429results about "Gel preparation" patented technology

The invention provides a solar interface evaporator based on amphoteric polyelectrolyte photo-thermal hydrogel, a preparation method and application, and belongs to the field of solar interface evaporation. The solar interface evaporator with a three-dimensional multi-surface evaporation structure is prepared by combining the polyelectrolyte resisting effect of the amphoteric polyelectrolyte photo-thermal hydrogel and the porous capillary effect of the sponge, and has the characteristics of high light absorptivity, good water absorption effect, excellent antibacterial property, mechanical property, salt resistance, evaporation property and the like; particularly, compared with a traditional hydrogel-based solar interface evaporator, the water delivery capacity and the salt resistance in high-concentration saline water are greatly improved through the application of the autonomously designed zwitterionic hydrogel, water molecules in the saline water are activated through the cooperation of salt-resistant ionized water, the evaporation enthalpy is reduced, and the evaporation efficiency is improved. And a great positive effect is achieved on improvement of the evaporation rate. The evaporator is easy to prepare and excellent in multi-dimensional performance, and a new way and thought are provided for application to seawater desalination and wastewater treatment.

The invention discloses a bionic bimodal hydrogel-based triboelectricity-super-capacitance sensor and a preparation method of the bionic bimodal hydrogel-based triboelectricity-super-capacitance sensor. A hydrogel-based sensor high-charge sensitive layer is used as a triboelectric layer, a flexible hydrogel-based high-conductivity hydrogel electrode layer is used as an upper electrode layer, a hydrogel-based sensor elastic spacing layer, a hydrogel-based sensor dielectric layer is used as an ion conductive layer, and the flexible hydrogel-based high-conductivity hydrogel electrode layer is used as a lower electrode layer. An integrated multi-layer device structure is stacked from top to bottom; a silver wire is led out from each of the two layers of flexible hydrogel-based high-conductivity hydrogel electrodes, and the bionic bimodal hydrogel-based triboelectricity-super-capacitance sensor is obtained. The sensor integrates two sensing mechanisms of triboelectricity and a super capacitor, can detect dynamic and static pressure at the same time, has the advantages of high sensitivity, wide detection range, quick response and the like, and is expected to be widely applied to the fields of human-computer interaction, robot sensing and the like.

The invention belongs to the technical field of sewage treatment, and discloses a biodegradable-photocatalytic composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a photocatalyst, sodium alginate and water to obtain gel containing the photocatalyst, then adding a photosynthetic bacteria concentrated solution, then adsorbing photosynthetic bacteria and the photocatalyst by using a carrier, and finally immobilizing in a calcium chloride solution to obtain the composite material. Photosynthetic bacteria are selected as microorganisms, and the method has the advantages of being flexible in metabolism mode, high in antibiotic tolerance, high in breeding speed, free of sludge treatment and the like. The photocatalyst and the photosynthetic bacteria are loaded on the polyurethane sponge, so that the photosynthetic bacteria are easily separated from water while being protected. The photocatalyst outside the carrier generates high-activity substances, and refractory antibiotics are converted into biodegradable intermediates. And a generated intermediate product is decomposed by microorganisms in the carrier, so that efficient degradation and mineralization of antibiotics in the sewage are realized.

The invention relates to the technical field of organic supramolecular chemical materials, in particular to an octyloxy-modified imine gelator, bi-component gel of the octyloxy-modified imine gelator and a preparation method and application of the octyloxy-modified imine gelator. The gelator is a symmetric o-octyloxy modified p-phenylenedialdehyde-maleonitrile imine gelator, and has an obvious aggregation-induced emission property; the gelator and the cholesteryl half-ester gel can form double-component organic gel without fluorescence emission in an organic solvent; the fluorescence-emission-free double-component gel formed in tert-butyl alcohol is red fluorescence-emission gel when meeting water, and is converted into blue fluorescence-emission gel when meeting NaClO, so that water and NaClO can be rapidly and intuitively detected; the gelator has fluorescence enhancement and blue shift after encountering NaClO in a solution state, has fluorescence'off-on 'detection on NaClO, has fluorescence emission intensity reduced after Hg < 2 + > is added in the solution state, and has fluorescence'on-off' detection performance on Hg < 2 + >.

