A non-aqueous electrolyte to be used in a Li-ion battery includes a lithium salt, a cyclic carbonate, a linear carbonate and an alkyl fluorinated phosphate, of the following general formula
wherein R1, R2 and R3, independently, are selected from the group consisting of straight and branched alkyl groups having 1-5 carbon atoms, and at least one of said alkyl groups is fluorinated, with the locations of said fluorination being at least β-positioned away from the phosphorous of said phosphate, such that said alkyl phosphate has a F/H ratio of at least 0.25, and said electrolyte solution is non-flammable.