The application discloses a kind of fire-retardant
lignin-based
formaldehyde-free
adhesive and preparation method thereof, belong to
adhesive preparation technical field, for solving in prior art,
adhesive bonding strength and
flame retardant performance need to be further improved technical problem;The present application is with
lignin as main body, sequentially through
triazine,
phosphonate and nitrogenization modification, introduce
nitrogen,
phosphorus and polar group, prepare fire-retardant glue precursor, then combine
catechol polyol and
boric acid reaction generated borate
polyol, and the
hybrid prepolymer obtained by the action of amino POSS
sol and
glycerol carbonate, synergistic curing under the action of initiator, construct dense stable crosslinking network, the
system has the
environmental protection of
lignin and the stability of organic-inorganic
hybrid material, give adhesive high strength, excellent
water resistance and
flame retardant performance, and
formaldehyde release is zero, suitable for green
environmental protection field application.