The invention relates to the technical field of organic material detection, in particular to an imine molecular sensor with a five-detection function, two-component gel as well as a preparation method and application of the imine molecular sensor. The imine molecular sensor has three signal responses of fluorescence on-off, ultraviolet absorption and color change to Fe < 3 + >, Co < 2 + > and Ni < 2 + > in a solution state, and has ultraviolet absorption and fluorescence on-off dual-detection performance to acid and alkali changes; the imine molecular sensor and cholesteryl half ester can form two-component gel through a heating-low-temperature ultrasonic cooling method; after Fe < 3 + >, Co < 2 + >, Ni < 2 + >, NaOH and HCl are respectively added, the orange of the gel becomes milky white, reddish brown, transparent red, milky white and milky white under sunlight, and the fluorescence of the orange of the gel disappears under an ultraviolet lamp, so that the rapid and sensitive detection of Fe < 3 + >, Co < 2 + >, Ni < 2 + >, acid and alkali under two states of the imine molecular solution and the gel is realized. The imine molecular sensor provided by the invention has the advantages of mild synthesis conditions, simple preparation and the like, and creates favorable conditions for popularization and application of the imine molecular sensor.

The preparation method comprises the following steps: mixing walnut oil and idesia oil according to a mass ratio of (85-90): (10-15), stirring and heating to 68-72 DEG C under the condition of a rotating speed of 55-70 rpm, adding a gel compounded by edible wax and polyglycerol fatty acid ester according to a mass ratio of (4-6): 1, continuing to stir until complete dissolution, adding an emulsifying agent, and uniformly stirring to obtain the beta '-crystal-form woody oil-based oleogel, so as to obtain the beta'-crystal-form woody oil-based oleogel, namely the beta '-crystal-form woody oil-based oleogel. The preparation method comprises the following steps: preparing a liquid grease gel solution, directly putting the liquid grease gel solution under the condition of-10 to-40 DEG C for quick freezing, then stirring for 3-6 minutes under the condition of the rotating speed of 150-250 rpm, and standing for 5-6 days under the environment of 20-25 DEG C to prepare the woody oil-based grease gel. The grease gel prepared by the method disclosed by the invention contains a stable beta'crystal form, is high in oil holding rate and proper in hardness, has relatively good oxidation stability, and can be applied to baking instead of animal butter or hydrogenated vegetable oil.

The invention relates to MXene-based ammonium glycyrrhizinate / konjac glucomannan / borax self-repairing hydrogel and a preparation method thereof, and belongs to the technical field of gel. The preparation method comprises the following steps: firstly, etching Ti3AlC2 by adopting concentrated hydrochloric acid and lithium fluoride, and carrying out multiple times of centrifugal washing, ultrasonic treatment and vacuum drying to obtain an MXene nanosheet; the preparation method comprises the following steps: preparing ammonium glycyrrhizinate and konjac glucomannan into hydrosol, and dispersing MXene nanosheets into the hydrosol to obtain dispersed MXene nanosheet sol; and adding a borax aqueous solution into the dispersed MXene nanosheet sol, stirring, carrying out ultrasonic dispersion, heating until boiling is started, stopping heating, and carrying out cross-linking in a room temperature environment to obtain the MXene-based self-repairing hydrogel. Due to existence of multiple reversible hydrogen bonds and multiple reversible boron-oxygen bonds in polymer chain segments and among the chain segments in the hydrogel, the acting force among molecular chain segments in the hydrogel is enhanced, the mechanical property and the self-repairing property of the hydrogel are remarkably improved, and meanwhile, the conductivity, the electromagnetic shielding property, the oxidation resistance and the antibacterial property of the hydrogel are improved; good application prospects are realized.

The invention discloses a preparation method of a salt-resistant double-layer photo-thermal aerogel evaporator. The preparation method comprises the following steps: S1, cutting and cleaning foamed nickel, and then carrying out vacuum drying; s2, preparing Cu2O / NF (nickel nitrate); s3, preparing ppy-Cu2O / NF (nickel fluoride); s4, preparing hydrogel; and S5, flatly placing a sample ppy-Cu2O / NF on the top surface of the hydrogel, continuing to stand for gelling, enabling the photo-thermal layer and the bottom layer hydrogel to be fully combined, pre-freezing, transferring into a freeze dryer, and freeze-drying to finally obtain the salt-tolerant double-layer photo-thermal aerogel evaporator, namely the lightweight porous aerogel material ppy-Cu2O / NF / FCP with the double-layer structure. The device has the advantages that the high-level evaporation rate and efficient energy conversion are achieved, and efficient photo-thermal conversion and heat management are achieved through the double-layer structure design.

