1458results about How to "Improve mass transfer effect" patented technology

A functionalized mesoporous carbon composition comprising a mesoporous carbon scaffold having mesopores in which polyvinyl polymer grafts are covalently attached, wherein said mesopores have a size of at least 2 nm and up to 50 nm. Also described is a method for producing the functionalized mesoporous composition, wherein a reaction medium comprising a precursor mesoporous carbon, vinyl monomer, initiator, and solvent is subjected to sonication of sufficient power to result in grafting and polymerization of the vinyl monomer into mesopores of the precursor mesoporous carbon. Also described are methods for using the functionalized mesoporous carbon, particularly in extracting metal ions from metal-containing solutions.

Adsorbents and methods for the adsorptive separation of para-xylene from a mixture containing at least one other C₈ aromatic hydrocarbon (e.g., a mixture of ortho-xylene, meta-xylene, para-xylene, and ethylbenzene) are described. Suitable adsorbents comprise nano-size zeolite X having an average crystallite size of less than about 500 nanometers. The adsorbents provide both improved capacity and mass transfer, which is especially advantageous for improving productivity in low temperature, low cycle time adsorptive separation operations in a simulated moving bed mode.

Coal based carbon foams that are produced by the controlled beating of coal particulate in a mold and under a non-oxidizing atmosphere and subsequently graphitized have been found to provide excellent electrode materials for electrochemical cell applications.

A gas-liquid contact tray with fixed valves for mass transfer, in which the fixed valve comprising an upstream portion, a midportion and a downstream portion is made by punch from the tray deck so as to form as a deflector, and the upstream portion and the downstream portion are integrated with the tray deck, characterized in that said midportion has a central plane portion and downward inclined margins, and the tray deck is further provided with perforations which are arranged between the fixed valves adjacent in the liquid flow direction. The gas-liquid contact tray with fixed valves for mass transfer according to the present invention has a low liquid entrainment, low liquid weeping, a high mass transfer capacity and good turn-down characteristics.

The invention discloses a method and a device for treating garbage percolate, wherein the method comprises the steps of pretreatment, anaerobic treatment, membrane biochemical treatment, nanofiltration treatment, sludge treatment and the like; the device comprises a primary sedimentation tank (1) and an adjusting tank (2), the adjusting tank (2) is connected with an anaerobic reactor (3), the anaerobic reactor (3) is connected with a denitrification tank (4), and the denitrification tank (4) is communicated with a nitrification tank (5); and the nitrification tank (5) is connected with an ultrafiltration apparatus (6), and the ultrafiltration apparatus (6) is connected with a nanofiltration device (7). The method and the device achieve COD degradation of high-concentration wastewater so that the COD of high-concentration COD of 50,000 reaches about 50 after treatment and reaches the standard of industrial reuse water, thus the method and the device achieve zero discharge of the percolate, initiate a new attempt to treat high-concentration percolate, and fill up the domestic blank.

The invention discloses a method for treating coking wastewater, which belongs to the field of wastewater treatment. The method comprises the following steps that: wastewater of a coking plant enters a regulating reservoir for the adjustment of water quality and water amount, and orderly enters a hydrolytic tank, an anaerobic tank, a preaeration tank, a preliminary sedimentation tank, an aerobic tank, a secondary sedimentation tank and a coagulation reaction tank for treatment, wherein the hydrolytic tank and the preaeration tank are filled with a bio-cord filler; the sludge of the preliminary sedimentation tank refluxes into the hydrolytic tank and the anaerobic tank respectively; a clarifying solution of the secondary sedimentation tank refluxes into the anaerobic tank; and the aerobic tank adopts a moving bed bio-film reactor. The bio-cord filler adopted in the invention has short film formation time and high biomass, does not need repeated washing, and has strong shock resistance; and the moving bed bio-film reactor can fix a large amount of nitrobacteria with long generation time, and has no the problem of blocking. The method can remove high-concentration ammonia nitrogen and organic substances in the coking wastewater, and the COD and the ammonia nitrogen of treated effluent can synchronously achieve the primary standard of the national integrated wastewater discharge standard (GB9878-1996).

