This application relates to the field of
polymer materials technology, providing a PET
elastomer,
composite material, dynamic covalent network
polymer, and its preparation method and application. The
elastomer is prepared by in-situ self-
assembly of
crown ether-primary
amide dual-functionalized PET through
melt blending. Its
molecular network integrates a quasi-
rotaxane supramolecular crosslinking network. This structure is formed by the host-guest interaction between the
crown ether and the primary
amide, and can act as a sliding crosslinking point to dissipate energy through the sliding of cyclic components. This application employs a two-step end-capping-in-situ self-
assembly process to overcome the technical obstacles of low PET chain-end activity and poor compatibility between
polyrotaxane and PET, achieving molecular-level dispersion of quasi-
rotaxane in the PET matrix. This fully utilizes the molecular
pulley effect to achieve breakthrough
toughening of the
elastomer. Simultaneously, it combines rigid nanofillers modified with aminosilane
coupling agents to form a soft-hard synergistic network, enabling the PET
composite material to maintain high
toughness while simultaneously improving strength, modulus, and thermal properties.