The invention discloses a method for removing fishy smell of minced fillet and improving gel characteristics based on an electric field effect and application of the method, and relates to the technical field of production of minced fillet products. Comprising the following steps: treating surimi rinsing wastewater by utilizing a low-voltage direct-current electric field to obtain rinsing recovery liquid; rinsing the fresh surimi by using the rinsing recovery liquid, and introducing nitrogen microbubbles in the rinsing process to make full contact with the surimi; and rinsing with clear water, and dehydrating to finish the treatment. According to the method disclosed by the invention, the rinsing recovery liquid treated by the electric field is selected and has a synergistic effect with the introduced nitrogen microbubbles, so that the myofibrillar protein content and the moisture content of the rinsed minced fillet are relatively high, and the fat content and fishy smell substances are obviously reduced; the gel strength of the final gel product reaches 493.03 g.cm and meets the 3A-grade surimi standard (the gel strength is greater than or equal to 400 g.cm), and the quality, color and flavor of the surimi gel are effectively improved; the method is simple to operate, high in efficiency and suitable for industrial production.

The invention discloses a preparation method of DNA (Deoxyribonucleic Acid) hydrogel with programmable mechanical strength. By regulating and controlling the molar ratio of the catalytic initiating chains to the total amount of the DNA monomer building blocks, multiple hydrogels which are equivalent in mass concentration and have different mechanical strengths are constructed. According to the method, a strategy similar to catalytic assembly is adopted, the feeding molar ratio of a catalytic initiating chain to a DNA monomer building block is creatively adjusted, the proportion of cross-linking reactions at different levels is regulated and controlled, then the DNA hydrogel with different mechanical strengths is synthesized under the isothermal condition, and the storage modulus range is about 200-2000 Pa. In addition, the change of the mechanical strength is independent of the total concentration of the matrix (DNA) of the hydrogel, the DNA sequence, the stress relaxation rate and other properties. The method provides a novel convenient method for constructing DNA hydrogels with different mechanical strengths, and possibly provides a novel tool for researching the specific influence of mechanical properties of materials on cell / tissue behaviors.

The invention belongs to the technical field of water purification materials, and particularly relates to a multifunctional water purification gel material and a preparation method thereof. The composite material consists of an outer-layer film, a middle-layer framework and an inner-layer carbon core, the outer-layer film is prepared from the following raw materials: sodium alginate, carboxymethyl starch, NaCl and Tween-20; the middle-layer framework is prepared from the following raw materials: chitosan, modified sodium bentonite and Fe-P nano powder; the inner-layer carbon core is prepared from the following raw materials: rice hull biochar, nano CaCO3, FeCl3. 6H2O and FeSO4. 7H2O. Efficient water purification is achieved through a three-layer synergistic structure, and the outer layer Ca < 2 + > cross-linked sodium alginate / carboxymethyl starch porous membrane intercepts particles and buffers metal ions; the middle layer is integrated with chitosan to chelate heavy metals, CTAB-bentonite electrostatically adsorbs anions and Fe-P nanoparticles to precipitate phosphate / arsenate; and the biochar-Fe3O4 complex on the inner layer provides deep adsorption and catalytic oxidation functions.

A polyvinyl alcohol-cellulose nanocrystal composite hydrogel interface evaporator, and a preparation method therefor and the use thereof. The preparation method for the composite hydrogel interface evaporator comprises the following steps: adding a cellulose nanomicrocrystal, polyvinyl alcohol and an acid liquor to water, mixing same, and heating the mixture to dissolve the polyvinyl alcohol, so as to obtain a hydrogel precursor solution; and adding reduced graphene oxide and a cross-linking agent to the hydrogel precursor solution, uniformly mixing same to obtain a mixed solution, gelatinizing the mixed solution, and then freeze-drying same, so as to obtain a target product. The preparation method is simple to operate, low in terms of cost, and environmentally friendly, and endows the hydrogel with excellent multifunctional properties, including wide spectrum absorption performance, seawater desalination performance, wastewater purification performance, etc.