The invention discloses a preenrichment-three segment suspension roasting-magnetic separation treatment method of complex refractory iron ores, and belongs to the technical field of mineral processing. The method comprises the following steps: 1, levigating the complex refractory iron ores, carrying out weak magnetic separation, and carrying out strong magnetic separation on mine tailings; 2, putting concentrate obtained after strong magnetic separation in a suspension roasting furnace, and heating to 450-800DEG C in a suspension state in order to carry out pre-oxidation roasting; 3, introducing nitrogen to displace air, and introducing a reducing gas to carry out reduction in a suspension loose state; 4, introducing air when the temperature decreases to 250-400DEG C in order to oxidize, taking out the obtained material when the temperature decreases to below 100DEG C, and carrying out ore milling; and 5, carrying out third segment magnetic separation, and mixing concentrate obtained after three segment magnetic separation with concrete obtained after the weak magnetic separation to obtain finial concentrate. The method has the advantages of simple process, improvement of the recovery rate of the complex refractory iron ores, strong adaptability, safe and reliable process, uniform and stable product quality, energy saving and consumption reduction.

The invention discloses a three-dimensional electrode bio-membrane system used for processing high-ammonium-nitrogen wastewater with a low carbon-nitrogen ratio. According to the invention, a barrier membrane concentric with a reactor body is arranged in the reactor body; with the barrier membrane, the reactor body is separated into a round anode zone and an annular cathode zone; a microbe carrier filling material is filled in the anode zone, and a positive electrode is arranged at the center of the anode zone; a negative electrode is arranged in the cathode zone, and conductive particles arefilled in the cathode zone, wherein the conductive particles serve as a third electrode; the negative electrode and the conductive particles both serve as microbe carriers; a water inlet pipe is arranged on the bottom of the anode zone, and a water outlet pipe is arranged in the cathode zone; the water outlet pipe is arranged on an outer wall on the upper end of the reactor body. According to theinvention, in a same electrode bio-membrane reactor, an eligible environment for the microbes is created with an electrochemical effect; an electron acceptor and an electron donor are respectively provided, such that nitrification and denitrification actions are respectively carried out, and ammonium-nitrogen wastewater can be effectively treated. The system is advantaged in low energy consumption, high efficiency, simple structure, and easy operation.

A high-temperature and aerobic composting method for solid wastes which adopts a vertical ventilation device relates to a high-temperature and aerobic composting method for the solid wastes. The composting method aims at solving the problems that in the aerobic fermentation process, the conventional bottom ventilation method causes obvious uneven fermentation at the upper part and the lower part of a stacking body in a fermentation device, thus quality stability and uniformity of the fermented product are affected. In the composting method, middle air distribution pipes are fixed in a fermentation tank arranged at the lower side of an inverted ventilating slot; both the bottom part and the middle part of the fermentation tank adopt intermittent ventilation type, the ventilation time is 5-30 minutes, intermittent time is 15-120 minutes and ventilation rate is 0.03-2m<3>/(min m<3> mixing materials). The composting method increases the contact area between air and materials; air direction forms a reverse rotational flow, which increases residence time of fresh air in the fermentation device, thus improving the mass transfer efficiency, and the operational cycle of a single fermentation is shortened by over 1/4.

The invention discloses an electrochemical reactor for processing nitrogenous organic wastewater, and an application and a processing method thereof, and belongs to the field of processing nitrogenous organic wastewater. The device comprises a reaction container, a power supply, a gas outlet pipe, a water outlet pipe, a water outlet pipe valve and a water inlet system, and further comprises a packing material, a negative plate and a positive plate, wherein the packing material is formed by mixing active carbon and magnet particles; the negative plate is connected with the negative electrode of the power supply; the negative plate is a silicon dioxide plate loaded copper-palladium coating electrode, and the coating material consists of Pd and Cu at a mass ratio of 6: 1; and the positive plate is a digital subtraction angiography (DSA) oxide coating electrode Ti/IrO2-PtO2. The reactor is a batch-type operation three-dimensional electrode reactor which adopts a mixture of active carbon particles and magnet particles with similar diameter as the packing material, and has the functions of efficiently removing nitrate nitrogen, ammonia nitrogen and COD (chemical oxygen demand), and is low in energy consumption; and the reactor is capable of achieving a purpose of removing nitrogen and COD in the nitrogenous organic wastewater.

The invention provides a method for preparing a macroporous reticulated polyvinyl alcohol spherical vector. The method comprises the following steps: firstly, polyvinyl alcohol, calcium carbonate, sodium alginate and water are mixed in a certain mass proportion, and stirring is performed for full dissolution of the polyvinyl alcohol and uniform mixture, and then white PVA sol is obtained; secondly, the sol obtained is added into saturated boric acid solution containing 3 percent of calcium chloride by a peristaltic pump, and PVA gel beads are formed, cleaned by water and then placed into diluted hydrochloric acid solution for dipping until no air bubble is generated; thirdly, a spherical vector is thrown into glutaral pentanedial water solution and adjusted into acidity so as to generate crosslinking reaction to form a more stable crosslinking structure; and fourthly, the spherical vector is dipped into water and cleaned into neutrality, and then the white macroporous reticulated PVA spherical vector with elasticity is obtained. The macroporous reticulated polyvinyl alcohol vector prepared by the method has stable macroporous reticulated structure and good hydrophilicity, physical and chemical stability and anti-biological degradability, is suitable for immobilized enzymes and microorganisms so as to form a plurality of bed-shaped bioreactors, and is used in the modern bioengineering field such as sewage treatment and so on.

