52results about How to "No reflow required" patented technology

The invention discloses a method for treating coking wastewater, which belongs to the field of wastewater treatment. The method comprises the following steps that: wastewater of a coking plant enters a regulating reservoir for the adjustment of water quality and water amount, and orderly enters a hydrolytic tank, an anaerobic tank, a preaeration tank, a preliminary sedimentation tank, an aerobic tank, a secondary sedimentation tank and a coagulation reaction tank for treatment, wherein the hydrolytic tank and the preaeration tank are filled with a bio-cord filler; the sludge of the preliminary sedimentation tank refluxes into the hydrolytic tank and the anaerobic tank respectively; a clarifying solution of the secondary sedimentation tank refluxes into the anaerobic tank; and the aerobic tank adopts a moving bed bio-film reactor. The bio-cord filler adopted in the invention has short film formation time and high biomass, does not need repeated washing, and has strong shock resistance; and the moving bed bio-film reactor can fix a large amount of nitrobacteria with long generation time, and has no the problem of blocking. The method can remove high-concentration ammonia nitrogen and organic substances in the coking wastewater, and the COD and the ammonia nitrogen of treated effluent can synchronously achieve the primary standard of the national integrated wastewater discharge standard (GB9878-1996).

The inulin extracting process includes the following steps: washing, crushing, water leaching, filtering in a primary filter, a tubular filter and an ultrafiltering and decolorizing machine successively, nanometer filtering to concentrate, decolorizing with active carbon, secondary filtering, electrodialysis, evaporating concentration and spray drying. The process has high inulin product purity and yield, short extracting period, simple operation and low production cost.

The invention discloses a granular sludge-based integrated anaerobic ammonium oxidation denitrification reactor and a method, relates to a granular sludge-based shortcut nitrification-anaerobic ammonium oxidation integrated denitrification reactor and a starting method, belongs to the technical field of biological sewage treatment and aims to solve the technical problems that nitrite nitrogen in a mixed solution reacts with ammonia nitrogen to generate nitrogen during a precipitation stage, the nitrogen is combined with floc sludge, and upward floating of the floc sludge can be caused, so that the effluent quality is deteriorated. The granular sludge-based integrated anaerobic ammonium oxidation denitrification reactor comprises an aeration pump, a flow meter, an aeration disk, a blow-down pipe, a water inlet pipe, sampling openings, a water bath sleeve, a reaction pipe, an online monitor, a three-phase separator, an annular water outlet tank, a sawtooth-shaped end surface, a water outlet pipe, a gas outlet pipe, a water sealed exhaust pipe, a water inlet barrel and a water inlet pump. The method comprises the following steps: 1, system booting; 2, program running; 3, stable running of the reactor. By adopting the granular sludge-based integrated anaerobic ammonium oxidation denitrification reactor disclosed by the invention, a removal rate of total nitrogen is higher than 85 percent.

The invention discloses a water purifying device and system of suspension sway-typed biochemical reactor, which comprises the following parts: water body, purifying device, water body fender system, technique flow path, pipe system, aerating system and program control system, wherein at least one purifying element is set in the water purifying device, which adopts MBR membrane reactor; the suspension system of the purifying element is set in the water purifying device, which contains rigid frame, rotary mechanism and locking piece; the water barrier wall divides the water body fender system into water body S1, S2 and S3...; the water body S2 and S3... is seal loop-shaped water body; the device assembles the purifying element in the water body S1 through the suspension unit of the purifying element, which combines the MBR membrane reactor with solid-liquid separator and oxidation ditch technique together; a pusher is set in the loop-shaped water body, which flows the water body and sways the purifying element.

A sewage treating apparatus with denitrifying function is composed of a pool body and a covering plate with several inoculating holes and exhausting hole. Said pool with water inlet and outlet is divided into an anaerobic decarbonizing region consisting of isolated flow-up chambers containing fixed filler and flow-down chamber, an aerobic nitrifying region consisting of the aerating chamber with internal aerating unit communicated with external air compressor and the precipitating chamber, and an anaerobic denitrifying region consisting several flow-up chambers containing fixed filler and several flow-down chambers.