The present invention relates to a colloidal composition comprising unmodified, discrete cellulose microparticles, such as a colloidal emulsion or colloidal gel, a method of preparing the colloidal composition and uses of the colloidal composition and cellulose particles The colloidal composition comprises a continuous phase and a dispersed phase, wherein the continuous phase is a liquid; wherein the dispersed phase comprises cellulose microparticles which are dispersed in the continuous phase of the colloidal composition, wherein the cellulose microparticles have a mean average particle length of from 0.1 to 20 µm a mean average particle width from 0.05 to 1.3 µm, and a maximum thickness not exceeding 0.2 µm determined by scanning electron microscopy; and an aspect ratio of length / width of 1 to 25, and wherein the colloidal composition has a flow index n of ≤ 1 determined by a rheometer at NTP (normal temperature (25°C) and pressure (1 atm)).

The invention provides polyacrylic acid-carboxylated chitosan interpenetrating network hydrophobic modified hydrogel as well as a preparation method and application thereof, and belongs to the technical field of wastewater treatment. The preparation method comprises the following steps: mixing an acrylic monomer, a hydrophilic acrylate monomer, an etherification type acrylamide monomer, an allyl quaternary ammonium salt type hydrophobic monomer, a crosslinking monomer and water, then mixing with a chitosan compound, and adjusting the pH value to obtain a reaction solution; and mixing the reaction liquid and a photoinitiator, then carrying out polymerization reaction, and sequentially pre-freezing and freeze-drying the obtained polymer hydrogel. Through multiple synergistic effects of photo-initiated rapid polymerization, amphiphilic hydrophobic modification, etherification auxiliary crosslinking and a chitosan compound interpenetrating network, the structural stability, complexing efficiency, industrial applicability and heavy metal adsorption performance are comprehensively improved; the adsorption rate and capacity of the hydrogel disclosed by the invention are obviously superior to those of the existing similar polyacrylic acid-based or chitosan-based hydrogel.

The invention relates to a moisture power generation device and a preparation method and application thereof, and belongs to the technical field of moisture power generation. The moisture power generation device comprises a flexible substrate, an upper electrode, a lower electrode and a power generation active material, the power generation active material is arranged between the upper electrode and the lower electrode; the power generation active material is of a core-sheath structure, a sheath layer on the edge is of a cross-linked hydrogel structure, and a core layer is a hydrogel precursor solution; the sheath layer limits the appearance of the hydrogel precursor solution in the core layer and is in contact with the atmosphere. The core-sheath structure of the power generation active material is prepared by an ultraviolet light induced polymerization / gelation one-step method. The moisture power generation device provided by the invention ensures stable and continuous electric energy output and remarkably improved moisture-electric energy conversion efficiency, adopts a miniaturized design, has the remarkable advantages of compact structure and convenience in integrated application, and is beneficial to large-scale production due to assembly convenience.

The invention relates to the field of functional gel composite material preparation and application thereof, in particular to an alpha-FeOOH gel composite material and a preparation method thereof.The preparation method includes the steps that 1, mixed solid powder is prepared and added into humic acid to be mixed to obtain gel, and the gel is added into a FeSO4 solution to be stirred and mixed; 2, a NaOH solution is dropwise added into the mixture, the mass ratio of FeSO4 to NaOH and the pH value of the NaOH solution are controlled, air is introduced for oxidation, and a supported alpha-FeOOH seed crystal suspension compound is obtained; 3, dispersing chitosan in a mixed aqueous solution of humic acid and acetic acid to obtain a mixed aqueous solution of chitosan and humic acid; 4, mixing the suspension compound with the mixed aqueous solution to obtain a cross-linked mixture solution; and 5, adding the FeSO4 solution again, introducing air to oxidize, and dropwise adding the NaOH solution to control the pH value of the cross-linked mixture solution, so that alpha-FeOOH is precipitated and grows on the seed crystal, and the alpha-FeOOH-gel slow-release composite material is obtained. The humic acid enables the degradable plastic to age, exposes functional groups, and is easier to mix.

