The invention belongs to the technical field of traditional Chinese medicine decoction piece processing, and particularly relates to a method for processing brewing exocarpium pieces. The method comprise the following steps: cleaning, performing ultraviolet radiation, performing quick-freezing and unfreezing, performing microwave drying, performing moistening and shaping, slicing, drying, packaging and performing preservation. According to the method for processing the brewing exocarpium pieces, due to ultraviolet radiation, effective components of the exocarpium pieces, such as flavonoids, can be increased; due to the modes of quick-freezing and unfreezing, loss of effective components can be reduced, cracking of cell walls of fresh exocarpium can be promoted, the dissolution degrees of the effective components in water can be increased, the microwave drying speed is rapid, a good thermal effect can be achieved, the activity of enzyme can be reduced, and the exocarpium pieces can be kept bright in color. The bitter taste of exocarpium can be removed, a product can be bright in color, uniform in size and good in reconstitution property, and problems that the exocarpium pieces are molded, deoiled, damaged by worms and the like when being preserved for a long time can be also solved. The product is green and pollution-free in the processing course, and market requirements can be effectively met.