471 results about "Carbazole derivative" patented technology

An organic electroluminescence element comprising: an anode layer, a cathode layer, and an organic luminescence layer therebetween, the organic luminescence layer having a carbazole derivative with a glass-transition temperature of 110° C. or higher, and a phosphorescent dopant. This structure makes it possible to provide an organic electroluminescence element which can make use of the triplet exciton state of the carbazole derivative even at room temperature and which has a practical life and superior heat-resistance.

Provided are an organic electroluminescence device having high current efficiency and a long lifetime, and a biscarbazole derivative for realizing the device. The biscarbazole derivative has a specific substituent. The organic EL device has a plurality of organic thin-film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin-film layers contains the biscarbazole derivative.

An Organic Light Emitting Diode (OLED) includes as active material a conjugated poly(N-alkyl-2,7-carbazole) derivative described by the formula: wherein n is an integer of about 3 to about 100, and R represents a substituant that is a linear or branched alkyl group containing 1 to 22 carbon atoms, or poly(ethyleneoxy), cyano, aryl, amide or benzoyl. Such OLEDs have improved light emitting properties, especially in the blue and red regions of the spectrum.

To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α1, α2, α3, and α4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar1 and Ar2 each represent an aryl group having less than or equal to 13 carbon atoms; R1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independently 0 or 1.

A light emitting element comprises a first electrode, a second electrode configured to transmitting light, an organic layer arranged between the first and the second electrodes, comprising a light emitting layer, and a capping layer arranged on the second electrode and made of a material with a higher refractive index than the refractive index of the material constituting the second electrode. The material constituting the capping layer comprises at least one selected from the group consisting of triarylamine derivative, carbazole derivative, benzimidazole derivative and triazole derivative.

The present invention describes indenocarbazole derivatives having electron and hole transport properties, especially for use in the emission layer and / or charge transport layer of electroluminescent devices or as matrix material. The invention further provides a process for preparing the compounds of the invention, and electronic devices comprising them.

To provide a method for producing a wide variety of carbazole derivatives which have a simple and uncomplicated process and in which variations in the yield, purity, etc. of a desired substance which are caused by an aryl group introduced is reduced as much as possible. A method for producing a carbazole derivative represented by General Formula (1) is provided, in which 9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole having an active site at the 3-position of the carbazole skeleton and an aromatic compound having an active site are coupled.In the formula, Ar1 represents an aryl group with 6 to 13 carbon atoms in a ring, and Ar1 may have a substituent.

Disclosed is an organic electroluminescent device (organic EL device) that is improved in the luminous efficiency, fully secured of the driving stability, and of a simple structure and also disclosed is a compound for organic EL device useful for the said device. The compound for organic EL device is, for example, an indolocarbazole derivative represented by the following general formula (3). The organic EL device comprises a light-emitting layer disposed between an anode and a cathode piled one upon another on a substrate and the said light-emitting layer comprises a phosphorescent dopant and the aforementioned indolocarbazole derivative as a host material. In general formula (3), L is an aromatic heterocyclic group of a fused-ring structure with a valence of (n+1), Ar1 to Ar3 each is an alkyl group, an aralkyl group, or a substituted or unsubstituted aromatic hydrocarbon or aromatic heterocyclic group, and n is an integer of 0-5.

Disclosed is an actinic ray curable ink-jet ink composition containing a photopolymerizable compound, a sulfonium salt (compound A) as a photoinitiator, which does not release benzene on actinic ray exposure, and a compound (compound B) as a sensitizing agent selected from the group consisting of (i) a polycyclic aromatic compound having a hydroxyl group, a substituted or unsubstituted aralkyloxy group or a substituted or unsubstituted alkoxy group, (ii) a carbazole derivative, and (iii) a thioxanthone derivative.

An object of the present invention is to provide a light emitting element which has low driving voltage and can increase lifetime longer than a conventional light emitting element. One feature is to include a plurality of layers which includes a layer containing a light emitting substance between first and second electrodes, in which at least one layer of the plurality of layers contains a carbazole derivative represented by General Formula (1) and a substance having an electron accepting property with respect to the carbazole derivative represented by General Formula (1). By employing this structure, the above object can be achieved.

A biscarbazole derivative having a specific group, which is represented by formula (1):and an organic electroluminescence device in which a plurality of organic thin-film layers including a light emitting layer are disposed between a cathode and an anode, and at least one of the organic thin-film layers include the biscarbazole derivative. The organic electroluminescence device exhibits high emission efficiency and has a long lifetime. In formula (1), each of A1 and A2 independently represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms; each of Y1 to Y16 independently represents C(R) or a nitrogen atom; each of R groups independently represents a hydrogen atom, etc.; and each of L1 and L2 independently represents a single bond, etc.; provided that at least one of A1, A2 and R represents a substituted or unsubstituted fluoranthenyl group, etc.