The invention discloses a method for efficiently dissolving all components of a plant biomass raw material. According to the method, a eutecticevaporate solvent system is adopted to carry out mild soaking treatment on a plant biomass raw material, and a homogeneous plant biomass all-component solution is finally formed by combining the dissolution synergistic coupling effect of a metal salt solution. All-component one-pot efficient dissolution of cellulose, hemicellulose and lignin in the plant biomass raw materials can be achieved, the dissolution efficiency reaches up to 100%, the dissolution process is mild, energy consumption is low, and the method has industrial application prospects; the prepared plant biomass all-component solution can be used as a material construction platform for preparing a series of plant biomass gel, films, fiber materials and the like with excellent performance, and can be used in the fields of sewage treatment, bio-based packaging, spinning, energy collection, 3D printing and the like.

Proposed is a conductive hydrogel including a micelle and a metal-organic framework / surfactant composite.

This invention discloses an ultra-high toughness multifunctional self-assembled C-S-H gel material and its preparation method. The ultra-high toughness multifunctional self-assembled C-S-H gel material includes a stacked core-shell structure layer, which is composed of core-shell structure particles. The core-shell structure particles have hydrated calcium silicate nanoparticles as the core and polyacrylic acid-acrylamide copolymer as the shell. The obtained ultra-high toughness multifunctional self-assembled C-S-H gel material has high toughness, good tensile deformation properties, and temperature-sensitive effect.

The invention belongs to the technical field of scale inhibitors, and particularly relates to a slow-release scale inhibitor and a preparation method thereof.The preparation method comprises the steps that 3, 4, 5-allyl trihydroxybenzoate, itaconic acid, sodium hydrogen sulfite, methacryloyloxyethyl-n-hexadecyl-dimethyl ammonium bromide and deionized water are mixed, after water bath heating, an ammonium persulfate aqueous solution is slowly added, and the scale inhibitor is obtained after reaction; the preparation method comprises the following steps: dissolving agar in deionized water, adding polyethylene glycol modified sodium alginate and a scale inhibitor into the deionized water, stirring, dropwise adding into edible oil to obtain gel microspheres, adding the gel microspheres into a calcium chloride aqueous solution, slowly stirring, cross-linking, cleaning and drying to obtain the slow-release scale inhibitor. The hydrogel microspheres swell to slowly release the scale inhibitor, meanwhile, the released scale inhibitor is hydrolyzed in water, ester groups are slowly broken, polycarboxylic acid, 3, 4, 5-trihydroxybenzoic acid and hydroxyethyl-n-hexadecyl-dimethyl ammonium bromide are slowly released, and good scale inhibition and corrosion inhibition effects are achieved.

The invention discloses a high-strength and high-salt-tolerance fabric composite hydrogel solar interface evaporation material and a preparation method and application thereof.The preparation method comprises the steps that multiple pieces of fabric are soaked in a Tris-HCl solution containing dopamine hydrochloride, and dipping and stirring are conducted for 12-24 h at the room temperature so that the dopamine hydrochloride can be polymerized on the fabric in situ; a photo-thermal material is attached to one piece of treated fabric and dried; the preparation method comprises the following steps: preparing a colorless thick precursor solution from polyvinyl alcohol, an acrylic monomer, an initiator and a cross-linking agent; soaking the treated fabric in the precursor solution in advance for 3-6 hours, putting the fabric attached with the photo-thermal material on the upper layer, putting other fabrics on the lower layer, stacking into 0-3 layers, putting into a mold with the thickness of 1.5-4.5 mm, injecting the precursor solution, putting into a drying oven with the temperature of 60-70 DEG C, and polymerizing for 3-5 hours, so as to obtain the fabric composite hydrogel solar interface evaporation material with high strength and high salt resistance. The fabric composite hydrogel material prepared by the invention has excellent mechanical properties, high salt resistance and better water evaporation rate.

