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A ball milling modification method for thin-layer hexagonal boron nitride modified with bifunctional groups

This invention belongs to the field of inorganic nanoparticle preparation technology, and relates to a ball milling modification method for bifunctionalized thin-layer hexagonal boron nitride: Hexagonal boron nitride powder, guanidine hydrochloride, and urea are continuously heated and stirred to obtain a homogeneous mixture of a eutectic solvent formed by guanidine hydrochloride and urea and the hexagonal boron nitride powder; this mixture is poured into a ball mill jar containing grinding balls and a liner, and a certain amount of ethanol and water are added as dispersants for high-energy ball milling; after the material is separated from the grinding balls, the milled material is vacuum filtered, dried, and the resulting powder is dispersed in water, then ultrasonicated, allowed to stand, vacuum filtered, and dried to obtain bifunctionalized thin-layer hexagonal boron nitride. This invention not only has the advantages of readily available raw materials and simple process, but also high efficiency, environmental friendliness, and low energy consumption. The hexagonal boron nitride obtained by this method has thinner layers, good biocompatibility, low relative density, and good thermal conductivity.
Owner:SHENYANG UNIVERSITY OF TECHNOLOGY