and the like. The prepared composite catalyst is stable in performance and high in activity at low temperature, polyoxymethylene dialkyl ether can be selectively synthesized, and the effect that reaction products do not conform to Schulz-Flory distribution is achieved by adjusting the composition of the composite catalyst.

The invention provides a conjugated frame encapsulated graphene functionalized polymer anti-corrosion anti-impact double-effect heat-conducting coating and a preparation method thereof, the method comprises the following steps: step S1, mixing graphene with a bromine source to prepare brominated graphene; step S2, adding a halogen monomer, a conjugated alkyne monomer, a catalyst and the brominated graphene obtained in the step S1 into a mixed solution, and inducing a conjugated frame to perform in-situ packaging on the surface of the graphene in an inert gas atmosphere to prepare conjugated frame packaged graphene; s3, performing high-temperature carbonization treatment on the conjugated frame packaged graphene obtained in the step S2, and permeating a corrosion-resistant matrix to prepare a conjugated frame packaged graphene functional polymer; and step S4, loading a heat conduction material and a thickening agent on the graphene functionalized polymer obtained in the step S3 to prepare the graphene functionalized polymer coating. The coating prepared by the invention has the characteristics of continuous conjugate frame, hierarchical pore structure and corrosion resistance and impact resistance, and is suitable for the field of protection of efficient heat exchange equipment.

The invention discloses a method for preparing a functionalized polymer based on a macro-micro reactor chemical-enzyme method, which comprises the following steps: reacting a mixed solution of an acrylate monomer, an initiator, a ligand, a functional alcohol and a solvent in a micro reactor to obtain a reaction solution containing functionalized polyacrylate, and the micro reactor comprises the macro-micro reactor containing a copper internal member. In a macro-micro reactor, enzymatic ester exchange and Cu (0)-RDRP coupling reaction are carried out to obtain poly (methyl) acrylate with a series of chemical structures and copolymers of the poly (methyl) acrylate. The method is wide in applicable substrate range, and compared with a traditional synthesis method, the macro-micro reactor containing the internal component can remarkably shorten the polymerization time, secondary purification of the monomer is avoided, and the conversion rate is greatly increased. The characteristic scale of the macro-micro reactor reaches centimeter level, and high-flux synthesis can be realized. The invention provides a technical scheme for the preparation of the functionalized poly (methyl) acrylate polymer, and has an industrial conversion prospect.

Described herein are hydrophilic functionalized polymers (HFPs), methods of preparing such HFPs. Also described are methods of solubilizing hydrophobic drugs using such HFPs. HFP-drug composites, and methods of administering such HFP-drug composites.

High molecular weight functionalized polymers (“high dielectric polymers”) are disclosed herein, along with related methods of use and manufacture. The high dielectric polymers have a relatively high dielectric permittivity (e.g., greater than 10) as well as a relatively low glass transition temperature (e.g., less than −30° C.). The polymers may be produced utilizing addition polymerization or anionic ring opening to yield a linear or branched polymer backbone containing numerous residual nucleophiles. Then, nucleophilic substitution may be carried out to functionalize the residual nucleophiles. The functionalized polymer may then be purified and used as polymer electrolyte in an electrochemical cell (e.g., as nonaqueous polymeric electrolyte in a secondary Li-ion battery), if desired.

The invention relates to the field of membrane material preparation, in particular to an amino acid derivative polymer membrane material and a preparation method thereof. The preparation method provided by the invention comprises the following steps: S1, preparing a polymer solution; S2, forming and depositing a membrane; S3, carrying out surface modification on the membrane; and S4, carrying out crosslinking treatment. The functional polymer membrane material is synthesized through the amino acid derivative, selective separation of specific ions or molecules can be achieved, and good biocompatibility, stability and application prospects are achieved. The technology can be widely applied to multiple fields of biological separation, environment purification, drug delivery and the like, and has remarkable innovativeness and practical value.