The invention relates to the technical field of solid-phase silica gel preparation, in particular to a preparation device and process of modified solid-phase silica gel for robot skin. The preparation device of the modified solid-phase silica gel for the robot skin comprises a supporting frame, a reaction kettle and a temperature control tube, wherein the reaction kettle and the temperature control tube are erected on the supporting frame; the guide pipe is mounted at the bottom end of the reaction kettle, one end of the guide pipe is inserted into the temperature control pipe and is provided with two groups of liquid guide plates, the liquid guide plates are symmetrically distributed based on the guide pipe, glue outlet holes are formed in the middle parts of the two groups of liquid guide plates, and the glue outlet holes are communicated with a first gel pump; the liquid outlet end of the first gel pump is connected with a centrifugal liquid guide mechanism used for shaking up and exhausting silica gel, and a gate plate piece used for sealing the guide pipe and the reaction kettle is installed in the guide pipe; the sealing cover is mounted on the reaction kettle, and a stirring mechanism for stirring silica gel preparation raw materials is mounted on the sealing cover. The device and the process for preparing the modified solid-phase silica gel for the robot skin, provided by the invention, have the advantages of uniform stirring and high extrusion molding quality.

The invention relates to a metal ion regulation-based ayu pectin gel forming method and application thereof. The method comprises using monovalent or divalent metal ions (such as Ca < 2 + >, Mg < 2 + >, Na < + >, K < + > and the like) to regulate the formation of the Ayu pectin gel. The preparation method comprises the following specific preparation steps: firstly, dissolving Aiyu pectin in deionized water, and uniformly stirring to prepare a pectin solution; then adding a required metal ion solution, and regulating and controlling the concentrations of different metal ions, so that the metal ions interact with pectin molecules; and standing the mixed solution at room temperature for a certain time, and inducing to form stable pectin gel. The method has the advantages that crosslinking of pectin molecular chains is regulated and controlled through metal ions, and the mechanical property and the water holding capacity of the gel can be remarkably improved; in addition, extra energy input is not needed, and the preparation process is simple, efficient, environment-friendly and green; the finally formed pectin gel has good thermal stability and structural strength, and is suitable for food, health care products and other fields.

The invention discloses a seawater initiation preparation method of metal wet gel and aerogel and application of the seawater initiation preparation method in electro-catalysis ethylene glycol oxidation. Comprising the following steps: 1) sequentially adding a metal salt, sodium citrate and a reducing agent into pure water, 2) adding seawater into a reaction solution to obtain wet gel, and 3) washing and drying the wet gel to obtain the aerogel. Seawater can be used for replacing expensive drugs used in a large amount in a salting-out method and an excessive sodium borohydride method, so that the metal nanoparticle solution is unstable, the metal aerogel material is prepared, and the preparation cost of the metal aerogel is greatly reduced. The metal aerogel obtained by the invention shows excellent catalytic performance in the application of electro-catalysis of ethylene glycol oxidation.

The invention belongs to the technical field of aviation fuel, and provides a method for producing sustainable aviation fuel by utilizing straws, which comprises the following steps: firstly, preparing synthesis gas from the straws; then carrying out a catalytic reaction on the synthesis gas and dimethyl ether through a primary molecular sieve catalyst, carrying out a catalytic reaction on the obtained catalytic product through a secondary metal catalyst, and separating to obtain ethanol; then preparing ethylene from the ethanol; and finally, preparing the aviation fuel from ethylene. The preparation method of the primary molecular sieve catalyst comprises the following steps: mixing a phosphoric acid solution with deionized water, adding a template agent according to a molar ratio of phosphoric acid to the template agent of 1: (0.5-0.55), and adding an aluminum source, a cerium source and silica sol while stirring to obtain gel; heating and crystallizing the gel; centrifugally washing the product to be neutral, drying and roasting; immersing the roasted product into a zinc nitrate solution, drying and calcining to obtain a zinc-loaded product; and performing dealumination treatment on the zinc-loaded product by using a citric acid solution, and roasting to obtain the zinc-loaded catalyst. According to the method, the ethanol yield in the aviation fuel production process can be remarkably improved.

The invention belongs to the technical field of photo-thermal material engineering, and particularly relates to a salt-resistant hydrogel evaporator utilizing solar evaporation for power generation and a preparation method and application thereof. The salt-tolerant hydrogel evaporator is prepared from the following raw materials: polyvinyl alcohol, hydrophilic conductive nanoparticles, bacterial nanocellulose and carbon nanotubes. Polyvinyl alcohol (PVA) is used as a framework, bacterial cellulose (BC) jointly forms a hydrogel structure with a hierarchical nanostructure, modified polyaniline conductive nanoparticles (CPs) are used for enhancing the electric signal transmission capacity of the hydrogel evaporator, and the salt-resistant hydrogel solar evaporator capable of realizing seawater desalination and electric power generation is prepared by adopting a simple and convenient method.

