The invention provides a positive active material and a preparation method thereof, a positive
pole piece, a battery and
electric equipment, the positive active material comprises secondary particles formed by primary particles, the positive active material comprises Li1 + aFebMc (PO4) d,-0.1 < = a < = 0.1, 0 < b < = 1, 0 < = c < = 0.5, 0 < d < = 1, and M comprises at least one of La, Ce, Cr, Mo, Ca, Hf, Ti, Fe, Zn, Y, Zr, W, Nb, Sm, Sb, Co, Ni, V, Mg, Na, B and Al; the
porosity of the positive
electrode active material is 6.5%-15%, and the average pore size of the positive
electrode active material is 145 nm-290 nm. The battery containing the positive
electrode active material provided by the invention has excellent capacity, rate capability and cycle performance.