The invention discloses a mechanical property regulation and control method of an aromatic microcapsule, and belongs to the technical field of microcapsules. The preparation process of the microcapsule comprises the following steps: self-assembling CNC and an amino-functionalized polymer ligand on an oil-water interface to form a stable Pickering emulsion. Wall materials are deposited on the surfaces of emulsion droplets in situ, the CNC interface coverage rate is regulated and controlled by adjusting parameters such as the ligand concentration and the emulsion water phase pH value, and then a series of aromatic microcapsules with different mechanical properties are prepared. In addition, the functional microcapsules can be designed in a customized manner according to different application requirements, and good application prospects are shown.

The invention relates to the technical field of electrochemistry, in particular to a polymer composite film, a composite current collector and a preparation method thereof, a positive electrode and application thereof. The polymer composite film comprises a polymer base layer, and a first modified layer and a second modified layer which are respectively arranged on two opposite side surfaces of the polymer base layer, the material of the polymer base layer comprises one or more of polyethylene glycol terephthalate, poly (1, 4-cyclohexylenedimethylene terephthalate) and polyethylene glycol terephthalate-1, 4-cyclohexylenedimethylene terephthalate; the first modified layer and the second modified layer respectively and independently comprise the following components: a functional polymer material; the functional polymer material comprises one or more of polyethylene naphthalate, polyadipyl metaphenylene diamine, a liquid crystal polymer, polyformaldehyde, polyphenylene sulfide and polyphenyl ether. The polymer composite membrane disclosed by the invention can be effectively broken when being damaged by relatively strong external force, so that thermal runaway of the battery can be effectively prevented.

The present invention relates to an advanced dressing characterized by a powder of polymeric material based on poly(lactic-co-glycolic) acid, functionalized with dextran, maltodextrin, collagen, citric acid, chitosan, polyphenols, colloidal silver, hyaluronic acid and / or salts thereof, polyethylene glycol and alginate. The present invention further relates to a process for producing the powder and the use of the powder in treating non-necrotic skin wounds.

An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 20 to about 40 phr of a polybutadiene having a cis-1,4 linkage content of at least 95%; about 40 to about 70 phr styrene / butadiene copolymer; about 5 to about 30 phr natural rubber or polyisoprene; a curative agent; an antioxidant; about 1 to about 20 phr carbon black; about 1 to about 30 phr plasticizing oil; about 40 to about 80 phr silica; about 1 to about 15 phr silane coupling agent and about 5 to about 30 phr of a polymer selected from the group consisting of an ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer.

The invention discloses a battery intelligent thermal management coating based on reversible Diels-Alder reaction and a preparation method and application thereof.The coating is of a multi-layer composite structure and comprises a basic binding layer, a functional thermal management layer and a protective isolation layer, the functional thermal management layer is composed of a functional polymer grafted with furan and maleimide groups, the reverse reaction temperature of the reversible Diels-Alder reaction is 80-120 DEG C, the temperature of the functional thermal management layer is 20-30 DEG C, and the temperature of the protective isolation layer is 20-30 DEG C. And the heat absorption capacity is 500-800J / g. The preparation method comprises the following steps: preparing slurry containing the functional polymer, coating a battery assembly with the slurry, and curing at 80-100 DEG C to form a coating. The coating can be applied to a battery electrode, an electrochemical energy storage device and a battery module, instantaneously absorbs heat through reverse reaction at the early stage of thermal runaway of the battery, and automatically resets after the temperature is reduced, so that circulating reuse is realized. The material is high in heat absorption efficiency, high in response speed, compatible with the electrochemical performance of the battery, capable of effectively reducing the thermal runaway risk of the battery, and suitable for various electrochemical energy storage devices such as lithium ion batteries and sodium ion batteries.

The invention discloses an anticoagulation endothelium slow release promoting coating and a preparation method thereof, and relates to the technical field of biomedical materials, the method comprises the following steps: soaking a substrate material in a guide layer solution prepared from dopamine, a silane coupling agent containing double bonds and an amino compound; immersing in an assembly layer solution prepared from a double-bond functionalized high-molecular compound and an endothelial active promoting substance, taking out, and carrying out photo-crosslinking curing; and immersing in a regulation and control layer solution prepared from a double-bond functionalized high-molecular compound and a zwitterionic monomer, and finally taking out for photo-crosslinking and curing to obtain the anti-coagulation endothelial sustained-release promoting coating. According to the method, efficient packaging and slow release of anticoagulation and endothelialization promoting active substances are achieved, and the prepared coating remarkably improves the performance of a blood contact instrument in the aspects of acute-stage thrombus formation resistance and long-acting endothelialization promotion after implantation.