The invention discloses a method for wrapping stem cells by adopting programmable DNA (deoxyribonucleic acid) hydrogel and application of the method, under isothermal physiological conditions, three-dimensional DNA hydrogel is formed through a hybridization chain reaction of an initiation chain (I) and hairpin structure DNA to realize reversible wrapping and release of the stem cells. The hairpin structure DNA is formed by denaturation-renaturation treatment of at least two DNA monomer building blocks, and the mechanical rigidity of the hydrogel is realized by regulating and controlling the molar ratio of the initiation chain (I) to the total amount of the DNA monomer building blocks; the DNA hydrogel can reversibly wrap and release stem cells, and the wrapped stem cells can maintain activity and dryness and recover normal multiplication capacity after being released. According to the method disclosed by the invention, the activity and dryness of the stem cells are remarkably maintained, obvious immune activation is avoided, and the method provides a brand new tool for in-vitro culture and engineering application of the stem cells and has a wide application prospect.

The invention relates to self-assembled microgel, a microgel assembled stent and a preparation method and a preparation device of the self-assembled microgel and the microgel assembled stent. The preparation method of the self-assembled microgel comprises the following steps: mixing a first solution and a second solution to obtain a pre-crosslinked product; mixing and emulsifying the pre-crosslinked product and a third solution to obtain a full-water-phase emulsified product; performing low-temperature condensation treatment on the all-water-phase emulsified product to obtain a low-temperature gel product; and further crosslinking the low-temperature gel product to obtain the self-assembled microgel. The invention provides the preparation method of the controllable reversible self-assembled microgel and the microgel assembled stent based on dynamic interaction of Schiff base and the like, the process is simple, the cost is relatively low, the equipment threshold requirement is low, the whole-process time consumption is relatively short, and the obtained product is high in cleanliness, high in safety, simple and convenient in form and easy to store and transport, and has a wide application prospect; and a new solution thought is provided for the fields of life science research and biomedicine.

The invention relates to core-shell hydrogel microsphere preparation equipment which comprises a microsphere preparation device and a microsphere collection device, the microsphere preparation device is provided with a nuclear phase inlet, a shell phase inlet, a plurality of nuclear phase distribution runners communicated with the nuclear phase inlet, and a plurality of shell phase distribution runners communicated with the shell phase inlet; the nuclear phase distribution flow channels and the shell phase distribution flow channels are converged into coaxial flow channels at the tail ends in a one-to-one correspondence manner; the microsphere collecting device comprises a microsphere collecting pool, the microsphere collecting pool is arranged below the coaxial flow channel, and the microsphere collecting pool is used for containing oil phase fluid; the nuclear phase fluid entering from the nuclear phase inlet and the shell phase fluid entering from the shell phase inlet form layered fluid at the coaxial flow channel, and the layered fluid is dropped into the microsphere collecting pool. According to the core-shell hydrogel microsphere preparation equipment provided by the invention, high-flux preparation of core-shell hydrogel microspheres can be realized.

The invention discloses a polyaluminum chloride-based flocculant as well as a preparation method and application thereof, belongs to the technical field of preparation of flocculants, and aims at solving the technical problem that the flocculation performance and the stability of a flocculant in the prior art need to be further improved. The surface charges of iron-based particles are adjusted through sodium citrate, so that the problem of particle agglomeration is effectively avoided, the coating uniformity of microgel is improved, and the specific surface area of the material is increased; abundant cation sites are introduced into the trimethylamine modified chitosan, so that the electrostatic adsorption capacity of the microgel on anion pollutants is remarkably enhanced, and meanwhile, the electrical property and the stability of a system are improved; the addition of sodium metasilicate further promotes the modified PAC to form a stable Al-O-Si bridging structure, the material is endowed with good three-dimensional skeleton strength and composite interface stability, the three components cooperate with each other and play key roles in particle dispersity, charge construction and skeleton stability, and finally, an efficient, stable and storable composite flocculation system is constructed.