Dual cure formulations with components comprising uretdione groups
A technology of isocyanate and dimer, which is applied in the direction of polyurea/polyurethane adhesives, adhesives, polyester coatings, etc., can solve problems such as no coating, no effect on coating hardness and scratch resistance
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(A) IRGACURE 184 Photoinitiator, Ciba(E) ARALDITE PT 912 Cocatalyst, glycidyl ester, Huntsman (C1) Zinc acetylacetonate Cocatalyst, Aldrich (C2)
[0084] raw material product description, manufacturer TEAB Tetraethylammonium Benzoate, RSA Corp. (C) DBTL Dibutyltin dilaurate, catalyst, Aldrich
[0085] A) Production of radiation curable resins
[0086] A1) Polyester Production
[0087] Adipic acid (292 g) and butanediol (295 g) were melted in a 21 flask with a distillation head under nitrogen flow. When the temperature reaches 160°C, water starts to distill out. The temperature was continuously raised to 220°C over a period of 1 hour. After 4 hours at this temperature, the separation of water slowed down. 200 mg of FASCAT 4102 (transesterification catalyst from Arkema) were incorporated with stirring and the operation was continued under reduced pressure, which was adjusted during the reaction so that distillate produc...
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