The invention provides a hot melt adhesive and a preparation method thereof, and relates to the technical field of adhesives. According to the hot melt adhesive, amorphous polyolefin (APAO) is used as a main body, ethylene-vinyl acetate copolymer (EVA) is added as a compatilizer, and Fischer-Tropsch wax is used as a viscosity modifier. The preparation method comprises the following steps: firstly synthesizing a dopamine functional polymer, and then carrying out melt blending on the dopamine functional polymer, APAO, EVA, tackifying resin and other components so as to stably introduce a catechol group into a hot melt adhesive system. When the hot melt adhesive is bonded with a metal surface, the catechol group can form a firm coordinate bond with metal ions, so that the adhesive force is greatly improved. The product provided by the invention has high adhesive force, excellent flexibility, good compatibility and construction performance, and is suitable for bonding and sealing metal materials.

A functionalized diene polymer having at least one first functional group and at least one second functional group, wherein the first functional group is selected from end groups, side groups, and combinations thereof, the second functional group is an end group, the first functional group comprises at least one unit derived from a functionalized monomer represented by formula (1) (wherein R1, R2, and R3 are selected from hydrogen and methyl, provided that at least one of R1, R2, and R3 is hydrogen, preferably R1, R2, and R3 are all hydrogen, n is 1, 2, 3, 4, or 5, each R4 is independently selected from aliphatic residues or arylaliphatic residues having 3 to 30 carbon atoms, and R4 contains at least one tertiary amine group when n = 1, and at least one of the residues R4 contains at least one tertiary alkylamine group when n = 2 to 5); or (ii) the first functional group is obtained by using a polymerization initiator of the general formula: N(R1)(R2)(R3M) (wherein R1 and R2 are the same or different from each other and are selected from linear or branched saturated alkyls, R3 is a saturated, linear or branched alkyl carbanion, and M is an alkali cation), the second functional group is an end group, and comprises at least one group selected from -COOX; -OX; -SX (wherein X represents hydrogen or a cation), a plurality thereof, and combinations thereof. Also provided are a method for producing the polymer, an article obtained from the polymer, and a method for producing an article with the polymer, wherein the functionalized diene polymer is a homopolymer or copolymer of a conjugated diene, and the conjugated diene is selected from the group consisting of butadiene, isoprene, isoprene, 1,3-pentadiene, 2,3-dimethylbutadiene, 1-phenyl-1,3-butadiene, 1,3-hexadiene, preferably butadiene.

The present invention provides a rubber composition suitable for use in tire manufacturing, comprising a functionalized polymer and a functionalized silica.

The invention relates to the technical field of chemical preparation, and discloses a preparation method of a phthalimide compound, which comprises the following steps: S1, raw material mixing: sequentially adding phthalic anhydride, a primary amine compound, p-toluenesulfonic acid and phosphorus pentoxide into a reaction container with a stirring device and a temperature control module, and stirring for 1-2 hours; adding ethanol as a solvent, and carrying out a stirring reaction; s2, curing: cooling the reaction liquid to 20-25 DEG C, slowly adding deionized water into the reaction liquid while stirring, standing, and separating out a solid product; a traditional dehydrating agent is changed into a low-cost green dehydrating agent combination, so that the cost loss is reduced, the stimulation effect is reduced, the catalytic activity is equivalent to that of p-toluenesulfonic acid by adding a new sulfonic group functional polymer, but the problems of volatility of liquid acid and equipment corrosion are avoided, a low-toxicity and low-cost solvent of ethanol is added, the toxicity is reduced, and the environment-friendly dehydrating agent is prepared. The preparation is safer, the cost is lower, and the applicability is wider.