The invention discloses a method for preparing polymethoxy dimethyl ether through reaction and rectification of a fixed bed. The method comprises the following steps: (1) preheating trioxymethylene, uniformly mixing the preheated trioxymethylene and methylal, and feeding the trioxymethylene and the methylal which are uniformly mixed into a fixed bed reactor for an etherification reaction; (2) feeding materials after the etherification reaction into a reaction rectifying tower for the reaction and the rectification, and discharging PODE2-8 from the tower bottom of the reaction rectifying tower; (3) transporting the PODE2-8 to a dewatering tower loaded with a 3A molecular sieve for dehydration, then transporting the dehydrated PODE2-8 into a first refining tower, transporting materials which are discharged from the tower bottom of the first refining tower into a second refining tower, discharging PODE3-5 from the tower top of the second refining tower, and discharging PODE6-8 from the tower bottom of the second refining tower. When the method disclosed by the invention is used for preparing the PODE3-8, the yield of the polymethoxy dimethyl ether can reach 95%, wherein the products of the PODE3-8 can reach 80%-95%, and after refinement, the PODE3-5 of which the quality purity reaches 99.9% can be obtained.

The invention relates to an active composite suspended filler, which is applied to the technology of biochemical treatment of organic wastewater, and discloses a porous support filler formed by a carrier basic materials and functional assistant materials. The porous support filler is in a through-hole spheroidal body or a through-hole cylindrical body, and one layer of porous active powder material layer is bonded on an outer surface of the through-hole spheroidal body or the through-hole cylindrical body. The active composite suspended filler is an inorganic suspended filler, has an uneven surface and roughness height; and pores with different sizes are distributed on the filler and are shaped like a honeycomb. The filler not only has high adsorption performance on harmful substances and dissolved oxygen, but also can form different dissolving intensity, is beneficial to improving processing efficiency for removing COD (Chemical Oxygen Demand) and ammonia nitrogen, and will be a novel high-efficient filler.

The invention relates to a nano carbon-doped porous fiber single electrode, a membrane electrode and a preparation method. According to the nano carbon-doped porous fiber single electrode, a semi-ordered porous nano fiber thin film is deposited at one side of a gas diffusion layer material; and a layer of metal nanoparticles with catalytic activity is evenly deposited on the nanofiber surface of the semi-ordered porous nano fiber thin film to form the nano carbon-doped porous fiber single electrode, wherein the semi-ordered porous nano fiber thin film is formed by a co-spun high-molecular polymer nano charged superfine fiber attached with a nano carbon material on the surface, and comprises a co-spun high-molecular polymer doped with the nano carbon material as the component. According to the nano carbon-doped porous fiber single electrode, the semi-ordered porous nano fiber layer is formed by the nano carbon material and a high-molecular polymer solution through electrostatic spinning and cospinning for the first time; a catalyst is sprayed on the porous nano fiber layer; and a mico-pore layer and a catalyst layer are combined into one, so that the properties of a prepared single battery are greatly improved; and the lifetime is greatly prolonged.

The invention, belonging to the technical field of catalyst and its application, particularly relates to an ultrafine molecular sieve structured catalytic material based on a porous silicon carbide carrier and a preparation method thereof. The material comprises ultrafine molecular sieve crystals as active elements and has a hierarchically porous structure, and the whole ultrafine molecular sieve coating has catalytic activity. The method is characterized by coating a colloidal molecular sieve precursor on the surface of a modified foam silicon carbide carrier, converting the molecular sieve precursor into ultrafine molecular sieve crystals by vapor phase treatment to realize the firm combination between the coating and the carrier. According to the invention, by controlling the synthesis conditions of the colloidal molecular sieve precursor and the method of adding a pore forming agent, the size of the molecular sieve crystals, silica-alumina ratio and intercrystalline porosity can be controlled; a pore structure and the type of the molecular sieve can be designed according to the geometrical structure of a target product; and the capacity of accommodating carbon is raised, the mass transfer capability of the catalyst is reinforced, and the life of catalyst is prolonged while keeping the high activity of the ultrafine molecular sieve and high target product selectivity.