The invention discloses a
polyimide covalent organic framework material based on truxene
ketone, a preparation method and application, and belongs to the technical field of preparation of
covalent organic framework materials, the
covalent organic framework material is prepared by taking 2, 7, 12-triamino-5H-diindole [1, 2-A: 1 ', 2'-C]
fluorene-5, 10, 15-
triketone as an amino ligand, taking
pyromellitic dianhydride or 2, 3, 6, 7-tetramethyl-4-
piperidine as an amino ligand, taking 2, 7, 12-triamino-5H-diindole [1, 2-A: 1 ', 2'-C]
fluorene-5, 10, 15-
triketone as an amino ligand, taking 2, 7, 12-triamino-5H-diindole [1, 1, 7-
naphthalenetetracarboxylic dianhydride is used as an
aldehyde group connecting unit and is formed through
acylation reaction condensation; according to the preparation method, a TRO ligand is introduced, high-activity sites with 18 carbonyl groups are formed in each pore channel of each layer, a shorter path is provided for rapid
diffusion of Li < + >, and rapid reaction
kinetics is achieved. And conjugate units are added and expanded in a COF framework through chain
engineering, so that the
electronic structure and the aperture are effectively adjusted, and the
electron conductivity and the
diffusion rate of Li < + > are improved. Due to the increase of the number of
benzene rings, active sites are continuously activated under large current, and even under the current of 20A g <-1 >, the material still has the state that the active sites are continuously activated, so that high reversible specific capacity,
high energy density and
high power density under the large current are realized.