The invention discloses a composite
proton exchange membrane based on large-area single-layer nano-
porous graphene Nafion and a preparation method of the composite
proton exchange membrane. The preparation method comprises the following steps: firstly, performing
plasma etching to obtain a
graphene /
copper foil sample; spin-
coating Nafion latex on the
graphene surface of the
graphene /
copper foil sample; the spin-coated graphene /
copper foil sample is dried and cured, a
Nafion film is hot-pressed on the spin-
coated surface of the graphene sample, and a Nafion / graphene /
copper foil sample is obtained; the method comprises the following steps:
etching a Nafion / graphene /
copper foil sample in an
etching solution, then washing the sample, and completing etching, cleaning and airing of the residual
copper foil; the Nafion latex is continuously spin-coated; the spin-coated Nafion / graphene sample is dried and cured, and then the spin-coated Nafion / graphene sample and a Nafion thin film are subjected to hot-pressing compounding; and soaking the Nafion / graphene / Nafion sample in an acid solution, and airing to obtain the
proton exchange membrane based on the large-area single-layer nano-
porous graphene Nafion composite. According to the invention, the
bottleneck of
performance improvement caused by insufficient selectivity of the proton exchange membrane and low proton transmission efficiency of the intrinsic graphene is effectively solved.