The application discloses a kind of
supercapacitor negative high-efficiency
composite electrode and preparation method thereof, including the block body iron of substrate and the outer layer PrNi x Fe 1‑x O3 conductive
active layer, and Fe2O3
active layer between the two, by wet chemical
etching and transient high temperature
joule heat method in-situ synthesis
active layer, and further utilize wet chemical
brush coating and transient high temperature
joule heat method in-situ synthesis conductive active layer, two are asymmetric sandwich structure, it is favorable to build charge transport path, improve charge transport efficiency, at the same time, can effectively relieve the
volume change generated in the process of
charge and discharge of
iron oxide, unlike the characteristics of particle
composite structure easy to collapse, inhibit the occurrence of
electrode material pulverization, wherein, using transient high temperature
joule heat preparation technology, layered in-situ build heterostructure, not only simple and fast, also make the structure compact and dense, maintain the stability of overall
electrode structure, improve the long-period cycle
charge and discharge capacity of
electrode.