The invention discloses a polypropylene/polyvinylidene fluoride blended modified material and a preparation method thereof. The polypropylene/polyvinylidene fluoride blended modified material includes, by weight, 20-70 parts of polypropylene, 10-50 parts of polyvinylidene fluoride, 5-30 parts compatibilizer, 5-30 parts of a toughener, 0.05-1 part of an antioxidant and 0.05-5 parts of an ultraviolet absorber. The preparation method comprises the following steps: the polypropylene, polyvinylidene fluoride, the compatibilizer, the toughener, the antioxidant and the ultraviolet absorber are weighed according to the above formula ratio, and are added into a twin-screw extruder, and the obtained mixture is plasticized, is dispersed, and then undergoes extrusion granulation to obtain the polypropylene/polyvinylidene fluoride blended modified material. The ultraviolet radiation resistance quantity of the polypropylene/polyvinylidene fluoride modified material prepared in the invention can be increased by 3 times, or more, the outdoor service life of a tube made from the polypropylene/polyvinylidene fluoride modified material is prolonged to 2 times or more of the original service life, theoxygen permeability is reduced by 80%, and the polypropylene/polyvinylidene fluoride modified material also can be used in a -20 to 100 DEG C environment, so the application range is expanded.