The invention discloses a synthetic method of 3-chlorine-2-hydrazinopyridine. The synthetic method is characterized by comprising the following steps: uniformly mixing 2-fluorine-3-chloropyridine and hydrazine hydrate, adding an alcohol solvent, reacting for 3-5 hours at a room temperature, drying the solvent, and carrying out rotary evaporation, thus obtaining the 3-chlorine-2-hydrazinopyridine. The synthetic method of the 3-chlorine-2-hydrazinopyridine has the advantages that the operation process is simple, the high-yield high-quality product can be obtained without heating flux, the product yield can reach 99.53%, and the product purity can reach 99.95%.

The invention especially relates to a biological treatment system for fixed-bed gasification waste water, which belongs to the field of water treatment technology. The system comprises a water inlet pipe, a water outlet pipe, a reinforced dephenolization apparatus, a reinforced denitrification apparatus, an intermittent fluidization biofiltration apparatus, an aeration apparatus and an alkali addition apparatus, wherein the reinforced dephenolization apparatus, the reinforced denitrification apparatus and the intermittent fluidization biofiltration apparatus are successively connected and separately connected with the aeration apparatus and the alkali addition apparatus; the reinforced dephenolization apparatus is internally provided with a plurality of carriers A used for immobilizing dephenolization bacteria; the reinforced denitrification apparatus is internally provided with a packing layer formed by a plurality of carriers B, and carriers C and carriers D are included in the carriers B; and the intermittent fluidization biofiltration apparatus is internally provided with a porous lifter plate and a packing layer formed by the carriers D. The system integrates the advantages of immobilized microorganism technology and biological reinforcement technology and has improved integral denitrification and dephenolization effect through optimized combination of three functional zones, i.e., a reinforced dephenolization zone, a reinforced denitrification zond and an intermittent fluidization biofiltration zone.

The invention relates to an accurate and simple transformer oil acid value detection method. The method comprises the steps of: (1) oil sample detection, (2) blank solvent detection, and (3) calculation. In the step (1), 3.0-4.0g of transformer oil requiring detection is accurately weighed; an extractant isopropyl alcohol is added to the sample; the mixture is well mixed by shaking; an alkali blue 6B indicating agent is dropped into the mixture, such that a mixed solution is obtained; 0.05mol/L of a KOH ethanol solution is used for titration, until the color of the solution turns to light red. In the step (2), the extractant with a volume same as that used in the step (1) is weighed; the alkali blue 6B indicating agent is dropped into the extractant, such that a mixed solution is obtained; 0.05mol/L of a KOH ethanol solution is used for titration, until the color of the solution turns to light red, such that the titration reaches an end. In the step (3), the calculation is carried out according to the formula of: c(mgKOH/g)=(V-V0)*c(KOH)*M(KOH)/m. The method provided by the invention is simple and fast. With the method, heating and refluxing are not needed, such that working efficiency is improved. Twice titration is changed into once titration, such that the operation processes are simplified, and operation errors of the system are reduced.

The invention provides a sewage treatment method using A/O biological contact oxidation process belonging to environmental engineering technology field, which solves the problems that in the prior art the adaptability of water quality is not strong, the impact resistance perfermance is weak, the effluent water quality is unstable and sludge bulks or the like. The sewage treatment method using A/O biological contact oxidation process comprises the following steps: A. pretreatment; B. hydrolytic treatment; C. aeration treatment; D. deposition and disinfection, and has advantages of high volume loading, rapid rate of biodegradation and low cost.

The invention discloses a method for biochemically treating coking wastewater. The method comprises the following steps of: pretreating coking wastewater; feeding pretreated coking wastewater into an anaerobic tank for anaerobic treatment; and feeding the treated wastewater into an aerobic three-phase fluidized bed for anaerobic treatment, wherein the pH of the anaerobic tank is between 6.0 and 7.5; the hydraulic retention time is between 8 and 30 hours; the pH of the aerobic three-phase fluidized bed is between 7.5 and 8.5; the hydraulic retention time is between 8 and 24 hours; the dissolved oxygen content is between 2 and 4mg/L; and effluent COD, ammonia nitrogen, volatile phenol and cyanide meet the steel industrial water pollutant effluent standard (GB13456-92) and the primary standard of the integrated wastewater effluent standard (GB 8978-1996). The method can effectively solve the problems of bad treatment effect, large amount of sludge, complicated process, high cost and the like caused by biochemically treating the coking wastewater by ammonia nitrogen and has the advantages of simple operation, low cost, economic feasibility, contribution to popularization, and capability of effectively improving and solving the problem of environment pollution caused by the coking wastewater.