The invention belongs to the technical field of conductive materials, and particularly relates to a method for preparing and activating pyridine functionalized swelling polymer microspheres and a method for preparing core-shell structure polymer conductive microspheres. The preparation method comprises the following steps: by taking polystyrene microspheres as seeds, preparing pyridine functionalized polymer microspheres through an emulsion swelling method, then introducing Pd < 2 + > ions through coordination, preparing activated microspheres with palladium nanoparticles uniformly coated on the surfaces of the polymer microspheres through in-situ reduction, preparing nickel-plated microspheres with uniform metal coatings through chemical plating, and finally preparing the polymer microspheres with uniform metal coatings. And finally, preparing the core-shell structure gold-plated polymer conductive microspheres through in-situ reduction, and applying the core-shell structure gold-plated polymer conductive microspheres to preparation of anisotropic conductive films. Through an emulsion swelling method, not only can the polymer microspheres with adjustable sizes be prepared, but also the polymer microspheres with different morphologies can be prepared. The preparation method of the conductive microspheres has the advantages of being wide in raw material source, easy and convenient to operate and adjustable in metal coating thickness, and is suitable for high-precision packaging in the microelectronic industry.

The invention discloses a synthesis method of a novel polyfluorene block copolymer modified by different blocks at two ends. Through a step-by-step grafting strategy, carboxyl terminated functional polymer blocks and boric acid ester terminated functional polymer blocks are introduced to the two ends of a polyfluorene PFO chain respectively, and the copolymer Polymer2-b-PFO-b-Polymer1 with the asymmetric structure is prepared. The preparation method comprises the following specific steps: step 1, synthesizing polyfluorene PFO-2 of which the tail end is hydroxyl and bromine; step 2, grafting the PFO-2 and the carboxyl-terminated polymer, and synthesizing a single-end modified block copolymer PFO-b-Polymer1 (PFO-b-Polymer1), so as to obtain a single-end modified block copolymer PFO-b-Polymer1; and step 3, carrying out secondary grafting on the product obtained in the step 2 and a polymer terminated by boric acid ester to obtain the polyfluorene block copolymer Polymer2-b-PFO-b-Polymer1 of which the two ends are modified by different blocks. By regulating and controlling the functional design of the blocks at the two ends of the polyfluorene, the photoelectric property, the thermal stability, the mechanical strength and the environmental tolerance of the material are effectively improved, and the material is suitable for the photoelectric fields of organic light-emitting diodes, field effect transistors, solar cells and the like.

The present disclosure relates to a functionalized polymer for use in a hemodialysis treatment for the extraction of at least one metal cation, the metal being iron, in a subject in need thereof, wherein said functionalized polymer has a weight average molecular mass between 100 kDa and 1000 kDa, and wherein a part of the monomeric units are functionalized with a chelating moiety, and is present in the dialysate of the hemodialysis treatment, the concentration of said chelating moiety in the dialysate being less than 0.35 mM, preferably between 0.0035 mM and 0.315 mM.

A stabilizer for inclusion in a photohardenable composition comprising a hardenable resin component and a photoinitiator, the stabilizer comprising a stable free radical functionalized polymer, wherein the stabilizer is dispersible or dissolvable in the hardenable resin component. A photohardenable composition including a hardenable resin component, a photoinitiator, and a stabilizer comprising a stable free radical functionalized polymer and methods including a photohardenable composition and products of the methods are also disclosed. A photohardenable composition can further include an upconverting component.

A lactam-functionalized polymer is disclosed. The dihydroxy lactam based polymer includes polyesters, polycarbonates, polyethers, poly (ester ethers), poly (ester amides), poly imides, polyamides, poly acrylates and poly (ester imides), and polyurethanes. The applications of the dihydroxy lactam based polymers are also disclosed.

The present invention relates to side-chain functionalized polymers and copolymers and their use as alkaline anion exchange membrane materials, for example in alkaline water electrolyzers, fuel cells or flow batteries.

