A self-cleaning solar energy high-reflectivity nano film and its manufacturing method, comprising a base layer, which is stainless steel or plexiglass, with a thickness of 0.3 mm to 1.2 mm, on which is a transition layer, made of copper or chromium, with a thickness of 20 nm to 50 nm, On it is a reflective layer, the reflective layer is silver, its thickness is 80nm ~ 150nm, on it is a protective layer, the protective layer is silicon dioxide, its thickness is 200nm ~ 800nm, on it is a self-cleaning layer, self-cleaning The layer is titanium dioxide, and its thickness is 50nm-250nm. When the reflective film of the present invention is a silver film, the reflectivity to sunlight is 94% to 97%, and when the reflective film is an aluminum film, the reflectivity is 90% to 92%. The present invention not only has high reflectivity, but also has The self-cleaning function is just as bright as new after just flushing with water, and the outdoor service life is long.