The invention discloses UV (Ultraviolet) curable polyester as well as a preparation method and application of the UV curable polyester. The preparation method of the UV curable polyester comprises the following steps: 1) mixing 1 part of triglycidyl ether and 3 to 4 parts of an acrylic monomer into a reaction kettle according to a mole fraction; adding a quaternary ammonium salt catalyst, a polymerization inhibitor and an organic solvent and reacting at 105 DEG C to 125 DEG C until the acid value is less than 10mgKOH/g; 2) adding acid anhydride, a polymerization inhibitor and p-toluenesulfonic acid into a matrix prepared by the step 1), and reacting at 105 DEG C to 130 DEG C for 2h to 4h; adding an epoxy compound which is 0.9 to 1.2 times of the mole fraction of the acid anhydride and adding the quaternary ammonium salt catalyst and the organic solvent to react until the acid value is less than 10mgKOH/g; decompressing and distilling to remove the solvent, and cooling and discharging a material, wherein the solid content of the resin reaches 100 percent or more and the viscosity is 3000mPa.s to 30000mPa.s. UV curable paint prepared by the polyester has excellent coating film performance and relatively low cost.

The invention discloses an inclined plate settler, which comprises a water inlet and a water inlet tank, the water inlet is arranged at the lower part of the right side of the water inlet tank, a water purification tank is arranged on the left side of the water inlet tank, and the lower part of the water purification tank is arranged There is a water distribution pipe with one end connected to the water inlet tank. The upper part of the water distribution pipe is provided with a sedimentation device connected to the two side walls of the water purification tank. The bottom of the water purification tank is connected with the sedimentation tank. The bottom of the sedimentation tank is provided with Mud outlet. In the present invention, a slant plate with an inclination angle of 60 degrees is installed above the sludge suspension layer, so that the suspended solids in the raw water slide back to the sludge suspension layer by gravity, then sink into the sludge collection bucket, and are discharged into the sludge through the sludge discharge pipe. The pool is treated separately or comprehensively applied. The whole machine has a simple structure, no wearing parts, durable, less maintenance, stable operation, easy operation, high treatment efficiency, and no need for sludge return.

The invention discloses a method of the solvent-free synthesis of cinchona alkaloid derivatives by adopting microwave radiation with the catalysis of a phase transfer catalyst. According to the method of the invention, 1, 4-dichloro-2, 3-naphthyridine, 3, 6-dichloropyridazine, 4, 6-dichloropyrimidines, 2, 5-diphenyl-4, 6-dichloropyrimidines or phthalic acid can react with quinine, hydroquinine, quinidine, dihydro quinidine, cinchonine or cinchonidine according to a mol ratio of 1:3 to 3:1 to obtain the cinchona alkaloid derivatives. Under the action of microwave, the synthetic process of the cinchona alkaloid derivatives can become simple and safe in operation, short in reaction time, and mild in reaction condition; more particularly, toxic organic solvents such as methylbenzene and DMF with a high boiling point, etc. are not adopted in the course of the reaction, thus being in line with the megatrend of green chemistry, furthermore, monosubstituted products and disubstituted products can be obtained with high yield by the control of reaction time and power.

The invention discloses a synthetic method of repaglinide, comprising the steps of dissolving N-acetyl glutamate of (S)-3-methyl-1-[2-(1-piperidyl)phenyl] butyl amine into dichloromethane, stirring, cooling, alkalifying, extracting and drying to obtain (S)-3-methyl-1-[2-(1-piperidyl)phenyl] butyl amine dichloromethane solution; cooling the solution, adding 3-ethyoxyl-4-carbethoxy phenylacetic acid, HOBT (N-hydroxybenzotriazole), DIEA (N,N-diisopropyl ethylamine) and EDC.HCl (1-ethyl-3-(3-dimethyllaminopropyl)carbodiimide hydrochloride) in turn and reacting; washing, drying and distilling to obtain repaglinide ethyl ester; adding ethanol, dropping alkali liquid, heating and reacting; and acidizing, growing crystals and performing suction filtration to obtain a product. The synthetic method has the advantages that EDC.HC1 is used as an acylation reagent, so that the reaction by-product urea is easy to elute; due to combination with HOBT, the condensation yield can be improved; the condensation condition is mild; the reaction time is short; the yield is 96%; the purity can reach more than 98%; recrystallization is not needed and the next hydrolytic reaction can be preformed directly; and the process is simple, so that the synthetic method is suitable for commercial production.