An object is to provide a carbazole derivative which has a wide band gap and with which excellent blue color purity is obtained. In addition, another object is to provide highly reliable light-emitting elements, light-emitting devices, lighting devices, and electronic devices in which the carbazole derivative is used. Carbazole derivatives represented by the general formulas (1), (P1), and (M1) are provided. Further, light-emitting elements, light-emitting devices, and electronic devices which are formed using the carbazole derivative represented any of the general formulas (1), (P1), and (M1) are provided.

An object is to provide a light emitting element with low drive voltage which contains an organic compound and an inorganic compound. One feature of a light emitting element of the present invention is to include a layer containing a light emitting material between a pair of electrodes, in which the layer containing a light emitting material has a layer containing a carbazole derivative represented by General Formula (1) and an inorganic compound which exhibits an electron accepting property to the carbazole derivative represented by General Formula (1). With such a structure, the inorganic compound accepts electrons from the carbazole derivative, carriers are generated internally, and a drive voltage of the light emitting element can be reduced.

An Organic Light Emitting Diode (OLED) includes as active material a conjugated poly(N-alkyl-2,7-carbazole) derivative described by the formula:wherein n is an integer of about 3 to about 100, and R represents a substituant that is a linear or branched alkyl group containing 1 to 22 carbon atoms, or poly(ethyleneoxy), cyano, aryl, amide or benzoyl. Such OLEDs have improved light emitting properties, especially in the blue and red regions of the spectrum.

The present invention provides a carbazole derivative of formula (I) for an organic electroluminescent device:wherein Y represents a heteroatom selected from N, O, P, S, or a bicyclic or tricyclic heterocyclic ring; andAr1 and Ar2 each independently represent an alkyl or aryl substituted or unsubstituted aromatic hydrocarbon, or an alkyl or aryl substituted or unsubstituted heterocyclic aromatic hydrocarbon.

Novel indolocarbazole derivatives potentially useful for the treatment of dementias characterized by tau hyperphosphorylation [Alzheimer's disease (AD), frontal lobe degeneration (FLD), argyrophilic grains disease, subacute sclerotising panencephalitis (SSPE) as a late complication of viral infections in the CNS], and cancer.

An object of the present invention is to provide a carbazole derivative which is useful in manufacturing a substance having resistance to oxidation. Another object is to provide a carbazole derivative which is useful in manufacturing a novel material with high reliability. Still another object is to provide a material for a light emitting element with high reliability. The present invention is a carbazole derivative represented by the following general formula (1) (where each of Ar1 and Ar2 represents an aryl group having 6 to 14 carbon atoms which may include a substitute, Ar1 and Ar2 may be either the same or different, and R in the formula represents hydrogen or an alkyl group having 1 to 4 carbon atoms). In addition, the present invention is a material for a light emitting element which includes a carbazole derivative represented by the following general formula (1) as a substituent.

An object is to provide a carbazole derivative that is useful as a raw material in manufacturing a light emitting element material having resistance to repetition of an oxidation reaction. The carbazole derivative is represented by General Formula (1) in the following. In General Formula (1), R1 represents any one selected from an alkyl group having 1 to 4 carbon atoms such as methyl, ethyl, and tert-butyl, and an aryl group having 1 to 12 carbon atoms such as phenyl, biphenyl, and naphthyl.

The present invention relates to a series of carbazole derivatives which are used in organic electroluminescent devices as the phosphorescent host materials of the emissive layers. The carbazole derivatives have glass transition temperature of between 70° C. and 220° C. and triplet energy of 2.62 eV or more. The carbazole derivatives comprise two carbazole groups and alkyl group and / or spiro group inserted between the carbazole group and aromatic group, which is represented by formula 1. The carbazole derivatives according to the present invention are used as host materials for the triplet emissive dyes and they have high energy and stability. They can also reduce the converse energy transfer from the dye molecules to the host molecules and improve the luminance and efficiency of the OLEDs, especially the efficiency and lifetime of the blue triplet OLEDs.