The invention belongs to the technical field of high polymer materials and coatings, and relates to an amino POSS (Polyhedral Oligomeric Silsesquioxane) crosslinking system for a water-based coating. The system takes water as a continuous phase, and comprises a water-soluble amino functionalized polyhedral oligomeric silsesquioxane (NPOSS) and an epoxy functionalized polyacrylate polymer microsphere aqueous dispersion, additives belonging to volatile organic compounds (VOC), such as organic solvents and coalescing agents, are not additionally added into the system. When in use, NPOSS as a multifunctional cross-linking agent is subjected to amine-epoxy addition reaction with an epoxy functionalized polymer in a water phase, and a cross-linked thermosetting coating can be formed on the surface of a base material such as an aluminum material, glass and the like. Compared with an existing water-based paint technology, the technology has the advantage that VOC emission in the film forming process of the water-based paint is remarkably reduced. Meanwhile, the NPOSS endows the coating with excellent thermal stability, mechanical strength and chemical resistance. The curing strategy is completely water-based, simple and convenient in process, environment-friendly and suitable for various fields with environmental protection requirements such as home furnishing, automobiles, aerospace and the like.

The application discloses a method for preparing photoelectric dual-response sensing polymer materials with self-repairing performance by using commercial olefin precursors and functionalized polymers based on the method; the method directly copolymerizes flexible comonomers and vinyl aromatic hydrocarbon monomers, and under suitable polymerization conditions, the two monomers are polymerized in a random copolymerization manner to generate functional polymers with micro-phase separation characteristics; the above method provided by the application can upgrade the commercial olefin monomers to obtain self-repairing performance, optical and electrical sensing performance, the conversion efficiency is high, the process is simple, the functionalization upgrading of the olefin polymers lacking of functions can be fully realized, the cost can be significantly reduced, the environmental pollution and resource waste can be reduced, and the application range of the olefin materials is widened.

A random terpolymer of N-(2-hydroxypropyl) methacrylamide, carboxybetaine methacrylamide and sulfobetaine methacrylamide, and a polymer brush and to a functionalized polymer brush containing this terpolymer are disclosed. The random terpolymer increases the resistance of the substrate surface to non-specific adsorption of substances from biological media and / or to non-specific interaction with biological media components, and is suitable for use in the form of a polymer brush, for example in sensors or membranes.

The present invention is directed to nanoparticles comprising an azanaphthalene-functionalized polymer and a biologically active component, where the polymer comprises a polyamine segment based on a bis(α,β-unsaturated carbonyl) monomer, an azanaphthalene-containing amine monomer that includes an azanaphthalene moiety, and an amine monomer. The present invention is further directed to polymeric nanoparticles for use in medical procedures, such as in vivo delivery of biologically active agents.

The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.

The invention belongs to the technical field of biomedicine, and particularly relates to a preparation method of a potassium K < + > recognition response quartz crystal microbalance chip and a blood potassium concentration quantitative detection method. A 3-aminopropyltriethoxysilane (APTES) solution is used for carrying out functionalization treatment on the surface of a silicon dioxide sheet, so that a large number of amino functional groups are obtained on the surface of the silicon dioxide sheet. The preparation method comprises the following steps: taking 4-acrylamide benzene-15-crown-5 as a template, then anchoring an ATRP (Atom Transfer Radical Polymerization) initiator-bromoisobutyryl bromide on the surface of the template through a covalent bond, and carrying out grafting construction of a benzene-15-crown-5 functional polymer brush by adopting Cu0-mediated surface-initiated atom transfer radical polymerization (Cu0-SI-ATRP) by taking 4-acrylamide benzene-15-crown-5 as a polymeric monomer. The potassium selective quartz crystal microbalance based on the crown ether functionalized polymer brush is obtained.

A functionalized copolymer comprising propylene repeating units and ω-substituted α-olefin repeating units, is disclosed. Also disclosed are polymer blends comprising the functionalized polymer and po

An embolic hydrogel for a patient comprises an aqueous buffer and at least one functionalized polymer, each having at least one polymer backbone chemically modified with one or more functional groups. The functional groups facilitate the formation of a primary reversible cross-link on the polymer backbone such that the embolic hydrogel transitions from a gel state to a viscous liquid state in response to shear forces applied to the embolic hydrogel and transitions from the viscous liquid state to the gel state in response to the absence of shear forces applied to the embolic hydrogel. The embolic hydrogel also includes at least one phase change polymer that produces secondary crosslinking therein in response to a physiological environment such that the embolic hydrogel transitions from a gel state to a solid state.