The invention discloses a continuous flow SBR domestic sewage treatment method and a device. The device comprises a reaction container, partition plates, a drainage mechanism, a water inlet pipe, an aeration device and a control mechanism; the interior of the reaction container is divided into at least four reaction areas by the partition plates, and the four reaction areas comprise a first reaction area, a second reaction area, a third reaction area and a fourth reaction area; the bottoms of the reaction areas are communicated with each other, the water inlet pipe is longitudinally mounted inthe middle in the reaction container, and the lower end of the water inlet pipe is communicated with the lower ends of the reaction areas. The method comprises the following steps: water introductionstage, aeration stage, precipitation stage, continuous water introduction stage, and continuous water discharge stage. According to the method, the traditional SBR reaction container is subjected tospace division, the continuous flow process design is achieved through the water level pressure difference, the water inlet pipe is arranged in the middle of the reaction container for unified water inflow, the automatic control procedure is simplified, meanwhile, an anoxic stirring link is omitted, and the treatment period is shortened on the premise that it is guaranteed that effluent reaches the fifth type of water on the earth surface.

The invention discloses the use of CaH2 in synthesizing cinchona alkaloid ligand, wherein the ligand has a structure disclosed in the specification. CaH2 can be used as the acid binder in synthesizing cinchona alkaloid ligand. monosubstituted product or disubstituted product including hydroquinine, Quinidine, Dihydroquinidine and their derivatives.

A reaction system for removal of nitrogen and phosphorus in domestic sewage by use of microalgae is disclosed, the domestic sewage contains many organic pollutants, detergents, pathogenic microorganism and parasitic ovum, and the domestic sewage is a main part of urban sewage. The reaction system for removal of the nitrogen and phosphorus in the domestic sewage by use of the microalgae comprises a high rate algal pond (1), the high rate algal pond (1) is connected with one end of a grille tank (3) through a sewage pipeline (2), a water collection tank (4) is connected with the grille tank (3) through a sewage pipeline, the water collection tank (4) is connected with one end of a primary settling tank (5) through a sewage pipeline, the primary settling tank (5) is connected with one end of a biochemical pool (6) through a sewage pipeline, the other end of the biochemical pool is connected with a secondary settling tank (7) by a sewage pipeline, the secondary settling tank (7) is connected with a MBR membrane pool (8) through a sewage pipeline, the MBR membrane pool (8) is connected with a disinfection pool (9) through a sewage pipeline, and the disinfection pool (9) is connected with a drainage well (10) through a sewage pipeline. The reaction system is applied to sewage treatment.

The invention discloses a circulating biological selection reactor for livestock and poultry culture sewage treatment. The reactor is mainly composed of a gas outlet, a reactor body, a water inlet, a sewage collecting pool and a water outlet, livestock and poultry culture sewage enters an anaerobic zone 1 through the water inlet and undergoes anaerobic denitrification, sludge in an incremental portion directly falls into the sewage collecting pool, anaerobic sewage overflows an overflow external plate, overflowed sewage is directly introduced to a biological selection zone 1 through a pipeline and undergoes biological adaptation, obtained sewage enters a biological aerobic zone 1 and undergoes selective biological aeration treatment, a nitration solution directly enters an anaerobic zone 2 and undergoes denitrification, cycle treatment is carried out, a gas is discharged from the gas outlet, sewage obtained after biological aerobic zone 3 treatment goes through a water fender, obtained water is drained from the water outlet, and sludge in the sludge collecting pool is discharged through a sludge pump. The reactor has the advantages of no refluxing of sludge or the nitration solution, realization of phosphorus removal through repeated anaerobic and aerobic treatment of sludge, direct falling of incremental and residual sludge to bottom without sludge discharge, and realization of thorough separation of three phases positioned in different directions.