The problem of the present invention is to provide a carbazole derivative which has an excellent heat resistance and can be formed into a film without crystallization. Also, a problem is to produce an organic semiconductor element, a light emitting element and an electronic device by employing the carbazole derivative. For the purpose, a novel carbazole derivative represented by following general formula (1) is provided: (in the formula, I represents a core carbazole (G0) illustrated by general formula (2), Z represents an internally branched carbazole (G1 to Gn-1) illustrated by general formula (3), E represents an end carbazole (Gn) illustrated by general formula (4), n represents an integer showing generation number of dendrimer, X1 represents hydrogen, halogen, a cynano group, an alkyl group, an aryl group, a heterocyclic residue or the like, X2 and X3 in (G(n-m)-1) (provided, n-m≧1) make a covalent bond with X4 in (G(n-m)), and each of R1 to R8 represents independently hydrogen, halogen, a cynano group, an alkyl group, a dialkylamino group, a diarylamino group, a heterocyclic residue or the like).

The present invention provides a material having excellent hole injecting and hole transporting properties. Moreover, the present invention provides a light-emitting element and a light-emitting device using the material having excellent hole injecting and hole transporting properties. The present invention provides a carbazole derivative represented by the general formula (1). By applying the carbazole derivative of the present invention to a light-emitting element or a light-emitting device, a lower driving voltage, enhanced emission efficiency, a longer lifetime and enhanced reliability of the light-emitting element or the light-emitting device can be realized.

An organic EL element comprising an organic thin film layer containing a light-emitting layer between an positive electrode and a negative electrode, in which a layer in the organic thin film layer comprises 1,3,6,8-tetraphenylpyrene compound expressed by the following structural formula (1), and a carbazole derivative expressed by the following structural formula (2),in the structural formula (1), R1–R4 may be identical or different, and may be a hydrogen atom or a substituent group,

Disclosed is a compound of Formula 1 and an organic light emitting device using the same. In Formula 1, R1 to R3 and X1 to X3 are as described in the specification. The compound of Formula 1 acts as a hole injection material, a hole transport material, a light emitting host, or a light emitting dopant in the organic light emitting device depending on the type of substituent.

The invention relates to a (1) or (2) and its application in preparation of organic EL device. M is Zn or Pt; three substituent group or R1, R2, R3 are different or the same and at least one of them is alkoxy substituent carbazole derivative shown as (3); R10 and R11 are different or the same, as alkyl of C1-4 (n=4-12); the other two substituent group is H and alkoxy and alkyl (C1-C4) or alkoxy substituent carbazole derivative shown as (3). The device made by the invention has high efficiency of EL, outstanding solubility and filmibility, easy to be mixed with polymer, benefiting for research to EL device, can be used to prepare red luminous, with simple technique, benefit for industrialized batch production .

Novel indolocarbazole derivatives potentially useful for the treatment of dementias characterized by tau hyperphosphorylation [Alzheimer's disease (AD), frontal lobe degeneration (FLD), argyrophilic grains disease, subacute sclerotizing panencephalitis (SSPE) as a late complication of viral infections in the CNS], and cancer.

The invention discloses an electroluminescent material from near-ultraviolet to deep blue containing 9-alkly-1, 3, 6, 8-aryl used as substitute for carbazole derivative and a preparation method thereof. The structure of the invention can be expressed by element analysis, nuclear magnetic resonance spectrum and mass spectrum; the optical physic properties of the invention are studied by ultraviolet absorption spectrum and fluorescence spectrum; the application of the invention in organic light-emitting diodes is also studied. The experiment indicates that the compound has good dissolve performance and good heat stability; the light of near-ultraviolet or deep blue given out by solid powder and film has good color purity; the maximum wavelength of light is 390-440nm.

Provided is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, fully secured of driving stability, and simply constructed. The EL device has a light-emitting layer disposed between an anode and a cathode stacked one upon another on a substrate and the light-emitting layer comprises a phosphorescent dopant and an indolocarbazole derivative as a host material. Examples of the indolocarbazole compounds include a compound represented by the following formula (2) or (3), wherein X is N or CH, at least one of Xs is N, and Ar1 to Ar3 each is a substituted or unsubstituted aromatic group.

It is an object to provide an organic field effect transistor including an electrode which can reduce an energy barrier at an interface between a conductive layer and a semiconductor layer, and a semiconductor device including the organic field effect transistor. A composite layer containing an organic compound and an inorganic compound is provided in at least part of one of a source electrode and a drain electrode in an organic field effect transistor, and as the organic compound, a carbazole derivative represented by the general formula (1) is used. By providing the composite layer in at least part of one of the source electrode and the drain electrode, an energy barrier at an interface between a conductive layer and a semiconductor layer can be reduced.